大别山双河和碧溪岭超高压变质岩流体包裹体研究

对大别山双河和碧溪岭含柯石英榴岩和硬玉石英岩进行了详细的流体包裹体研究。根据流体包裹体的成分和盐度的不同,可以划分出至少五种类型不同的气液包裹体;（１）Ｎ２包裹体;（３）高盐度流体包裹体;（３）ＣＯ２包裹体;（４）ＣＯ２－Ｈ２Ｏ包裹体;（５）低盐度流体包裹体。本仅见于含柯石英榴辉岩,而高盐度流体包裹体则几乎存在于所有的榴辉岩和硬玉石英岩中。ＣＯ２包裹体沿榴辉岩中微剪切带分布,或存在于强变形的硬玉石     

Analysis of the interannual variability of annual daily extreme water levels in the St Lawrence River and Lake Ontario from 1918 to 2010

We compared the interannual variability of annual daily maximum and minimum extreme water levels in Lake Ontario and the St Lawrence River (Sorel station) from 1918 to 2010, using several statistical tests. The interannual variability of annual daily maximum extreme water levels in Lake Ontario is characterized by a positive long‐term trend showing two shifts in mean (1929–1930 and 1942–1943) and a single shift in variance (in 1958–1959). In contrast, for the St Lawrence River, this interannual variability is characterized by a negative long‐term trend with a single shift in mean, which occurred in 1955–1956. As for annual daily minimum extreme water levels, their interannual variability shows no significant long‐term change in trend. However, for Lake Ontario, the interannual variability of these water levels shows two shifts in mean, which are synchronous with those for maximum water levels, and a single shift in variance, which occurred in 1965–1966. These changes in trend and stationarity (mean and variance) are thought to be due to factors both climatic (the Great Drought of the 1930s) and human (digging of the Seaway and construction of several dams and locks during the 1950s). Despite this change in means and variance, the four series are clearly described by the generalized extreme value distribution. Finally, annual daily maximum and minimum extreme water levels in the St Lawrence and Lake Ontario are negatively correlated with Atlantic multidecadal oscillation over the period from 1918 to 2010. Copyright © 2013 John Wiley & Sons, Ltd.     

On the computation of the electrical potential inside a horizontally‐layered half‐space

A new formulation is proposed for the electrical potential developed inside a horizontally‐layered half‐space for a direct current point‐source at the surface. The recursion formula for the kernel coefficient in the potential integral is simpler than the generally used two‐coefficient recursion. The numerical difficulties that may occur during the computation of the integrals and near the source axis are examined and solutions are proposed. The set of equations permits a stable and accurate computation of the tabular potential everywhere in the medium.     

Evidence of a Mixed-Layer Dynamics Contribution to the Entrainment Process

The internal thermal boundary layer developing over the Mediterranean during a cold-air outbreak associated with a Tramontane event has been studied by means of airborne lidar, in situ sensors, and a modelling approach that consisted of nesting the University of Washington (UW) planetary boundary-layer (PBL) model in an advective zero-order jump model. This approach bypasses some of the deficiencies associated with each model: the absence of the dynamics in the mixed layer for the zero-order jump model and the lack of an inversion at the PBL top for the UW PBL model. Particular attention is given to the parameterization of the entrainment flux at the PBL top. Values of the entrainment closure parameter derived with the model when matching PBL structure observations are much lower than those derived with standard zero-order jump models. They also are in good agreement with values measured in different meteorological situations by other studies. This improvement is a result of the introduction of turbulent kinetic energy production in the mixed layer.     

A Time Monte Carlo method for addressing uncertainty in land-use change models

One of the main objectives of land-use change models is to explore future land-use patterns. Therefore, the issue of addressing uncertainty in land-use forecasting has received an increasing attention in recent years. Many current models consider uncertainty by including a randomness component in their structure. In this paper, we present a novel approach for tuning uncertainty over time, which we refer to as the Time Monte Carlo (TMC) method. The TMC uses a specific range of randomness to allocate new land uses. This range is associated with the transition probabilities from one land use to another. The range of randomness is increased over time so that the degree of uncertainty increases over time. We compare the TMC to the randomness components used in previous models, through a coupled logistic regression-cellular automata model applied for Wallonia (Belgium) as a case study. Our analysis reveals that the TMC produces results comparable with existing methods over the short-term validation period (2000–2010). Furthermore, the TMC can tune uncertainty on longer-term time horizons, which is an essential feature of our method to account for greater uncertainty in the distant future.     

Record of enhanced late Pliocene tectono‐volcanic activity in the Lesser Antilles forearc basin: Insights into the long‐term behaviour of the Lesser Antilles subduction zone

In this study, we investigate the Lesser Antilles forearc basin, focusing on the late Pliocene to Pleistocene sedimentary archives in order to track the occurrence of extreme events triggered by enhanced subduction‐related tectono‐volcanic activity. We identify late Piacenzian deposits covering a major regional erosional surface, displaying sedimentary dykes and large marine boulders embedded in a mixed continental–marine matrix, characteristic of tsunamites. We interpret this episode of platform emersion and the successive cataclysmic deposits as resulting from enhanced tectonic activity at the interface of the subduction zone, synchronous with the initiation of the Lesser Antilles volcanic arc. We then discuss the implications in terms of the mechanical behaviour of the Lesser Antilles subduction zone.     

