Considérations sur le volcanisme post-ophiolitique dans les Alpes occidentales

Résumé L'activité magmatique ophiolitique du géosynclinal alpin (diabases, gabbros, serpentines, etc.) a été suivie par une activité à caractère volcanique moins bien connue. En effet, les appareils correspondant à cette activité ont complètement disparu; nous devons nous contenter pour tous renseignements de l'étude des fragments de roches contenus dans des grauwackes tertiaires appartenant au Flysch (grès de Taveyanne, grès d'AItdorf pro parte, grès du Champsaur).La détermination de la nature originelle des laves est, en outre, rendue difficile par le fait, découvert récemment, que ces grauwackes ont subi un métamorphisme régional les plaçant dans le faciès à zéolites; on peut raisonnablement admettre qu'il s'agissait d'andésites basaltiques.L'áge des épanchements est encore indéterminé, il doit être compris entre le Crétacé supérieur et la fin de l'Eocène. L'hypothèse la plus plausible consiste à admettre que les volcans, aujourd'hui complètement érodés se trouvaient dans la partie la plus interne du domaine pennique. Toutefois au moment du dépôt des grès de Taveyanne, les coulées ne se trouvaient plus dans leur position initiale, elles avaient glissé vers l'avant-pays sous forme d'une nappe.Il est très probable que cette activité volcanique post-ophiolitique n'est pas restreinte au segment franco-suisse des Alpes occidentales mais que des formations analogues aux grès de Taveyanne se retrouvent ailleurs, notamment en Sicile et dans les Apennins.

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The magmatic activity which gave birth to the ophiolites (diabases, gabbros, serpentinites) of the alpine geosyncline was followed by subaerial volcanism. This volcanic activity is not well known as the volcanoes were completely destroyed by erosion. Our only source of information is to be found in fragments of volcanic rocks which are part of Tertiary Flysch graywackes (Taveyanne sandstones, part of the Altorf sandstones, Champsaur sandstones).The determination of the initial composition of the lavas is further complicated by metasomatic transformations; it has been recently shown that the Taveyanne graywackes were submitted to a light regional metamorphism corresponding to the zeolitic facies ofCoombs. However, it seems that these lavas were originally basaltic andesites.The age of this volcanism is not precisely known, it cannot be later than Upper Eocene as the time of deposition of the Taveyanne sandstones is Uppermost Eocene-Lower Oligocene; it is probably post-Cenomanian. It is likely that the volcanoes were located in the southern part of the Penninic zone; however at the time of deposition of the graywackes the volcanic flows had already left their initial location, gliding toward the Foreland as part of a Nappe.Very probably, remnants of this post-ophiolitic volcanism are not restricted to the French-Swiss segment of the Western Alps, but will be found elsewhere, particularly in the Apennine Mountains and in Sicily.

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Zusammenfassung Die magmatische Tätigkeit, die Ophiolithe (Diabase, Gabbros, Serpentinite) der alpinen Geosynklinale entstehen ließ, wurde von subärischem Vulkanismus abgelöst. Diese Vulkantätigkeit ist wenig bekannt, da die Vulkane durch Erosion völlig zerstört wurden. Unsere einzige Informationsquelle findet sich in vulkanischen Gesteinsfragmenten, die Bestandteile der Tertiär-Flysch-Grauwacken sind.Die Bestimmung der ursprünglichen Zusammensetzung der Laven wird weiter durch metasomatische Umwandlungen erschwert. Kürzlich wurde gezeigt, daß die Taveyanne-Grauwacken einem regionalen Metamorphismus ausgesetzt waren, welcher der zeolithischen Fazies von Coombs entspricht. Es scheint jedoch, daß diese Laven ursprünglich basaltische Andésite waren.Das Alter dieses Vulkanismus ist nicht genau bekannt; es kann aber nicht später sein als das Obere Eozän, da die Ablagerungszeit der Taveyanne-Sandsteine Oberstes Eozän—Unteres Oligozän ist. Wahrscheinlich lagen die Vulkane im südlichen Teil der penninischen Zone; zur Zeit der Ablagerung der Grauwacken waren die Vulkanite bereits in die Überschiebungsmassen mit einbezogen.Sehr wahrscheinlich sind die Überreste dieses nach-ophiolithischen Vulkanismus nicht auf den französisch-schweizerischen Abschnitt der Westalpen beschränkt, sondern werden sich auch andernorts speziell auf dem Apennin und in Sizilien finden lassen.

