Arsenic incorporation in a salt marsh ecosystem

Replicate portions of a Delaware salt marsh were enclosed in cylindrical microcosms and exposed to elevated levels of inorganic arsenic (arsenate). All biotic and abiotic components in dosed cylinders rapidly incorporated arsenic. Spartina blades showed the greatest arsenic enrichment, with dosed plants incorporating arsenic concentrations an order of magnitude higher than controls. Spartina detritus and sediments also exhibited greatly elevated arsenic concentrations. Virtually all of the arsenic was incorporated into plant tissue or strongly sorbed to cell surfaces. Thus, elevated arsenic concentrations in estuarine waters will be reflected in living and non-living components of a salt marsh ecosystem, implying that increased arsenic will be available to organisms within the marsh ecosystem.     

Preliminary observations of oxygen and carbon dioxide of the wintertime Bering Sea marginal ice zone

Wintertime oxygen and pH profiles across the marginal ice zone of the central and southeastern Bering Sea shelf are analyzed and compared with summer data. During the winter, at water depths shallower than 75 m, the water column is homogeneous and near freezing. Between the 75- and 200-m isobaths the structure is essentially two-layered, a cool and fresh upper layer overlying a warmer, more saline bottom layer. The oxygen concentration in the surface mixed layer is higher than the summer values, but the degree of saturation is lower because of the lower temperature in winter. The oxygen degree of saturation in the bottom mixed layer on the shelf in winter are higher than in the surface water in winter and the bottom water in summer.In summer the oxygen and carbon dioxide data show extreme variability governed primarily by biological processes. Winter oxygen and pH data, however, do not scatter as much as the summer data and indicate conservative mixing of several sub-surface water masses. The surface water is undersaturated in both oxygen and carbon dioxide and seems to absorb oxygen, but little carbon dioxide, from the atmosphere.Two stations were occupied in the Aleutian Basin. The homogeneous surface layer has the same oxygen and pH values as in the minimum temperature layer observed in the summer by other investigators at the same location. The result substantiates the hypothesis of early investigators that the summer minimum temperature layer is the remnant local winter water. All winter surface waters sampled are undersaturated with respect to oxygen, suggesting that the input of oxygen through the air-sea exchange does not keep up with the rate of upwelling and cooling, which reduces the degree of oxygen saturation. Surface carbon dioxide is also undersaturated because of cooling. The maximum temperature layer at these two Aleutian Basin stations is warmer, fresher, and contains more oxygen, but less carbon dioxide, than in the summer, suggesting advective input of some nonlocal seawater.     

Upwelling and river runoff as sources of dissolved nitrous oxide to the Alsea estuary,Oregon

Surface waters of Alsea Bay, an unpolluted estuary on the Oregon coast, were analysed for nitrous oxide, nitrate and nitrite on a weekly or biweekly basis during the summer of 1979. The estuary was found to be a variable source of N₂O to the atmosphere. Large and rapid increases in the concentrations of N₂O, NO₃^?, and NO₂^? occurred at the beginning of the sampling period and are attributed to the influx of nutrient-rich upwelling water into the estuary with the tide. The subsequent decline in concentrations of nitrate, nitrite and nitrous oxide over the remainder of the summer is attributed to a decrease in upwelling intensity, a decline in nitrification rates and to assimilatory nitrate reduction. Measurements of nitrous oxide at six stations along the Alsea River were also made in September and October before and after the onset of the rainy season. Samples taken after flood conditions were established were systematically 50% higher than pre-flood samples. The data suggest that soil runoff results in elevated concentrations of N₂O in rivers.     

Kinetic studies of lead(II) uptake by the seagrass Zostera muelleri in water by radiotracing,atomic absorption spectrometry and electrochemical techniques

Evidence was found that uptake of lead from seawater in both model and natural systems by the leaves of the seagrass Zostera muelleri does occur for live, dead and scraped leaves at all the lead concentrations tested. Positive uptake of lead was measured using the three analytical techniques of radio-tracer, differential pulse anodic stripping voltammetry and atomic absorption spectrometry; similar uptake profiles were obtained for each technique. Profiles always showed an initial rapid uptake phase followed by a gradual transition to a plateau phase at which an approximate equilibrium between lead attached to seagrass and free ionic lead in seawater was reached. The presence of active lead uptake processes was indicated in experiments which attempted to remove lead from leaves by a chelating agent.     

Massless scalar field in Robertson-Walker space-time

Recently, exact spatially-homogeneous solutions have been found for a conformally invariant massless scalar fieldS(t) coupled to a Robertson-Walker geometry. We investigate extending these solutions to inhomogeneous scalar fieldsS(t, x ^l ). For an isotropic scalar fieldS(t, r) we find a solution satisfying three of the five field equations. If we use REDUCE, we show that the remaining equations forceS=S(t).     

Relationships between Campi Flegrei and Mt. Somma volcanism: evidence from melt inclusions in clinopyroxene phenocrysts from volcanic breccia xenoliths

Summary We present compositions of reheated melt inclusions in clinopyroxene phenocrysts from three mafic xenoliths in Breccia Museo, Campi Flegrei, Italy. Melt inclusion compositions are remarkably different from the compositions of known contemporary Campi Flegrei lavas, being significantly enriched in K₂O and depleted in Na₂O. Some differences are also evident in FeO^* (total Fe as FeO) and TiO₂ contents. The clinopyroxene phenocrysts could not have crystallised from Campi Flegrei magmas. We suggest that they originated from a volcanic system genetically very similar to, and possibly linked with, the >14 ka volcanic system of Mt. Somma, another Campanian volcano ∼ 30 km east from Campi Flegrei, from which Vesuvius subsequently developed. This result indicates a close relationship (or link) between the two volcanic systems which have until now been considered separate. We speculate that the link was established prior to eruption of the Neapolitan Yellow Tuff (NYT) (∼ 12 ka). The xenoliths were derived from a volcanic system older than the host breccias themselves. We suggest that this older volcanism had close similarities with the volcanism of the older products of Mt. Somma (∼25 ka). Received March 20, 2000; accepted November 2, 2000     

What type was SN 1987A?

A comparison is made of the light and colour curves of the SN 1987A in the first 280 days with the mean properties of type II supernovae. The conclusion is that even though it has H lines, and was not a typical type II supernova, but a peculiar object from a photometric point of view. The implications for inclusion of SN 1987A in the context of the usual Minkowski-Zwicky classification are explicitly discussed.