Time series analysis of CO concentrations from an Eastern Kentucky coal fire

Coal fires in natural outcrops, in abandoned and active coal mines, and in coal and coal-refuse piles are responsible for the uncontrolled emissions of gases, including CO, CO₂, H₂S, hydrocarbons, and volatile aromatics. Typically, measurements of gases at a mine vent are made over a short time interval, perhaps no more than 10 min, including the time for replicate measurements. Such timing provides little information on longer-term variations in emissions, although comparisons of seasonal measurements suggest such changes do occur. To address this problem, we placed temperature and CO data loggers in coal fire vents to collect time series measurements for a period of up to three weeks. For one experiment, 11 days of data at one-minute intervals indicated that the CO emissions were generally in the 400–550 ppmv range. However near daily depressions in CO concentrations occurred and in some cases fell below 50 ppmv; followed by an increase to ~ 700–800 ppmv; in turn followed by a return to the ambient conditions. Data for a separate 21-day collection period in a different vent of the same fire exhibited similar trends, albeit at a higher CO concentration. The drop in CO concentration may be associated with a meteorologically-driven inhalation cycle of the fire, whereby air diluted the combustion generated CO. We propose this was followed by an increase in the intensity of the fire due to increased O₂ from the inhaled air, producing increased CO concentrations, before settling back to the ambient conditions.     

Diver-operated piston corer for nearshore use

A diver-operated piston corer suitable for collecting cores of >3 m length from fine-grained nearshore sediment has been developed. The corer uses a platform that rests on the sediment surface supporting both the operators and a derrick that maintains the piston at the sediment-water interface. The core is insected into and recovered from the sediment manually. The technique offers several advantages; low cost, minimal disruption of the sediment-water interface, little compaction of the sediment, the ability to collect longer length cores than is possible with gravity corers, and the ability to be deployed from relatively small boats. Dissolved ammonium and inorganic carbon data are presented from a 3.3-m core collected by this technique from Tomales Bay, California.     

Transient climate changes in a perturbed parameter ensemble of emissions-driven earth system model simulations

We describe results from a 57-member ensemble of transient climate change simulations, featuring simultaneous perturbations to 54 parameters in the atmosphere, ocean, sulphur cycle and terrestrial ecosystem components of an earth system model (ESM). These emissions-driven simulations are compared against the CMIP3 multi-model ensemble of physical climate system models, used extensively to inform previous assessments of regional climate change, and also against emissions-driven simulations from ESMs contributed to the CMIP5 archive. Members of our earth system perturbed parameter ensemble (ESPPE) are competitive with CMIP3 and CMIP5 models in their simulations of historical climate. In particular, they perform reasonably well in comparison with HadGEM2-ES, a more sophisticated and expensive earth system model contributed to CMIP5. The ESPPE therefore provides a computationally cost-effective tool to explore interactions between earth system processes. In response to a non-intervention emissions scenario, the ESPPE simulates distributions of future regional temperature change characterised by wide ranges, and warm shifts, compared to those of CMIP3 models. These differences partly reflect the uncertain influence of global carbon cycle feedbacks in the ESPPE. In addition, the regional effects of interactions between different earth system feedbacks, particularly involving physical and ecosystem processes, shift and widen the ESPPE spread in normalised patterns of surface temperature and precipitation change in many regions. Significant differences from CMIP3 also arise from the use of parametric perturbations (rather than a multimodel ensemble) to represent model uncertainties, and this is also the case when ESPPE results are compared against parallel emissions-driven simulations from CMIP5 ESMs. When driven by an aggressive mitigation scenario, the ESPPE and HadGEM2-ES reveal significant but uncertain impacts in limiting temperature increases during the second half of the twenty-first century. Emissions-driven simulations create scope for development of errors in properties that were previously prescribed in coupled ocean–atmosphere models, such as historical CO₂ concentrations and vegetation distributions. In this context, historical intra-ensemble variations in the airborne fraction of CO₂ emissions, and in summer soil moisture in northern hemisphere continental regions, are shown to be potentially useful constraints, subject to uncertainties in the relevant observations. Our results suggest that future climate-related risks can be assessed more comprehensively by updating projection methodologies to support formal combination of emissions-driven perturbed parameter and multi-model earth system model simulations with suitable observational constraints. This would provide scenarios underpinned by a more complete representation of the chain of uncertainties from anthropogenic emissions to future climate outcomes.     

Extreme peak value vessel response combinations with wide band spectra

An extension is proposed to the standard peak value distribution for time histories possessing wide banded spectra, which allows the distribution of an associated variable to be calculated at the instant that the peak value occurs, the theory is applicable to a wide range of practical circumstances, where it is desired to specify the value of associated response variables at the instant that the dominant response is a maximum. An example is given of the specification of coincident heave and roll of a barge for input to a structural load case analysis.     

