Organic geochemistry of silicified wood,Petrified Forest National Park,Arizona

Lignin derivatives have been isolated for the first time from carbonaceous sections of the silicified (~90% SiO₂) conifer Araucarioxylon arizonicum. The products released by sequential high vacuum pyrolysis and identified by combined gas chromatography-mass spectrometry (GC-MS) include a wide variety of alkyl-substituted, phenolic and condensed aromatic compounds.Brauns spruce lignin was pyrolized and analyzed by GC-MS as a comparison for the fossil wood data. The primary pyrolyzates at the 300°C step were CO₂, H₂O, ethanol and propanol. The main product at 450°C was 4-methyl-2-methoxyphenol (methyl guaiacol), but at 600°C the pyrolyzates were similar both in product composition and in relative abundance to those from silicified wood. The results suggest that the fossil wood experienced a mild thermal event during which the ether bonds were ruptured and loss of oxygen occurred along with the rearrangement of the original wood into a highly stable polymer.     

Determination of the sources and circulation paths of thermal fluids: the Abano region,northern Italy

Water samples from natural springs and artesian wells in the Abano region of northern Italy are characterized by anomalous temperatures and compositions. Concentrations of major components and oxygen isotopes in samples of these fluids have been interpreted in the context of the regional geologic environment, circulation of groundwaters, and reactions between rocks and circulating groundwaters. These considerations define sourceregions and pathlines of the groundwaters.Circulation of fluids in the Abano region is interpreted to be the result of meteoric water infiltration into outcrops of Permian and Mesozoic aquifers in the pre-Alps, which lie north of the Abano region. These aquifers have southerly dips and, therefore, extend under the Abano region at depths between 0.5 and 2.5 km. This aquifer geometry is conducive to forced convection both of aqueous ions derived from the evaporate, limestone and dolomite bearing formations, and of thermal energy along flow paths which extend from the outcrops in the sourceregions to depths of 2 km below the Abano region and upward along high angle faults to thermal springs. Local variation in compositions of water samples is consistent with the mixing of local meteoric waters and formation fluids that were ultimately derived from Alpine sources.     

The opening of the Bay of Biscay - a review

The anticlockwise rotation of the Iberian Peninsula away from south Brittany during the Mesozoic has been demonstrated from palaeomagnetic data. Marine magnetic, seismic and gravity surveys have indicated that there is oceanic crust in the Bay of Biscay. Initial rifting began in the Triassic but the major part of the rotation of the Iberian Peninsula occurred during the Late Cretaceous. Two mechanisms for the opening of the Bay of Biscay have been proposed, firstly a simple anticlockwise rotation of the Iberian plate and secondly, a 350 km sinistral displacement of the Iberian plate along transform faults about a pole of rotation near Paris. Geological data, partly new, favours the first mechanism but with a pole of rotation approximately 100 km east of the west end of the Pyrenees rather than in the southeast corner of the Bay of Biscay. Geophysical data indicates a further small rotation of the Iberian Peninsula during the Late Eocene which resulted in the formation of the Pyrenees.     

Implications of abundant hygroscopic minerals in the Martian regolith

Converging lines of evidence suggest that a significant portion of the Martian surface fines may consist of salts and smectite clays. Salts can form stoichiometric hydrates as well as eutectic solutions with depressed freezing points; clays contain bound water of constitution and adsorb significant quantities of water from the vapor phase. The formation of ice may be suppressed by these minerals in some regions on Mars, and their presence in abundance would imply important consequences for atmospheric and geologic processes and the prospects for exobiology.     

Direct imaging of extra-solar planets with stationary occultations viewed by a space telescope

The feasibility of detecting planets outside the solar system through imaging at optical wavelengths by a telescope in space is considered. The “black” limb of the moon can be used as an occulting edge to greatly reduce the background light from the planet's star. With this technique and if certain other technical requirements can be realized, a hypothetical Jupiter-Sun system could be detected at a distance of 10 pc. For this system, a signal-to-noise ratio of 9 could be achieved in less than 20 min with a 2.4-m telescope in space. For diffraction limited optics, the required integration time is inversely proportional to the fifth power of the telescope aperture. An orbit for the telescope is described that could achieve a stationary lunar occultation of any star that would last nearly two hours, providing six times more integration time than required by the hypothetical Jupiter-Sun example.     

