Effect of heat treatment on dynamic properties of selected rock types taken from the Salt Range in Pakistan

Temperature is one of the variables that influence the elasto-plastic behavior and integrity of rock outcrops. Fluctuations in temperature can trigger alteration of some of the mineral properties and impact the brittle-plastic transition. Initiation and propagation of thermally induced tension cracks tend to weaken most rock types. The principal goal of this study was to anticipate impacts of thermal stress-strain cycles on the dynamic response of representative rock units exposed in the Khewra Gorge of the Salt Range Punjab of Pakistan. Ten types of sedimentary rock units were sampled, including marl, dolomite, three types of limestone, and five different sandstones exhibiting varying characteristics in outcrop. Boulder specimens were collected from the field and transported to the laboratory to prepare 50 drill cores that could be subjected to thermal cycling between 50 and 200 °C in increments of 50 °C. Room temperature core samples were tested using an Erudite resonance frequency meter to measure their Q-factors and the resonance frequency (F_r) at an applied loading frequency of 7 KHz with 0.01 V output voltage. Results suggest that thermal cycling tends to reduce the dynamic Young’s modulus (E_d) and Q-factor. Other parameters, such as damping ratio (ξ), specific damping capacity (Ψ), and loss factor (?) appeared to increase with increasing temperature cycles, likely as a result of developing thermally induced tensile fractures. The resultant values of the null hypothesis (t-critical and t-stats) suggests that the null hypothesis can be discarded because there was no observable difference between the measured and expected values for the cores tested. The observations and data emanating from this study might be useful in designing low-level radioactive waste landfills, nuclear waste repositories, and deep underground excavations where the increased temperature could alter the mechanical behavior of the parent rock mass.     

Assessment of the reliability of supervised classifications of Landsat-7, ASTER,and SPOT-5 multispectral data in rock unit discriminations of Jabal Daf-Wadi Fatima area,Saudi Arabia

Multispectral, multiresolution remotely sensed data were processed to emphasize geological interpretation of Jabal Daf-Wadi Fatima area. The investigated area is situated in the central western part of Saudi Arabia and geologically consists of igneous and metamorphosed rocks overlain by sedimentary sequence belonging to the Arabian-Nubian Shield. Three sets of digital satellite data, Landsat-7 ETM+, ASTER, and SPOT-5, were used in this study. The application of image processing techniques enables to identify and delineate the lithologic units and the structural features of the study area. The results of this study indicate that the confusion matrix of the three maximum likelihood supervised classifications of the three datasets shows that the Landsat ETM+ bands scored the best degree of average and overall accuracy (77 and 78%, respectively). This classification distinguishes most of the rock units for mapping in the investigated area. The supervised classification of ASTER and SPOT bands has lower degrees of accuracy than the classified Landsat data. The supervised classification of SPOT bands has a degree of average and overall accuracy of 66 and 67%, respectively, but it is the best for distinguishing the spectral signatures of the different members of Fatima Formation (lower, middle, and upper members). The statistical analyses of the confusion matrices of classifications and the interpretation of the produced classified thematic maps revealed that the classification accuracy does not necessary depend on the spatial resolution of satellite data. The data of the highest spatial resolution such as SPOT data are also very useful in emphasizing and classifying the rock units of a small outcrop area. The detailed geological map of Jabal Daf-Wadi Fatima area is interpreted in this work from supervised classified images of different resolutions as well as the structure map of this area. This study shows that it is preferable to use the supervised classifications of multiresolution data for rock unit discrimination in detailed field mapping.     

Structural properties of Urfa stone doped with erbium oxide

In this study, we investigated the structural properties of Urfa stone (US) doped with erbium oxide (Er₂O₃). Solid US was powdered by using an agate mortar, and its elemental composition was determined using inductive coupling plasma (ICP) methods. Varying amounts of Er₂O₃ (5, 10, 20, 30, and 40%) were added as a dopant to the US powder using mechanical alloying methods. The resultant samples were sintered at 1000 °C for 1 h. The structural properties of the Er₂O₃-doped US samples were subsequently investigated using X-ray diffraction (XRD), Fourier-transform infrared spectrometry (FTIR), and photoluminescence methods. Results from the XRD analysis of the Er₂O₃-doped US powder indicated two crystalline phases: (1) calcium oxide (CaO) or lime and (2) Er₂O₃. After the samples were sintered at 1000 °C, CaO, Er₂O₃, calcium carbonate (CaCO₃), and mixed crystalline phases were observed. Results from the FTIR analysis of the Er₂O₃-doped US samples indicated absorption bands at 711.91, 872.08, and 1396.87 cm^?1 in the spectra. Finally, photoluminescence analysis results indicated a shift in the emission and excitation bands to longer and shorter wavelengths, respectively, in the solid state (non-aqueous media) US-Er complex.     

