Sulfur cycling at the Mid-Atlantic Ridge: A multiple sulfur isotope approach

The role of sulfur in two hydrothermal vent systems, the Logatchev hydrothermal field at 14°45′N/44°58′W and several different vent sites along the southern Mid-Atlantic Ridge (SMAR) between 4°48′S and 9°33′S and between 12°22′W and 13°12′W, is examined by utilizing multiple sulfur isotope and sulfur concentration data. Isotope compositions for sulfide minerals and vent H₂S from different SMAR sites range from + 1.5 to + 8.9‰ in δ³⁴S and from + 0.001 to + 0.051‰ in Δ³³S. These data indicate mixing of mantle sulfur with sulfur from seawater sulfate. Combined δ³⁴S and Δ³³S systematics reveal that vent sulfide from SMAR is characterized by a sulfur contribution from seawater sulfate between 25 and 33%. This higher contribution, compared with EPR sulfide, indicates increased seawater sulfate reduction at MAR, because of a deeper seated magma chamber and longer fluid upflow path length, and points to fundamental differences with respect to subsurface structures and fluid evolution at slow and fast spreading mid-ocean ridges.Additionally, isotope data uncover non-equilibrium isotopic exchange between dissolved sulfide and sulfate in an anhydrite bearing zone below the vent systems at fluid temperatures between 335 and 400 °C. δ³⁴S values between + 0.2 to + 8.8‰ for dissolved and precipitated sulfide from Logatchev point to the same mixing process between mantle sulfur and sulfur from seawater sulfate as at SMAR. δ³⁴S values between ? 24.5 and + 6.5‰ and Δ³³S values between + 0.001 and + 0.125‰ for sulfide-bearing sediments and mafic/ultramafic host rocks from drill cores taken in the region of Logatchev indicate a clear contribution of biogenic sulfides formed via bacterial sulfate reduction. Basalts and basaltic glass from SMAR sites with Δ³³S = ? 0.008‰ reveal lower Δ³³S lower values than suggested on the basis of previously published isotopic measurements of terrestrial materials.We conclude that the combined use of both δ³⁴S and Δ³³S provides a more detailed picture of the sulfur cycling in hydrothermal systems at the Mid-Atlantic Ridge and uncovers systematic differences to hydrothermal sites at different mid-ocean ridge sites. Multiple sulfur isotope measurements allow identification of incomplete isotope exchange in addition to isotope mixing as a second important factor influencing the isotopic composition of dissolved sulfide during fluid upflow. Furthermore, based on Δ³³S we are able to clearly distinguish biogenic from hydrothermal sulfides in sediments even when δ³⁴S were identical.     

Detecting groundwater contamination of a river in Georgia, USA using baseflow sampling

Algal blooms and fish kills were reported on a river in coastal Georgia (USA) downstream of a poultry-processing plant, prompting officials to conclude the problems resulted from overland flow associated with over-application of wastewater at the plant’s land application system (LAS). An investigation was undertaken to test the hypothesis that contaminated groundwater was also playing a significant role. Weekly samples were collected over a 12-month period along an 18 km reach of the river and key tributaries. Results showed elevated nitrogen concentrations in tributaries draining the plant and a tenfold increase in nitrate in the river between the tributary inputs. Because ammonia concentrations were low in this reach, it was concluded that nitrate was entering via groundwater discharge. Data from detailed river sampling and direct groundwater samples from springs and boreholes were used to isolate the entry point of the contaminant plume. Analysis showed two separate plumes, one associated with the plant’s unlined wastewater lagoon and another with its LAS spray fields. The continuous discharge of contaminated groundwater during summer low-flow conditions was found to have a more profound impact on river-water quality than periodic inputs by overland flow and tributary runoff.     

