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81.
Framvaren, a super-anoxic fjord in southern Norway, contains 7–8 mmoll−1 of sulphide and a total carbonate concentration of 18.5 mmol kg−1 in the bottom water. The chemistry of calcium has been studied, considering sources, biogenic and chemical processes and sedimentary sinks. Calcium associated with the bacteria biomass at the redox interface (18m depth) appears to be the primary source of dissolved calcium in the deep, anoxic water. Excess calcium and high total carbonate cause supersaturation of calcite, which is precipitated chemogenically. Calcite (and presumably some aragonite) is identified both in sediment trap material and the bottom sediments below the depth of supersaturation. 相似文献
82.
James G Wilson 《Marine environmental research》1983,8(3):129-148
The concentration of Ni in C. edule ranges from 17·8 μg/g to 53·82 μg/g with the highest concentration in the gills and mantle and the lowest in the foot and adductor muscles. The concentration does not change with either size or season.There is no significant increase in mortality even in the highest Ni concentration (100 μg/litre), nor is body condition correlated with experimental Ni concentrations. The rate of uptake of Ni (y) is described by the equation: where x1 = Ni concentration (μg/litre) and x2 = time (h).The respiration rates did not significantly change up to the highest Ni concentration used (1000 μg/litre).It is postulated that the main pathway for Ni uptake is through the gills, possibly through mucus sheet or transmembrane absorption, with a secondary uptake route via the viscera.C. edule may therefore be a suitable indicator species for Ni. 相似文献
83.
To improve resolution of seismic-reflection profiles in continental slope water depths of 900 to 1500 m, a single hydrophone
was towed about 150 m off the bottom to receive reflected signals from a surface-towed sparker sound source. That deep-towed
hydrophone data show that valleys which appear V-shaped in records from a surface-towed hydrophone are flat-bottomed, and
that subbottom reflections from an erosional unconformity can be much better resolved. The data produced by this technique
are very hepful when used in conjunction with records from conventional surface-towed seismic-profiling equipment. 相似文献
84.
85.
James N. Butler 《Marine Chemistry》1975,3(1):9-21
The rate of evaporative weathering of a component of crude oil residue is assumed to be proportional to its equilibrium vapor pressure and to the amount remaining in the sample. This model is tested using literature data on normal paraffin profiles of crude oil weathered artificially and gas chromatographic data on crude oil residues weathered on rocky shores. Semiquantitative agreement over the time range from 1 to 400 days is demonstrated. Application of the model to gas chromatograms of pelagic tar lumps collected at Station S near Bermuda in 1972 implies that most of these lumps were formed by fragmentation of much larger and older masses, some within less than one day of the time they were collected. The weathering of pelagic tar thus involves a great deal more physical fragmentation than was previously supposed. 相似文献
86.
Concentrations of total recoverable inorganic tin (TRISn), monomethyltin (MeSn3+), dimethyltin (Me2Sn2+), trimethyltin (Me3Sn+) and (3-dimethylsulphonio)propionate (DMSP) were determined in leaves of Spartina alterniflora from three sites in the Great Bay estuary (NH) from 8 May to 15 September 1989. Total methyltin concentration increased from 8·9 ng g−1 (fresh weight) on 8 May to 472 ng g−1 on 23 May, decreased to 52 ng g−1 on 7 June and 16ng g−1 on 20 June, and remained low until the last sample on 18 September. Statistical calculations showed that methyltin concentrations varied significantly with sampling week, but not with site. DMSP concentrations showed very different behaviour. During the same sampling period DMSP concentrations varied only from 7·5 to 26 μmol g−1 (fresh weight). DMSP concentrations varied significantly for site, but not sampling week. 相似文献
87.
The mechanical cable is an essential element in towing operations, remote control of equipment, salvage operations, civil engineering applications, etc.Failure of these cables can result in loss of life and loss of equipment worth hundreds of thousands of dollars. Obviously then, sensors that can indicate the condition of these cables so that the risk to their continued use and their remaining safe life can be determined when in operation are very important from the point of view of commercial and military interest.This paper presents a brief review of research into failure mechanisms of various cables and the acoustic emission signatures of the various cables under simulated loading. The development of a specific operational monitor for a towed cable system is also given. 相似文献
88.
89.
Distribution of dissolved species and suspended particulate copper in an intertidal ecosystem affected by copper mine tailings in Northern Chile 总被引:1,自引:0,他引:1
The coastline near Chañaral in Northern Chile is one of the most highly Cu-contaminated zones in the world due to discharges from mining activities for more than 60 years. The speciation of Cu has been studied to determine the importance of organic complexation in highly contaminated areas, and to assess the likely physiological impacts of Cu on marine organisms. Dissolved Cu concentrations of up to 500 nM were measured, completely saturating organic ligands and leading to free Cu2+ concentrations in excess of 10− 8 M. These values are higher than those reported in any other marine environment, and because they occur over an extensive area, provide a unique opportunity to study the effects of Cu on marine ecosystems and to see how Cu behaves when its speciation is predominantly inorganic. We found strong gradients in free Cu2+ between Chañaral and adjacent areas with lower Cu, where speciation is dominated by organic complexation. There is also a significant increase in the partitioning of Cu onto suspended particles in the contaminated areas, consistent with previous studies that showed that organic ligands stabilize Cu in the dissolved phase, whilst “excess” Cu is rapidly scavenged. Those high dissolved Cu concentrations persist in spite of solid phase partitioning and advective processes along this open-ocean coastline, suggesting that Cu inputs into the system are still very large. Measurements were made using anodic stripping voltammetry with a thin mercury film coated with Nafion, which previous workers have shown can mitigate ambiguity in the data arising from inadvertent reduction of organic complexes. Our findings suggest that this is a useful methodology for contaminated systems. 相似文献
90.
Multi-proxy evidence of long-term changes in ecosystem structure in a Danish marine estuary, linked to increased nutrient loading 总被引:3,自引:0,他引:3
Marianne Ellegaard Annemarie L. Clarke Nina Reuss Simon Drew Kaarina Weckstrm Stephen Juggins N. John Anderson Daniel J. Conley 《Estuarine, Coastal and Shelf Science》2006,68(3-4):567
This paper presents a study of changes in eutrophication over the past 100 years in a fertile estuary. The Danish estuary Mariager Fjord is a long, narrow sill-fjord with a permanently anoxic basin. In 1997 anoxia spread from the basin to the entire inner estuary, killing almost all eukaryotes and prompting debate on the causes. This paper reports a multi-proxy survey of 210Pb-dated sediment cores from the anoxic basin. Analyses of diatoms, dinoflagellates, pigments and geochemical proxies were used to determine changes in ecosystem structure over the past 100 years. The aim was to establish ‘base-line conditions’, for management purposes, of the biological structure prior to 1900, and to examine possible causes of changes observed. Geochemical proxies total nitrogen (TN), total carbon (TC) and biogenic silica (BSi) were consistently high throughout the sediment record. Increased concentrations of pigments and natural isotopes (δ13C, δ15N) suggested increasing production and nutrient loading. The main changes in the biological proxies occurred between 1915 and the 1940s, and indicated that the estuary has been somewhat eutrophic since 1900, but that the eutrophication process increased over the past 100 years. A reconstruction of TN concentration by a diatom-based transfer function supports this interpretation, with inferred TN ca. 1900 around 60 μmol l−1, and an increase in TN concentration over the past century to ca. 130 μmol l−1 by 1995. Inferred TN decreased to ca. 100 μmol l−1 by 2001, similar to present day monitoring data. 相似文献