Geospatial assessment of soil erosion intensity and sediment yield: a case study of Potohar Region,Pakistan

Estimation of spatial extent of soil erosion, one of the most serious forms of land degradation, is critical because soil erosion has serious implications on soil fertility, water ecosystem, crop productivity and landscape beauty. The primary objective of the current study was to assess and map the soil erosion intensity and sedimentation yield of Potohar region of Pakistan. Potohar is the rainfed region with truncated and complex topography lying at the top of the Indus Basin, the world’s largest irrigation networks of canals and barrages. Spatially explicit Revised Universal Soil Loss Equation (RUSLE) Model integrated with Remote Sensing-GIS techniques was used for detecting/mapping of erosion prone areas and quantification of soil losses. The results show that the Potohar region is highly susceptible to soil erosion with an average annual soil loss of 19 tons ha^?1 year^?1 of which the maximum erosion (70–208 tons ha^?1 year^?1) was near the river channels and hilly areas. The sediment yield due to the erosion is as high as 148 tons ha^?1 year^?1 with an average of 4.3 tons ha^?1 year^?1. It was found that 2.06% of the total area falls under severe soil erosion, 13.34% under high erosion, 15.35% under moderate soil erosion while 69.25% of the area lies in the low (tolerable) soil erosion. Chakwal and Jhelum districts of the region are seriously affected by erosion owing to their topography and soil properties. The information generated in this study is a step forward towards proper planning and implementation of strategies to control the erosion and for protection of natural resources. It is, hence, necessary that suitable water harvesting structures be made to control water to prevent soil erosion and provision of water in the lean season in this region. Tree plantation and other erosion control practices such as strip cropping can also minimize soil erosion in this region.     

Efficacy of laser cleaning in the removal of biological patina on the volcanic scoria of the rock-hewn churches of Lalibela,Ethiopia

The Lalibela rock-hewn churches are one of the most important religious pilgrimage sites in Ethiopia. These churches are carved from the scoriaceous basalt rock substrate, which has been exposed to attack by biological agents with significant loss of surface material. Particularly, the widespread growth of lichens and other microorganisms on the carved surfaces of the churches has proven to represent a substantial threat for the preservation of the site. In this study, laboratory tests have been conducted to assess the feasibility of using laser technology as an efficient cleaning method of biological patina from polymineralic stone substrates. Multi-analytical techniques were applied for the characterization of the stone samples collected from two of the Lalibela churches: Bete Giyorgis and Bete Amanuel. Stone samples artificially inoculated with bacteria, yeast, fungi isolates, and lichen-encrusted samples were laser cleaned using UV and IR laser wavelengths. The high content of Fe and Ti oxides and the high porosity have made the stone surfaces easily susceptible to low-energy laser treatment. Results indicate that laser cleaning can be applied to polymineralic lithotypes and UV irradiation can successfully remove lichen colonies. Further studies need to be conducted to optimize the laser procedure in polymineralic, high porosity stones.     

Chinese overseas industrial parks in Southeast Asia: An examination of policy mobility from the perspective of embeddedness

The development of overseas industrial parks is a key component of the Belt and Road Initiative and an expected experimental way of promoting inclusive globalization by inventing new forms of cooperation between China and local host countries. Policy mobility, a classic theory within international political geography addressing the connection between local and global policies, has implications for overseas industrial parks development. In this paper, we argue that policies are not easily moved directly from one place to another; instead, policies are embedded due to the role of local actors in policy mobility. This article first provides an overview of seven China-Southeast Asia economic and trade cooperation zones identified by the Ministry of Commerce, and analyzes their key participants. It then discusses policy mobility by looking into the roles of revenue, land, and talent in developing these industrial parks. The paper finds that these parks face challenges, such as the complicated geographical environments of host countries, huge pressure from enterprise investment capital, the lack of overseas service platforms, and underdeveloped agglomeration economies. In the light of the current situation, policy suggestions for the future sustainable development of overseas industrial parks are put forward.     

Geothermal energy potential of Tulsishyam thermal springs of Gujarat,India

Tulsishyam thermal springs are located in the Saurashtra region of Gujarat, India with discharge temperatures varying from 39 to 42 °C. The pH of these thermal springs varies from 7.1 to 7.4, indicating neutral character. Though these thermal springs propagate through the near surface layer of Deccan basalt, detailed geochemical analysis of the thermal waters using Piper diagram suggests that the water is interacting with the granitic basement rock. Silica and cation geothermometry estimates have reservoir temperature in the range of 138 to 207 °C categorizing it into a low to moderate enthalpy geothermal system. Furthermore, the area has high heat flow values of 53–90 mW/m² because of shallow Moho depth. The prevailing conditions suggest that the geothermal energy can potentially be exploited through an enhanced geothermal system (EGS). The study also indicates different mineral phases that may precipitate out of water during exploitation of geothermal energy and it should be taken into account while designing an EGS for the area.     

Seismic behavior of self-centering reinforced concrete wall enabled by superelastic shape memory alloy bars

Reinforced concrete (RC) wall is a common type of structural component used in high-rise buildings to resist lateral loads induced by earthquakes. RC walls are typically designed and detailed to dissipate energy through significant inelastic responses to meet expected seismic performance under moderate-to-strong earthquakes. However, costly repair or even demolition caused by excessive residual deformation is usually inevitable. Given this deficiency, this study investigates the feasibility of utilizing superelastic shape memory alloy (SMA) bars to achieve self-centering (SC) RC walls. Under this condition, the residual deformation of SC–RC walls is reduced by superelastic SMA with large recoverable strain and remarkable fatigue properties. The mechanical properties of superelastic nickel–titanium bars and SC–RC wall design are described. A numerical SC–RC wall model is developed and validated by comparing the test results. Parametric studies of SC–RC wall systems are then conducted to investigate the effects of axial compressive load ratio, bottom slit length, and lower plateau stress factor of SMA. Results show that the proposed SC–RC walls have excellent SC ability and moderate energy dissipation capacity. The damage regions and levels of the SC–RC wall systems are also discussed.