Application of a nonlinear frequency domain wave–current interaction model to shallow water recurrence effects in random waves

The effect of ambient currents on nearshore nonlinear wave–wave energy transfer in random waves is studied with the use of a nonlinear frequency domain wave–current interaction model. We focus on the phenomenon of wave recurrence as a classical nonlinear phenomenon whose characteristics are well established for systems truncated to small numbers of frequency modes. The model used for this study is first extended to enhance accuracy; comparisons of permanent form solutions to analytical forms confirm the model accuracy. Application of the model to a highly truncated system confirmed the model’s consistency with published results for both positive (following) and negative (adverse) currents. Propagation of random wave spectra over a flat bottom was performed with the model, with the intent of determining the prevalence of recurrence between the spectral peak and its harmonics. For spectra of moderate Ursell number, it was found that positive currents extended the length scale of recurrence relative to the case with no currents; conversely, negative currents reduced the recurrence lengths. However, beyond a propagation distance of ≈40 wavelengths of the spectral peak, recurrence becomes almost completely damped as the spectra becomes broad and the spectral energies equilibrate. For spectra of high Ursell number, in contrast, recurrence is almost immediately damped, suggesting that the nonlinearity is sufficient to allow immediate spectral broadening and equilibration and overwhelming any preferential interactions among the spectral peak and its harmonics, regardless of current magnitude or direction.     

Catch-quota balancing in multispecies individual fishing quotas

Individual fishery quotas (IFQs) are an increasingly prevalent form of fishery management around the world, with more than 170 species currently managed with IFQs. Yet, because of the difficulties in matching quota holdings with catches, many argue that IFQs are not appropriate for multispecies fisheries. Using on-the-ground-experience with multispecies IFQ fisheries in Iceland, New Zealand, Australia, and Canada, we assess the design and use of catch-quota balancing mechanisms. Our methodology includes a mix of interviews with fishery managers, industry representatives, and brokers, literature review, and data analysis. We find that a combination of incentives and limits on use rates for the mechanisms provide sufficient flexibility to the quota owner without the fishery manager incurring excessive levels of overexploitation risk. Contrary to some opinions, these programs are evidence that it is possible to implement IFQ programs for multispecies fisheries and that they can be profitable and sustainable.     

Guidelines on the use of structure-from-motion photogrammetry in geomorphic research

As a topographic modelling technique, structure-from-motion (SfM) photogrammetry combines the utility of digital photogrammetry with a flexibility and ease of use derived from multi-view computer vision methods. In conjunction with the rapidly increasing availability of imagery, particularly from unmanned aerial vehicles, SfM photogrammetry represents a powerful tool for geomorphological research. However, to fully realize this potential, its application must be carefully underpinned by photogrammetric considerations, surveys should be reported in sufficient detail to be repeatable (if practical) and results appropriately assessed to understand fully the potential errors involved. To deliver these goals, robust survey and reporting must be supported through (i) using appropriate survey design, (ii) applying suitable statistics to identify systematic error (bias) and to estimate precision within results, and (iii) propagating uncertainty estimates into the final data products. © 2019 John Wiley & Sons, Ltd.     

Testing a statistical curve‐fitting procedure for quantifying sediment populations within multi‐modal particle‐size distributions

This paper describes a series of tests designed to evaluate the capacity of a personal computer (PC) based statistical curve‐fitting program called MIX to quantify composite populations within multi‐modal particle‐size distributions. Three natural soil samples were analysed by a Coulter Multisizer, and their particle‐size distributions analysed using MIX software to identify the modes, standard deviations and proportions of their composite populations. The particle‐size distributions of the three natural soil samples were then numerically combined in equal proportions using a spreadsheet program to create synthetic particle‐size distributions of known populations. MIX was then tested on the synthetic particle‐size distributions to see if the modes and proportions it identified were similar to those modes and proportions known to characterize the synthetic particle‐size distributions. The main outcome is that MIX can very accurately describe the modal particle size and proportions of the major composite populations within a particle‐size distribution. However MIX has difficulty in identifying small populations (those contributing <10 per cent of a total particle‐size distribution), particularly when they are located in the central sections of particle‐size distributions, overlain by larger populations, or when positioned in the fine tails of distributions. Despite these minor shortcomings, MIX is a valuable tool for the examination and interpretation of particle‐size data. Copyright © 2005 John Wiley & Sons, Ltd.     

