Paléoenvironnements et caractérisation des roches mères pétrolières des séries pré-salifères du bassin intérieur du Gabon

The Interior Basin of Gabon, created during the break-up between South America and Africa, displays thick Neoproterozoic to Aptian p.p. fluvio-lacustrine deposits overlain by Aptian to Albian marine facies. Rock–Eval analyses from outcrop and drillhole samples show high content in organic matter (up to 25%) related to types I and II. These intervals are encountered within Permian, Neocomian–Barremian as well as Aptian siliciclastic succession. They constitute fairly good to excellent potential petroleum source rocks, which are most probably at the origin of oil indices recognized both in drillholes and in surface.     

Fluid inclusions in granulites, granulitized eclogites and garnet clinopyroxenites from the Dabie–Sulu terranes, eastern China

Minor granulites (believed to be pre-Triassic), surrounded by abundant amphibolite-facies orthogneiss, occur in the same region as the well-documented Triassic high- and ultrahigh-pressure (HP and UHP) eclogites in the Dabie–Sulu terranes, eastern China. Moreover, some eclogites and garnet clinopyroxenites have been metamorphosed at granulite- to amphibolite-facies conditions during exhumation. Granulitized HP eclogites/garnet clinopyroxenites at Huangweihe and Baizhangyan record estimated eclogite-facies metamorphic conditions of 775–805 °C and ≥15 kbar, followed by granulite- to amphibolite-facies overprint of ca. 750–800 °C and 6–11 kbar. The presence of (Na, Ca, Ba, Sr)-feldspars in garnet and omphacite corresponds to amphibolite-facies conditions. Metamorphic mineral assemblages and P–T estimates for felsic granulite at Huangtuling and mafic granulite at Huilanshan indicate peak conditions of 850 °C and 12 kbar for the granulite-facies metamorphism and 700 °C and 6 kbar for amphibolite-facies retrograde metamorphism. Cordierite–orthopyroxene and ferropargasite–plagioclase coronas and symplectites around garnet record a strong, rapid decompression, possibly contemporaneous with the uplift of neighbouring HP/UHP eclogites.

Carbonic fluid (CO₂-rich) inclusions are predominant in both HP granulites and granulitized HP/UHP eclogites/garnet clinopyroxenites. They have low densities, having been reset during decompression. Minor amounts of CH₄ and/or N₂ as well as carbonate are present. In the granulitized HP/UHP eclogites/garnet clinopyroxenites, early fluids are high-salinity brines with minor N₂, whereas low-salinity fluids formed during retrogression. Syn-granulite-facies carbonic fluid inclusions occur either in quartz rods in clinopyroxene (granulitized HP garnet clinopyxeronite) or in quartz blebs in garnet and quartz matrices (UHP eclogite). For HP granulites, a limited number of primary CO₂ and mixed H₂O–CO₂(liquid) inclusions have also been observed in undeformed quartz inclusions within garnet, orthopyroxene, and plagioclase which contain abundant, low-density CO₂±carbonate inclusions. It is suggested that the primary fluid in the HP granulites was high-density CO₂, mixed with a significant quantity of water. The water was consumed by retrograde metamorphic mineral reactions and may also have been responsible for metasomatic reactions (“giant myrmekites”) occurring at quartz–feldspar boundaries. Compared with the UHP eclogites in this region, the granulites were exhumed in the presence of massive, externally derived carbonic fluids and subsequently limited low-salinity aqueous fluids, probably derived from the surrounding gneisses.     

Effet de la teneur en eau d'un sol sur la réduction bactérienne d'oxydes de fer

Iron-reducing activity of autochthonous bacteria from two temporary hydromorphic soils is evaluated by the study of iron reductive dissolution, as a function of water content. The release of ferrous iron in solution is coupled to the mineralization of soil organic carbon. Water soil saturation is not necessary for iron reductive dissolution, since the highest dissolution is obtained for a wet, but not water-saturated soil (100% of water holding capacity WHC), and dissolution is also very high in a soil at 75% WHC. To cite this article: S.J. Stemmler et al., C. R. Geoscience 336 (2004).     

