Potential environmental issues of CO2 storage in deep saline aquifers: Geochemical results from the Frio-I Brine Pilot test,Texas, USA

Sedimentary basins in general, and deep saline aquifers in particular, are being investigated as possible repositories for large volumes of anthropogenic CO₂ that must be sequestered to mitigate global warming and related climate changes. To investigate the potential for the long-term storage of CO₂ in such aquifers, 1600 t of CO₂ were injected at 1500 m depth into a 24-m-thick “C” sandstone unit of the Frio Formation, a regional aquifer in the US Gulf Coast. Fluid samples obtained before CO₂ injection from the injection well and an observation well 30 m updip showed a Na–Ca–Cl type brine with ∼93,000 mg/L TDS at saturation with CH₄ at reservoir conditions; gas analyses showed that CH₄ comprised ∼95% of dissolved gas, but CO₂ was low at 0.3%. Following CO₂ breakthrough, 51 h after injection, samples showed sharp drops in pH (6.5–5.7), pronounced increases in alkalinity (100–3000 mg/L as HCO₃) and in Fe (30–1100 mg/L), a slug of very high DOC values, and significant shifts in the isotopic compositions of H₂O, DIC, and CH₄. These data, coupled with geochemical modeling, indicate corrosion of pipe and well casing as well as rapid dissolution of minerals, especially calcite and iron oxyhydroxides, both caused by lowered pH (initially ∼3.0 at subsurface conditions) of the brine in contact with supercritical CO₂.     

Social memory and resilience in New Orleans

A key concept in resilience studies is that human societies can learn from hazard events and use their accumulated social memory to better contend with future catastrophes. This article explores the deliberate referral to historical records complied after Hurricane Betsy in 1965 and how they were used to prepare for tropical storms at the time of Hurricane Katrina in 2005. Despite proclamations that Louisiana would not repeat its mistakes, hazards planners seriously neglected the historical record.     

Volcano monitoring in NZ and links to SW Pacific via the Wellington VAAC

Monitoring for natural hazards like earthquakes, volcanic eruptions and landslides in New Zealand is under taken by GNS Science through the GeoNet project, funded by the Earthquake Commission (EQC). The volcano monitoring function, which includes seismograph and GPS networks, visual observations, webcams, deformation, gas and chemical measurements, assesses the status of New Zealand’s 12 active volcanoes and disseminates warnings as necessary. Interaction with the Wellington VAAC addresses aviation concerns. Near-real-time data is obtained from the monitoring networks and processed via two data centres, with two Duty Officers who respond to pager alerts. Through the National Civil Defence Plan, the volcano monitoring function is delegated to GNS Science, which is responsible for setting the volcanic alert level at each volcano. The Alert level is then used by responding agencies, industries, utility providers and the public to set their response. The New Zealand alert level system is based on the current status of the volcano, and is not necessarily predictive. The aviation industry is one of these responding industries. As a consequence of the 1995 and 1996 eruptions of Ruapehu volcano, it became apparent that the aviation industry required more information than the standard VAAC data and an additional service known as VAAS (NZ Volcanic Ash Advisory System) was established by MetService NZ and GNS Science. This arrangement provides enhanced services to the airlines and ensures rapid dissemination and quantification of information like SIGMET and NOTAM. GNS Science has informal relationships with similar geological based organisations in SW Pacific countries, especially Vanuatu and the Solomon Islands, and is able to quantify information about eruptions in those countries. Similarly, MetService NZ has relationships and is able to obtain pilot reports and updates from the meteorological and air traffic control organisations.     

Mn-oxides and sequestration of heavy metals in a suburban catchment basin of the Chesapeake Bay watershed

The Chesapeake Bay is greatly impacted by numerous pollutants including heavy metals and understanding the controls on the distribution of heavy metals in the watershed is critical to mitigation and remediation efforts in controlling this type of pollution. Clasts from a stormwater catchment basin draining a subdivision near George Mason University, Fairfax VA (38°50.090°N 78°19.204°W) were investigated using X-ray diffraction (XRD), Scanning electron microcopy (SEM) and energy dispersive spectroscopy (EDS) to determine the nature of Mn-oxide coatings and relationship to bound heavy metals. Mn-oxides are poorly crystalline and occur as subhedral to anhedral platy particles and more rarely as euhedral plates. Micronodules are a commonly observed texture. Chemical compositions of coatings are variable with average major constituent concentrations being Mn (33.38 wt%), Fe (11.88 wt%), Si (7.33 wt%), Al (5.03 wt%), and Ba (0.90 wt%). Heavy metals are found in the coatings with Zn being most prevalent, occurring in approximately 58% of analyses with an average concentration of (0.66 wt%). Minor amounts of Co, Ni, Pb, and Cl are observed. Heavy metals and Cl are interpreted as being derived from road pollution. Mn-oxides can serve as a sequestration mechanism for pollution but may also release heavy metals. Field and laboratory observations indicate Mn-oxides occurring on the surface of the clasts can be mechanically mobilized. This is a mechanism for transporting heavy metals into the Chesapeake Bay watershed. Deicing agents may serve as a mechanism to release heavy metals through cation exchange and increased ionic strength. This is the first detailed mineralogical investigation of Mn-oxides and the roles they may play in pollution in the Chesapeake Bay.     