A former asteroidal planet as the origin of comets

The idea of a missing planet between Mars and Jupiter has been with us since the formulation of the Titius-Bode law. The discovery of the asteroid belt in that location led to speculation about a planetary breakup event. Both ideas remained conjectures until Ovenden's finding in 1972, from which it could be derived that the mass of the missing planet was about 90 Earth masses and that its breakup was astronomically recent. Apparently much of that mass was blown out of the solar system during the disruption of the planet. Because of the action of planetary perturbations, only two types of orbits of surviving fragments could remain at present-asteroid orbits and once-around very-long-period elliptical orbits. Objects in the latter type of orbit are known to exist-the very-long-period comets. A large number of these are on elliptical trajectories with periods of revolution of 5 million years; yet they are known to have made no more than one revolution in an orbit passing close to the Sun. By direct calculation it is possible to predict the distribution of the orbital elements of objects moving on long-period ellipses which might have originated in a breakup event in the asteroid belt 5 million years ago. The comet orbits have the predicted distribution in every case where a measure is possible. Some of the distribution anomalies, such as a bias in the directions of perihelion passage, are statistically strong and would be difficult to explain in any other uncontrived way. In addition, a relative deficiency of orbits with perihelia less than 1 AU indicates that the comets must have had small perihelion distances since their origin, rather than that they have been perturbed into small perihelion orbits from a distant “cloud” of comets by means of stellar encounters. The comet orbital data lead to the conclusion that all comets originated in a breakup event in the asteroid belt (5.5±0.6) × 10⁶ years ago. Asteroid and meteoritic evidence can now be interpreted in a way which not only is supportive but also provides fresh insights into understanding their physical, chemical, and dynamical properties. Particularily noteworthy are the young cosmic-ray exposure ages of meteorites, evidence of a previous high-temperature/pressure environment and of chemical differentiation of the parent body, and compositional similarities among comets, asteroids, and meteorites. Certain “explosion signatures” in asteroid orbital element distributions are likewise indicative. Tektites may also have originated in the same event; but if so, there are important implications regarding the absolute accuracy of certain geological dating methods. Little is known about possible planetary breakup mechanisms of the requisite type, though some speculations are offered. In any case, the asteroid belt is an existing fact; and the arguments presented here that a large planet did disintegrate 5 million years ago must be judged on their merits, even in the absence of a suitable theory of planetary explosions.     

Properties of the clouds of Venus,as inferred from airborne observations of its near-infrared reflectivity spectrum

We have measured the shape and absolute value of Venus' reflectivity spectrum in the 1.2-to 4.0-μm spectral region with a circular variable filter wheel spectrometer having a spectral resolution of 1.5%. The instrument package was mounted on the 91-cm telescope of NASA Ames Kuiper Airborne Observatory, and the measurements were obtained at an altitude of about 41,000 feet, when Venus had a phase angle of 86°. Comparing these spectra with synthetic spectra generated with a multiple-scattering computer code, we infer a number of properties of the Venus clouds. We obtain strong confirmatory evidence that the clouds are made of a water solution of sulfuric acid in their top unit optical depth and find that the clouds are made of this material down to an optical depth of at least 25. In addition, we determine that the acid concentration is 84 ± 2% H_2SO4 by weight in the top unit optical depth, that the total optical depth of the clouds is 37.5 ± 12.5, and that the cross-sectional weighted mean particle radius lies between 0.5 and 1.4 μm in the top unit optical depth of the clouds. These results have been combined with a recent determination of the location of the clouds' bottom boundary [Marov et al., Cosmic Res.14, 637–642 (1976)] to infer additional properties about Venus' atmosphere. We find that the average volume mixing ratio of H₂SO₄ and H₂O contained in the cloud material both equal approximately 2× 10^?6. Employing vapor pressure arguments, we show that the acid concentration equals 84 ± 6% at the cloud bottom and that the water vapor mixing ratio beneath the clouds lies between 6 × 10^?4 and 10^?2.