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Gravimetry on the Erimo Seamount, Japan

A gravimetric survey on the sea-bottom was performed on the Erimo Seamount by the French submersible “Nautile”. It took place during the second phase of the Kaiko French-Japanese Program. The reference station was established on the Erimo submarine observatory at a depth of 3942 m and from this point the survey of four stations was carried out. The obtained accuracy of the gravity field measurements was about 0.1 mGal.

A three-dimensional model of the seamount and its surroundings was constrained by the free-air anomaly values from the sea surface and from the sea bottom and by the perfect Seabeam topography survey of the whole area. The model which fitted the observed values best, allowed us to identify a low-density layer of coral limestones and volcaniclastics capping the seamount and to define the geometry of the interface between basalts and coral rocks.     

Comparative studies of the kinetic parameters of various algaenans and kerogens via open-system pyrolyses

Kinetic parameters were determined for the first time, via open-system pyrolyses, on algaenans (highly resistant biomacromolecules that are selectively preserved during kerogen formation) isolated from extant microalgae. Parallel studies were also carried out on 10 kerogens exhibiting, with one exception, a low level of maturity. These kerogens included samples chiefly derived from the selective preservation of the above algaenans and samples mainly, or almost exclusively, derived from the “natural vulcanization” pathway. Important differences in activation energy (E_a) distributions were observed between the four algaenans investigated and correlated with their chemical structures. The kerogens predominantly derived from algaenan-selective preservation (Pula alginite, NE 70 and BJ 248 Torbanites, Rundle Oil Shale) also exhibited pronounced differences in E_a distributions. These distributions provided: (i) information on the diversity of the source materials; and (ii) reflected the occurrence of important differences in chemical structures and thermal behaviour between three of the tested kerogens, even though they are all classified as low maturity type I. The Kimmeridge Clay samples and the Lorca Oil Shale showed broad E_a distributions shifted to low energies when compared with the above algaenans and kerogens. Such shifts reflect an important (or even almost exclusive for some of these kerogens) contribution of materials originating from sulphur incorporation into various lipids during early diagenesis. Finally, the kinetic data derived for the nine low maturity fossil samples were extrapolated to a very low, geological heating rate of 3°C Ma⁻¹ and the generation rate curves and cumulative yield curves thus obtained were compared.     

Use of discriminant statistical analysis to determine the origin of an industrial pollution type in the aquiferous system of the area of Berrahal, Algeria

The continuous increase of industrial activities in the area of Berrahal (northeast of Algeria) resulted in an increase of waste disposal, inducing environmental pollution and contamination of groundwater. Available data on groundwater contamination were used to develop a statistical study for contaminated regions and to identify exposure scenarios of pollution. Chemical analysis of the samples shows that water of most wells and drillings is in bad quality or not drinkable, whereas statistical processing of these data by principal component analysis and discriminant factorial analysis suggests that wastewater coming from companies of the industrial park of Berrahal is very rich in organic pollutants (high percentages of BOD₅ and NO₂ ^?) and has high mineralization (has strong concentration in major elements and high electric conductivity); these constitute the main factors of the deterioration of the quality of this water. The considered exposure pathways were drinking water exploited from wells and drillings implanted in this area and its contact with soil (ingestion and dermal contact) that could threaten either humans or wildlife, on site or off site. In addition, groundwater was considered to be a potential risk pathway, especially for the ecosystem of Lake Fetzara and for the aquiferous system.     

Évolution géodynamique messino-pliocène en Languedoc central : le paléo-réseau hydrographique de l’Orb et de l’Hérault (Sud de la France)

Résumé

En Languedoc central, la cartographie des sédiments formés lors de la crise messinienne et de ceux de la séquence pliocène, ainsi que les données patées paléontologiques nouvelles (Aigues-Vives et Servian) permettent de proposer une reconstitution du tracé messimeli des rivières actuelles (Orb et Hérault) transformées en rias à la suite du relèvement eustatique pliocène. L’Hérault messinien se singularise par une incision beaucoup plus faible que celle des autres rivères. En effet, la nature karstique de l’arinère-pays immédiat permet un enfouissement des eaux météoriques au profit d’aquifères profonds sous-jacents au drainage aérien du réseau hydrographique messinien. Le Languedoc central illustre, entre Roussillon et Rhône, le modèle géodynamique messino-pliocène de Clauzon. © Elsevier, Paris     

Soulèvement et plissement tectoniques révélés par analyse mathématique empirique de profils longitudinaux de rivières : un cas à TaiwanEmpirical mathematical analysis of longitudinal river profiles reveals tectonic uplift and folding: a case in Taiwan

We analyse longitudinal river profiles in southwestern Taiwan. As all necessary data are not available, a physical modelling of river erosion would be subject to large uncertainties. We thus shortcut this modelling and adopt simple empirical exponential equations giving riverbed elevation as a function of downstream distance. We identify a positive altimetric anomaly, which reveals active uplift of an anticline at the front of the fold-and-thrust belt. To cite this article: J. Angelier, R.-F. Chen, C. R. Geoscience 334 (2002) 1103–1111.     