A large sedimentary basin in the Terra Sirenum region of the southern highlands of Mars

Different lines of evidence point to hydrological cycling in the martian past. The extent, duration, and magnitude of this cycling remains unclear, as well as the magnitude of aqueous processes on the surface. Here, we provide geomorphic and mineralogic evidence of a large inter-crater sedimentary basin located in the Terra Sirenum region, which was once covered by a body of liquid water with an areal extent of at least 30,000 km² and a depth of approximately 200 m. The topographic basin, which is modified by a number of large impact craters, is partly controlled by ancient impact and tectonic structures. As a result of evaporation of the large body of water, salt flats formed in the lowest topographic reaches of the basin. Hydrated phyllosilicates occur in close proximity to the salt flats and in the ejecta and rim materials of small impact craters with stratigraphic relations that suggest that they underlie the evaporite deposits. Crater statistics place the maximum age of aqueous activity during the Late Noachian epoch. The relatively pristine mineral deposits in the basin have a high potential to yield information of the geochemistry and water activity during the ancient Noachian Period when conditions were seemingly more conducive to life.     

Development of an observational error model

In calculating the orbit of a minor planet with a least-squares algorithm, current practice is to assume that all observations of a given era have the same uncertainty, and that the errors in these observations are uncorrelated. These assumptions are unrealistic; and they lead to sub-optimal orbits.Our objective is to develop and validate an observational error model that provides realistic estimates of the uncertainties and correlations in asteroid observations. When used to populate the covariance matrix of the least-squares algorithm, the resulting orbits are shown to more accurately and precisely represent asteroid trajectories.     

A reanalysis of the Apollo light scattering observations, and implications for lunar exospheric dust

Conspicuous excess brightness, exceeding that expected from coronal and zodiacal light (CZL), was observed above the lunar horizon in the Apollo 15 coronal photographic sequence acquired immediately after orbital sunset (surface sunrise). This excess brightness systematically faded as the Command Module moved farther into shadow, eventually becoming indistinguishable from the CZL background. These observations have previously been attributed to scattering by ultrafine dust grains (radius ∼0.1 microns) in the lunar exosphere, and used to obtain coarse estimates of dust concentration at several altitudes and an order-of-magnitude estimate of ∼10⁻⁹ g cm⁻² for the column mass of dust near the terminator, collectively referred to as model “0”.We have reanalyzed the Apollo 15 orbital sunset sequence by incorporating the known sightline geometries in a Mie-scattering simulation code, and then inverting the measured intensities to retrieve exospheric dust concentration as a function of altitude and distance from the terminator. Results are presented in terms of monodisperse (single grain size) dust distributions. For a grain radius of 0.10 microns, our retrieved dust concentration near the terminator (∼0.010 cm⁻³) is in agreement with model “0” at z=10 km, as is the dust column mass (∼3–6×10⁻¹⁰ g cm⁻²), but the present results indicate generally larger dust scale heights, and much lower concentrations near 1 km (<0.08 cm⁻³ vs. a few times 0.1 cm⁻³ for model “0"). The concentration of dust at high altitudes (z>50 km) is virtually unconstrained by the measurements. The dust exosphere extends into shadow a distance somewhere between 100 and 200 km from the terminator, depending on the uncertain contribution of CZL to the total brightness. These refined estimates of the distribution and concentration of exospheric dust above the lunar sunrise terminator should place new and more rigorous constraints on exospheric dust transport models, as well as provide valuable support for upcoming missions such as the Lunar Atmosphere and Dust Environment Explorer (LADEE).     

The dayside magnetospheric boundary layer at Mercury

Magnetic field and plasma data from the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft on the outbound portions of the first (M1) and second (M2) flybys of Mercury reveal a region of depressed magnetic field magnitude and enhanced proton fluxes adjacent to but within the magnetopause, which we denote as a dayside boundary layer. The layer was present during both encounters despite the contrasting dayside magnetic reconnection, which was minimal during M1 and strong during M2. The overall width of the layer is estimated to be between 1000 and 1400 km, spanning most of the distance from the dayside planetary surface to the magnetopause in the mid-morning. During both flybys the magnetic pressure decrease was ∼1.6 nPa, and the width of the inner edge was comparable to proton gyro-kinetic scales. The maximum variance in the magnetic field across the inner edge was aligned with the magnetic field vector, and the magnetic field direction did not change markedly, indicating that the change in field intensity was consistent with an outward plasma-pressure gradient perpendicular to the magnetic field. Proton pressures in the layer inferred from reduced distribution observations were 0.4 nPa during M1 and 1.0 nPa during M2, indicating either that the proton pressure estimates are low or that heavy ions contribute substantially to the boundary-layer plasma pressure. If the layer is formed by protons drifting westward from the cusp, there should be a strong morning–afternoon asymmetry that is independent of the interplanetary magnetic field (IMF) direction. Conversely, if heavy ions play a major role, the layer should be strong in the morning (afternoon) for northward (southward) IMF. Future MESSENGER observations from orbit about Mercury should distinguish between these two possibilities.     