An inexpensive instrument for measuring benthic current velocity and direction at sea

An instrument which measures the velocity and direction of benthic water currents at depths of up to 80 m is described. Characteristics of this meter include: (i) readings are not affected by water flow during sinking or retrieval; (ii) it is portable; (iii) it operates unattended; (iv) it is inexpensive; and (v) it requires only simple maintenance. A timing circuit which operates two time periods in succession is used to activate and de-activate a revolution counter and a fluidfilled compass which are mounted on a special frame and vane system. In the field, the instrument accurately measured average current velocities of up to 6 m s⁻¹. Data are presented which illustrate the usefulness of this instrument in describing the velocity and direction of benthic currents along the east coast of Australia and demonstrate a positive correlation between benthic current velocity and catch rates of the commercially-exploited spanner crab Ranina ranina.     

Image resolution and evaluation of genetic hypotheses for planetary landscapes

The spatial resolution of image data tends to constrain the horizontal length scale of genetic hypotheses that are addressable by those data. No ‘simple’ formula exists when image resolution is sufficient to test a given geomorphic process, which is dependent on what characteristics are diagnostic of the particular process. Genetic hypotheses should be formulated along the lines of the “multiple working hypotheses” concept as described in a classic paper by Chamberlin [J. Geol. 5 (1897) 837]. An essential element of a viable working hypothesis is a clear indication of the characteristics predicted by, or a consequence of, the hypothesis. An untestable hypothesis is not an effective working hypothesis. The history of the study of lunar sinuous rilles is outlined as an illustration of the influence of image resolution and the formulation of genetic hypotheses on the subsequent advancement of understanding of the problem. Sinuous rilles on Venus and Mars, and controversial sinuous ridges on Mars are also reviewed. In the lunar case, the three-order-of-magnitude improvement in spatial resolution provided by Lunar Orbiter photographs over Earth-based telescopic photographs did not result in definitive examination and elimination of published hypotheses for the formation of sinuous rilles. Topographic data obtained from cartographically controlled Apollo orbital photographs, along with important observations and samples obtained by the astronauts on the lunar surface, did test and exclude several hypotheses. The formulation of a genetic hypothesis, including testable consequences of that hypothesis, is a greater determinant of its ultimate utility to the scientific community than is the image resolution available at any given time.     

Geologic and geochemical study of the Picacho gold mine, California: gold in a low-angle normal fault environment

The Picacho gold deposit, located in southeasternmost California, is a low-grade gold deposit in a nearly flat-lying denudational fault of regional extent and probable Oligocene age. The deposit is hosted by intensely fractured and faulted Mesozoic leucogranite and by chloritic augen gneiss and schist, and is overlain unconformably and in fault contact by unmineralized late Oligocene Quechan volcanic rocks. The deposit is structurally characterized by normal and normal-oblique faults of low to high dip at shallow depths in the mine, merging downward with a synchronous, low-dipping ore-stage extensional fault system (the Chocolate Mountains/Gatuna Fault) of probable Oligocene age in deeper portions of the deposit. The fault system was infiltrated during much of its active life by hot, dilute, highly exchanged meteoric water having temperatures of 170°–210° C, salinity <2 wt% NaCl equivalent and calculated δ¹⁸O_fluid between −2.6‰ and 5.2‰. This main-stage fluid precipitated quartz, pyrite, and specular hematite, accompanied by silicification and sericitization. Auriferous ore-stage pyrite was precipitated late in the fault evolution probably by mixing of reducing ore fluid with relatively oxidized main-stage fluid during regional Oligocene extension on the Chocolate Mountains/Gatuna Fault. The Picacho deposit is characterized by a gold–arsenic–antimony geochemical signature consistent with bisulfide complexing of gold in reducing fluid, in contrast with typical denudation fault-hosted base-metal-rich deposits associated with high-salinity fluids elsewhere in the southwestern United States. The deposit is overprinted by Miocene normal faults having a wide range of dips. These postore faults are associated with red earthy hematite precipitation, pyrite oxidation, and supergene enrichment of gold. Editorial handling: L. Meinert