Experimental study of brucite dissolution and precipitation in aqueous solutions: surface speciation and chemical affinity control

Dissolution and precipitation rates of brucite (Mg(OH)₂) were measured at 25°C in a mixed-flow reactor as a function of pH (2.5 to 12), ionic strength (10⁻⁴ to 3 M), saturation index (−12 < log Ω < 0.4) and aqueous magnesium concentrations (10⁻⁶ to 5·10⁻⁴ M). Brucite surface charge and isoelectric point (pH_IEP) were determined by surface titrations in a limited residence time reactor and electrophoretic measurements, respectively. The pH of zero charge and pH_IEP were close to 11. A two-pK, one site surface speciation model which assumes a constant capacitance of the electric double layer (5 F/m²) and lack of dependence on ionic strength predicts the dominance of >MgOH₂⁺ species at pH < 8 and their progressive replacement by >MgOH° and >MgO⁻ as pH increases to 10-12. Rates are proportional to the square of >MgOH₂⁺ surface concentration at pH from 2.5 to 12. In accord with surface speciation predictions, dissolution rates do not depend on ionic strength at pH 6.5 to 11. Brucite dissolution and precipitation rates at close to equilibrium conditions obeyed TST-derived rate laws. At constant saturation indices, brucite precipitation rates were proportional to the square of >MgOH₂⁺ concentration. The following rate equation, consistent with transition state theory, describes brucite dissolution and precipitation kinetics over a wide range of solution composition and chemical affinity:

     

ISIS IR: The first infrared fibre-fed spectrograph

ISIS IR is the first attempt to use fibre optics for near infrared spectroscopy (1.8m). It is a field spectrograph (2D spectroscopy), and can work at various resolving powers (up to 25000). It can be transported anywhere, and soon it will be used at CFHT with one NICMOS 3-based camera.Département d'Astrophysique Extragalactique et de Cosmologie     

Some comments on the limb shift of solar lines

We searched for a variation with heliographic latitude of the solar limb effect by comparing the relative wavelengths of weak and strong Fraunhofer lines. The blue shifts associated with the limb effect appear 9%±5% larger in the polar radius vector than in an equatorial radius vector at cos = 0.5. This should perhaps be interpreted as an increase with latitude of either solar convection or of convective overshoot. Recent observations of poleward meridional flows of 30m s^–1 should be corrected for this limb effect variation. This correction increases this flow velocity to 70 m s^–1. A search for a similar variation in plages and in network boundaries had negative results, the variation being +1%±5% and -1%±6% respectively.Now at the Multiple Mirror Telescope Observatory, University of Arizona, Tucson, Ariz. 85721, U.S.A. The MMTO is jointly operated by the University of Arizona and the Smithsonian Institution.The Sacramento Peak Observatory is operated by the Association of Universities for Research in Astronomy, Inc. under contract AST 78-17292 with the National Science Foundation.     

Heliocentric evolution of the degradation of polyoxymethylene: Application to the origin of the formaldehyde (H2CO) extended source in Comet C/1995 O1 (Hale-Bopp)

The H₂CO production rates measured in Comet C/1995 O1 (Hale-Bopp) from radio wavelength observations [Biver, N., and 22 colleagues, 2002a. Earth Moon Planets 90, 5-14] showed a steep increase with decreasing heliocentric distance. We studied the heliocentric evolution of the degradation of polyoxymethylene (formaldehyde polymers: (CH₂O)_n, also called POM) into gaseous H₂CO. POM decomposition can indeed explain the H₂CO density profile measured in situ by Giotto spacecraft in the coma of Comet 1P/Halley, which is not compatible with direct release from the nucleus [Cottin, H., Bénilan, Y., Gazeau, M.-C., Raulin, F., 2004. Icarus 167, 397-416]. We show that the H₂CO production curve measured in Comet C/1995 O1 (Hale-Bopp) can be accurately reproduced by this mechanism with a few percents by mass of solid POM in grains. The steep heliocentric evolution is explained by the thermal degradation of POM at distances less than 3.5 AU. This study demonstrates that refractory organics present in cometary dust can significantly contribute to the composition of the gaseous coma. POM, or POM-like polymers, might be present in cometary grains. Other molecules, like CO and HNC, might also be produced by a similar process.