where k is a constant equal to 6.5 × 10−16 mol/cm2/s and Ω is the saturation index with respect to magnesite. This equation is consistent with spiral growth step generation controlling magnesite precipitation rates. Corresponding magnesite precipitation rates measured using mixed-flow reactors are shown to be consistent with both the rates measured by HAFM and the spiral growth theory, confirming the rate limiting mechanism. Step advancement, however, is observed to slow far faster than step generation with decreasing temperature; the activation energy for step advancement is 159 kJ/mol whereas step generation rates have an estimated activation energy of 60 kJ/mol. As such, it seems likely that at ambient temperatures magnesite growth is limited by very slow step advancement rates.  相似文献   
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11.
]The activities of 18 radionuclides in 4 samples from the Saint-Séverin meteorite have been measured after chemical separation. The results show that the DI sample from the D piece has been less irradiated than the samples B2, B3 and B4 from the B piece. This is based on activities of isotopes produced both by spallation as 26Al, 53Mn, 54Mn, 55Fe, 57Co and by thermal neutron capture as 59Ni and 60Co.Comparison of experimental values to calculated production rates suggests that the D piece was connected to the main body of the meteorite by a small surface, and that the DI sample in this piece was opposite to the main body of the meteorite.  相似文献   
12.
An innovative mode of groundwater recharge to a buried esker aquifer is considered. The current conceptual model affords a natural safeguard to underlying aquifers from the overlying muds. A hypothesis of groundwater recharge to a buried esker aquifer via preferential pathways across its overlying muds is tested here by heuristic numerical one-dimensional and two-dimensional modeling simulations. The hypothesis has been tested against two other conventionally accepted scenarios involving: (1) distal esker outcrop areas and (2) remote shallow-bedrock recharge areas. The main evidence comes from documented recharge pressure pulses in the overlying mud aquitard and in the underlying esker hydraulic-head time series for the Vars-Winchester esker aquifer in Eastern Ontario, Canada. These perturbations to the potentiometric surface are believed to be the aquifer response to recharge events. The migration rate of these pressure pulses is directly related to the hydraulic diffusivity of the formation. The measured response time and response amplitude between singular radar precipitation events and well hydrographs constituted the heuristic model calibration targets. The main evidence also includes mud-layering deformation (water escape features) which was observed in seismic surveys of the over-esker muds. These disturbed stratigraphic elements provide a realistic mechanism for migrating water to transit through the muds. The effective hydraulic conductivities of these preferential pathways in the muds were estimated to be between 2?×?10?6 and 7?×?10?6 m/s. The implications of these findings relate to the alleged natural safeguard of these overlying muds.  相似文献   
13.
Résumé

En Languedoc central, la cartographie des sédiments formés lors de la crise messinienne et de ceux de la séquence pliocène, ainsi que les données patées paléontologiques nouvelles (Aigues-Vives et Servian) permettent de proposer une reconstitution du tracé messimeli des rivières actuelles (Orb et Hérault) transformées en rias à la suite du relèvement eustatique pliocène. L’Hérault messinien se singularise par une incision beaucoup plus faible que celle des autres rivères. En effet, la nature karstique de l’arinère-pays immédiat permet un enfouissement des eaux météoriques au profit d’aquifères profonds sous-jacents au drainage aérien du réseau hydrographique messinien. Le Languedoc central illustre, entre Roussillon et Rhône, le modèle géodynamique messino-pliocène de Clauzon. © Elsevier, Paris  相似文献   
14.
ABSTRACT

In the European Alps, high mountain environments are subject to major impacts resulting from climate change, which strongly affect human activities such as mountaineering. The purpose of the study was to examine changes in access routes to 30 high mountain huts in the Western Alps since the 1990s. Data were derived from the use of two different methods, geo-historical studies and a questionnaire, and were used to identify both the climate-related processes affecting the climbing routes and the strategies implemented by public entities, Alpine clubs, guide companies, and hut keepers to maintain acceptable safety and technical conditions. The case studies revealed issues affecting three access routes and the results from the questionnaire showed that the main processes affecting access routes were loss of ice thickness and retreat from the front of the glaciated areas. Commonly, in situ equipment was installed to facilitate access for mountaineers and/or a part of a route was relocated to a safer area. The authors conclude that in most cases, the measures were effective but they were limited by financial, ethical and legal issues, especially in protected or classified areas that could jeopardise their durability and effectiveness.  相似文献   
15.
A gravimetric survey on the sea-bottom was performed on the Erimo Seamount by the French submersible “Nautile”. It took place during the second phase of the Kaiko French-Japanese Program. The reference station was established on the Erimo submarine observatory at a depth of 3942 m and from this point the survey of four stations was carried out. The obtained accuracy of the gravity field measurements was about 0.1 mGal.

A three-dimensional model of the seamount and its surroundings was constrained by the free-air anomaly values from the sea surface and from the sea bottom and by the perfect Seabeam topography survey of the whole area. The model which fitted the observed values best, allowed us to identify a low-density layer of coral limestones and volcaniclastics capping the seamount and to define the geometry of the interface between basalts and coral rocks.  相似文献   

16.
The filling history of the Níspero deeply buried Lower Cretaceous carbonate reservoir (below 4000 m) from the south part of Gulf of Mexico was studied using a combination of data from petrography, stable isotopes and fluid inclusions and compared with a one-dimensional burial model to derive timing.  相似文献   
17.
The internal thermal boundary layer developing over the Mediterranean during a cold-air outbreak associated with a Tramontane event has been studied by means of airborne lidar, in situ sensors, and a modelling approach that consisted of nesting the University of Washington (UW) planetary boundary-layer (PBL) model in an advective zero-order jump model. This approach bypasses some of the deficiencies associated with each model: the absence of the dynamics in the mixed layer for the zero-order jump model and the lack of an inversion at the PBL top for the UW PBL model. Particular attention is given to the parameterization of the entrainment flux at the PBL top. Values of the entrainment closure parameter derived with the model when matching PBL structure observations are much lower than those derived with standard zero-order jump models. They also are in good agreement with values measured in different meteorological situations by other studies. This improvement is a result of the introduction of turbulent kinetic energy production in the mixed layer.  相似文献   
18.
An algorithm is given for normalizing conservative linear Hamiltonian systems. This one generalizes Siegel's method to the cases where the eigenvalues are multiple. We obtain by a canonical transformation a normal form of two blocks, one of which is the upper Jordan form, and the other, the lower Jordan form. We select real solutions from the solutions of these equations, and we apply the result to the restricted three body problem in the vicinity of the triangular points for Routh's critical mass ratio.

n est la matrice unité d'ordren,O n est la matrice nulle d'ordren.  相似文献   
19.
Kamel has recently extended to non-Hamiltonian equations a perturbation theory using Lie transforms. We show here how Kamel's extension can be approached from an intrinsic viewpoint, which reformulation leads to a simpler algorithm. Then we complete Kamel's contribution by establishing the rules for inverting the transformation generated by the perturbation theory, and for composing two such transformations.  相似文献   
20.
Magnesite growth rates and step velocities have been measured systematically as a function of temperature from 80 to 105 °C and saturation state in 0.1 M NaCl solutions using hydrothermal atomic force microscopy (HAFM). The observations indicate that at these conditions magnesite precipitation is dominated by the coupling of step generation via spiral growth at screw dislocations and step advancement away from these dislocations. As these two processes occur in series the slowest of these dominates precipitation rates. At 100 °C magnesite growth rates (r) determined by HAFM are consistent with
r=k(Ω-1)2,
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