The transition from complex crater to peak-ring basin on the Moon: New observations from the Lunar Orbiter Laser Altimeter (LOLA) instrument

Impact craters on planetary bodies transition with increasing size from simple, to complex, to peak-ring basins and finally to multi-ring basins. Important to understanding the relationship between complex craters with central peaks and multi-ring basins is the analysis of protobasins (exhibiting a rim crest and interior ring plus a central peak) and peak-ring basins (exhibiting a rim crest and an interior ring). New data have permitted improved portrayal and classification of these transitional features on the Moon. We used new 128 pixel/degree gridded topographic data from the Lunar Orbiter Laser Altimeter (LOLA) instrument onboard the Lunar Reconnaissance Orbiter, combined with image mosaics, to conduct a survey of craters >50 km in diameter on the Moon and to update the existing catalogs of lunar peak-ring basins and protobasins. Our updated catalog includes 17 peak-ring basins (rim-crest diameters range from 207 km to 582 km, geometric mean = 343 km) and 3 protobasins (137-170 km, geometric mean = 157 km). Several basins inferred to be multi-ring basins in prior studies (Apollo, Moscoviense, Grimaldi, Freundlich-Sharonov, Coulomb-Sarton, and Korolev) are now classified as peak-ring basins due to their similarities with lunar peak-ring basin morphologies and absence of definitive topographic ring structures greater than two in number. We also include in our catalog 23 craters exhibiting small ring-like clusters of peaks (50-205 km, geometric mean = 81 km); one (Humboldt) exhibits a rim-crest diameter and an interior morphology that may be uniquely transitional to the process of forming peak rings. A power-law fit to ring diameters (D_ring) and rim-crest diameters (D_r) of peak-ring basins on the Moon [D_ring = 0.14 ± 0.10(D_r)^1.21±0.13] reveals a trend that is very similar to a power-law fit to peak-ring basin diameters on Mercury [D_ring = 0.25 ± 0.14(D_rim)^1.13±0.10] [Baker, D.M.H. et al. [2011]. Planet. Space Sci., in press]. Plots of ring/rim-crest ratios versus rim-crest diameters for peak-ring basins and protobasins on the Moon also reveal a continuous, nonlinear trend that is similar to trends observed for Mercury and Venus and suggest that protobasins and peak-ring basins are parts of a continuum of basin morphologies. The surface density of peak-ring basins on the Moon (4.5 × 10⁻⁷ per km²) is a factor of two less than Mercury (9.9 × 10⁻⁷ per km²), which may be a function of their widely different mean impact velocities (19.4 km/s and 42.5 km/s, respectively) and differences in peak-ring basin onset diameters. New calculations of the onset diameter for peak-ring basins on the Moon and the terrestrial planets re-affirm previous analyses that the Moon has the largest onset diameter for peak-ring basins in the inner Solar System. Comparisons of the predictions of models for the formation of peak-ring basins with the characteristics of the new basin catalog for the Moon suggest that formation and modification of an interior melt cavity and nonlinear scaling of impact melt volume with crater diameter provide important controls on the development of peak rings. In particular, a power-law model of growth of an interior melt cavity with increasing crater diameter is consistent with power-law fits to the peak-ring basin data for the Moon and Mercury. We suggest that the relationship between the depth of melting and depth of the transient cavity offers a plausible control on the onset diameter and subsequent development of peak-ring basins and also multi-ring basins, which is consistent with both planetary gravitational acceleration and mean impact velocity being important in determining the onset of basin morphological forms on the terrestrial planets.     

Roles of methane and carbon dioxide in geological processes on Mars

We discuss in this paper possible roles of methane and carbon dioxide in geological processes on Mars. These volatiles in the martian crust may migrate upward from their sources either directly or via various traps (structural, sedimentary, ground ice, gas hydrates). They are then likely emitted to the atmosphere by seepage or through diverse vent structures. Though gas hydrates have never been directly detected on Mars, theoretical studies favor their presence in the crust and polar caps; they could have played an important role as significant gas reservoirs in the subsurface. The martian gas hydrates would possibly be a binary system of methane and carbon dioxide occupying clathrate cavities. Landforms such as mud volcanoes with well-known linkage to gas venting are extensively distributed on Earth, and methane is the primary gas involved. Thus, identification of these landforms on Mars could suggest that methane and possibly carbon dioxide have contributed to geological processes of the planet. For example, we present a newly identified field in Chryse Planitia where features closely resembling terrestrial mud volcanoes occur widely, though with no observable activity. We also present results of a preliminary search for possible recent or present-day, methane-emission zones in the regions over which enrichments of atmospheric methane have been reported.