Late Pliocene to late Pleistocene environments preserved at the Palisades Site, central Yukon River, Alaska

The Palisades Site is an extensive silt-loam bluff complex on the central Yukon River preserving a nearly continuous record of the last 2 myr. Volcanic ash deposits present include the Old Crow (OCt; 140,000 yr), Sheep Creek (SCt; 190,000 yr), PA (2.02 myr), EC (ca. 2 myr), and Mining Camp (ca. 2 myr) tephras. Two new tephras, PAL and PAU, are geochemically similar to the PA and EC tephras and appear to be comagmatic. The PA tephra occurs in ice-wedge casts and solifluction deposits, marking the oldest occurrence of permafrost in central Alaska. Three buried forest horizons are present in association with dated tephras. The uppermost forest bed occurs immediately above the OCt; the middle forest horizon occurs below the SCt. The lowest forest bed occurs between the EC and the PA tephras, and correlates with the Dawson Cut Forest Bed. Plant taxa in all three peats are common elements of moist taiga forest found in lowlands of central Alaska today. Large mammal fossils are all from common late Pleistocene taxa. Those recovered in situ came from a single horizon radiocarbon dated to ca. 27,000 ¹⁴C yr B.P. The incongruous small mammal assemblage in that horizon reflects a diverse landscape with both wet and mesic environments.     

Lamellar structures in low-calcium orthopyroxenes

Clinoenstatite lamellae are found to be distributed in three distinct patterns that define three microstructural types. There are regions of the crystal devoid of lamellae and these correspond to ordered or O-orthopyroxene. When the lamellae are present but not in any periodic arrangement, disordered or D-orthopyroxene is identified. In some areas, the lamellae are spaced periodically and these are regions of “superlattice” orthopyroxene. These microstructural types explain all previous X-ray results on orthopyroxenes. Microstructural differences between low and high calcium orthopyroxenes are discussed.     

A lithological assessment of the resistivity data acquired during the airborne geophysical survey of Anglesey,North Wales

A recent airborne geophysical survey has provided high resolution estimates of the electrical resistivity of the near-surface and deeper (bedrock) formations found across Anglesey and a portion of the coastal area of North Wales. This single small survey provides new geophysical information on both the complex configuration of the Neoproterozoic and Cambrian bedrock units and the shallow near-surface geology and glacial features.     

Tectonic evolution of Northeastern Siberia and adjacent regions

Previous models for the tectonic evolution of northeastern Siberia have proposed the existence of a Kolyma plate composed of the Kolyma and Omolon massifs of presumed Precambrian age. Lithologic similarities between the Siberian platform and the Cherskiy Mountains and the presence of oceanic and island arc type deposits in the Kolyma-Indigirka interfluve suggest that no such plate exists. The eastern margin of the Siberian plate is suggested to lie along a line between the Ulakhan Sis Range, the Alazeya uplift and the Arga Tas Range; the Cherskiy Mountains and the Verkhoyansk fold belt are parts of the Siberian plate. The Paleozoic deposits of the Omolon massif are unlike those found in the Cherskiys or Siberia. Paleomagnetic data from the Omolon massif are discordant from data from Siberia. It is suggested that the Omolon massif represents a microplate which accreted onto Siberia in the Jurassic. Ophiolites in central Chukotka are of the same emplacement age as in the western Brooks Range and may have been emplaced at the initiation of the rotation of Arctic Alaska. Geometric and limited stratigraphic data suggest that the East Siberian Sea may be floored by oceanic crust left by an incomplete closure between Arctic Alaska, Siberia and Omolon. The tectonic position of the Prikolymsk massif remains ambiguous.     

Late Ordovician stratigraphy northwest of the Sugarloaf,mid-Wales — a discussion

Several modifications are proposed to the Ordovician stratigraphy recently proposed by Mackie and Smallwood (1987), based in particular on the recognition of a major Mynydd Trawsnant anticline on the northwest flank of the Tywi structure and on field relationships indicating the Foel Formation directly to overlay the Caradoc black shale succession and directly to underlay the Craig Las Formation. The Clyn Glas Formation is suggested to have accumulated at a slope base rather than a shelf–slope break.     

Coal resources,production, and quality in the Eastern kentucky coal field: Perspectives on the future of steam coal production

The Eastern Kentucky coal field, along with adjacent portions of Virginia and southern West Virginia, is part of the greatest production concentration of high-heating-value, low-sulfur coal in the United States, accounting for over 27% of the 1993 U.S. production of coal of all ranks. Eastern Kentucky's production is spread among many coal beds but is particularly concentrated in a limited number of highquality coals, notably the Pond Creek coal bed and its correlatives, and the Fire Clay coal bed and its correlatives. Both coals are relatively low ash and low sulfur through the areas of the heaviest concentration of mining activity. We discuss production trends, resources, and the quality of in-place and clean coal for those and other major coals in the region.