An X-ray absorption fine structure and nuclear magnetic resonance spectroscopy study of gallium-silica complexes in aqueous solution

The influence of aqueous silica on gallium(III) hydrolysis in dilute (2 × 10⁻⁴ ≤ m_Ga ≤ 5 × 10⁻³) and moderately concentrated (0.02 ≤ m_Ga ≤ 0.3) aqueous solutions was studied at ambient temperature, using high resolution X-ray absorption fine structure (XAFS) and nuclear magnetic resonance (NMR) spectroscopies, respectively. Results show that, in Si-free acidic solutions (pH < 3), Ga is hexa-coordinated with oxygens of H₂O molecules and/or OH groups in the first coordination sphere of the metal. With increasing pH, these hydroxyl groups are progressively replaced by bridging oxygens (-O-), and polymerized Ga-hydroxide complexes form via Ga-O-Ga chemical bonds. In the 2.5-3.5 pH range, both XAFS and NMR spectra are consistent with the dominant presence of the Ga₁₃ Keggin polycation, which has the same local structure as A1₁₃. Under basic pH (pH > 8), Ga exhibits a tetrahedral coordination, corresponding to Ga(OH)₄⁻ species, in agreement with previous NMR and potentiometric studies. Major changes in Ga hydrolysis have been detected in the presence of aqueous silica. Ga is tetra-coordinated, both in basic and acid (i.e., at pH > 2.7) Si-bearing solutions (0.01 ≤ m_Si ≤ 0.2), and forms stable gallium-silicate complexes. In these species, Ga binds via bridging oxygen to 2 ± 1 silicons, with an average Ga-Si distance of 3.16 ± 0.05 Å, and to 2 ± 1 silicons, with an average Ga-Si distance of 3.39 ± 0.03 Å. These two sets of Ga-Si distances imply the formation of two types of Ga-silicate aqueous complex, cyclic Ga-Si_2-3 species (formed by the substitution of Si in its tri-, tetra- or hexa-cyclic polymers by Ga atoms), and chainlike GaSi_2-4 species (similar to those found for A1), respectively. The increase in the number of Si neighbors (a measure of the complex concentration and stability), in alkaline media, with increasing SiO₂(aq) content and decreasing pH is similar to that for A1-Si complexes found in neutral to basic solutions. At very acid pH and moderate silica concentrations, the presence of another type of Ga-Si complex, in which Ga remains hexa-coordinated and binds to the silicon tetrahedra via the GaO₆ octahedron corners, has also been detected. These species are similar to those found for Al³⁺ in acid solutions. Thus, as for aluminum, silicic acid greatly hampers Ga hydrolysis and enhances Ga mobility in natural waters via the formation of gallium-silicate complexes.     

Calculations of activity-composition relations in multi-site solid solutions: the example of AB2O4 spinels

A model to calculate activities in multisite solutions like spinels, from a general expression of the Gibbs free energy is developped. The free energy is written as that of a solution with ideal mixing of cations on each sublattice corrected by any suitable higher order terms. It is shown that activities of i^th end-member can be simply written: $${\text{act (}}i{\text{) = (}}\gamma _i {\text{/}}\gamma _i^{\text{0}} {\text{)}}\mathop \prod \limits_j (N_j /N_j^0 )^{P(j,{\text{ }}i)} .$$ N _j are site occupancy fractions; the γ _i are equal to one for the ideal multisite model and depend only on the higher order corrections to this model; ⁰ indicate values for the i ^th end member. The exponents in the matrix P are integers and constants. The activities cannot be expressed explicitly as function of the macroscopic composition. The site occupancy fractions which minimize the Gibbs free energy must be calculated first solving a set of non linear equations which define the internal equilibrium conditions. The (Fe²⁺, Mg) (Al, Cr, Fe³⁺) spinel are used to illustrate these calculations. For multicomponent AB₂O₄ spinels activity expressions derived for the reference ideal multisite mixing model are: $${\text{act (AB}}_{\text{2}} {\text{O}}_{\text{4}} {\text{) = }}\frac{{({\text{A}})[{\text{B}}]^2 }}{{({\text{A}})_0 [{\text{B}}]_0^2 }}$$ (A): fraction of tetrahedral sites occupied by A²⁺; [B]: fraction of octahedral sites occupied by B³⁺. Because the site occupancy fractions at equilibrium are not independent (but related by the internal equilibrium relations) many equivalent expressions of the activities can be obtained. Finally approximations proposed in the literature to obtain simple explicit activity-concentration relationships are discussed.     

Radiometric mapping of the Berg River estuary

Geographic Information Systems (GIS) consists of various tools to perform spatial analyses in a wide variety of disciplines, including radiometric analysis to characterize the distribution of natural radionuclide concentrations. Recently, open-source GIS has become popular among geospatial users because it can be freely used, and powerful tools are constantly developed to enhance software capabilities. Gamma-ray spectroscopy was used to measure the concentrations of these natural radionuclides by dragging a Delta Underwater Gamma System (DUGS) among the sediment in the Berg River estuary located in Velddrif, South Africa. In this study, QGIS was used to visually illustrate and interpret the distribution of natural radionuclides, that is, potassium (K⁴⁰), thorium (Th²³²), and uranium (U²³⁸). These concentrations can be used to investigate various geographical and geological phenomena, which include sediment processes. The data were then interpreted to derive sediment characteristics. Various features of tidal estuaries were demonstrated by the results.