New chitinozoans from the historical type area of the Hirnantian Stage and additional key sections in the Wye Valley,Wales, UK

The type locality for several core elements of the Hirnantia brachiopod fauna is a small disused quarry on the western slopes of Cwm Hirnant. There, the Hirnant Limestone Member of the Foel‐y‐Ddinas Mudstone Formation yields a new, well‐preserved chitinozoan assemblage, attributed to the Spinachitina taugourdeaui Biozone. This allows tight correlation with the Hirnantian of Baltica and Laurentia and neatly ties the chitinozoan zonation with the classical brachiopod fauna. Nearby, the chitinozoan assemblage from the Caradoc Cymerig Limestone Member at Gelli‐grîn belongs to the Spinachitina cervicornis Biozone?, and is identical to that recovered from the Burrellian in the Onny Valley, Welsh Borderland. A Silurian assemblage higher up section, discovered in the Cwm‐yr‐Aethnen Formation, is attributed to the globally recognized Eisenackitina dolioliformis Biozone. Attempts to integrate the chitinozoan and graptolite biozonation, in the central Welsh Rhayader area, were less successful. Copyright © 2008 John Wiley & Sons, Ltd.     

象牙海岸Issia地区铌钽砂矿的研究(英文)

在西非的象牙海岸Issia地区分布着许多铌钽矿床,包括原生矿和砂矿。原生矿产在分带很好的伟晶岩中。这个地区发育着许多花岗岩和花岗伟晶岩。伟晶岩可分为:(1)分异不好的伟晶岩,无矿化;(2)含Be伟晶岩,分带较好,见绿柱石;(3)含Be-Nb-Ta的伟晶岩,分带很好,是矿体;(4)Be-Nb-Ta-Li伟晶岩,分带很好,是矿体。除了10多个原生矿外,还有许多砂矿。砂矿有两种类型:一种近原生矿的坡积砂矿,另一种是经河流冲刷搬运后的冲积砂矿。我们选择了Etienne-Meguhe砂矿作为近原生矿的坡积砂矿的代表,Bemadi矿作为河流冲积型的砂矿的代表,对这两种类型的砂矿的风化、搬运、沉积机理进行了比较研究。研究发现不同的搬运距离和搬运模式对铌钽砂矿的主要矿物——铌钽铁矿的化学性质没有什么影响,而其物理形态则发生了变化。坡积型砂矿的铌钽铁矿常与石英、长石等矿物连生,其颗粒大小与原生的Nb-Ta伟晶岩中的铌钽铁矿一致;经河流冲积而形成的砂矿中,铌钽铁矿颗粒变小、轮廓变得圆滑,几乎无连生矿物,但矿体集中,常在河流的冲积扇中分布,易开采。     

Comparative studies of the kinetic parameters of various algaenans and kerogens via open-system pyrolyses

Kinetic parameters were determined for the first time, via open-system pyrolyses, on algaenans (highly resistant biomacromolecules that are selectively preserved during kerogen formation) isolated from extant microalgae. Parallel studies were also carried out on 10 kerogens exhibiting, with one exception, a low level of maturity. These kerogens included samples chiefly derived from the selective preservation of the above algaenans and samples mainly, or almost exclusively, derived from the “natural vulcanization” pathway. Important differences in activation energy (E_a) distributions were observed between the four algaenans investigated and correlated with their chemical structures. The kerogens predominantly derived from algaenan-selective preservation (Pula alginite, NE 70 and BJ 248 Torbanites, Rundle Oil Shale) also exhibited pronounced differences in E_a distributions. These distributions provided: (i) information on the diversity of the source materials; and (ii) reflected the occurrence of important differences in chemical structures and thermal behaviour between three of the tested kerogens, even though they are all classified as low maturity type I. The Kimmeridge Clay samples and the Lorca Oil Shale showed broad E_a distributions shifted to low energies when compared with the above algaenans and kerogens. Such shifts reflect an important (or even almost exclusive for some of these kerogens) contribution of materials originating from sulphur incorporation into various lipids during early diagenesis. Finally, the kinetic data derived for the nine low maturity fossil samples were extrapolated to a very low, geological heating rate of 3°C Ma⁻¹ and the generation rate curves and cumulative yield curves thus obtained were compared.     

Considérations sur le volcanisme post-ophiolitique dans les Alpes occidentales

Résumé L'activité magmatique ophiolitique du géosynclinal alpin (diabases, gabbros, serpentines, etc.) a été suivie par une activité à caractère volcanique moins bien connue. En effet, les appareils correspondant à cette activité ont complètement disparu; nous devons nous contenter pour tous renseignements de l'étude des fragments de roches contenus dans des grauwackes tertiaires appartenant au Flysch (grès de Taveyanne, grès d'AItdorf pro parte, grès du Champsaur).La détermination de la nature originelle des laves est, en outre, rendue difficile par le fait, découvert récemment, que ces grauwackes ont subi un métamorphisme régional les plaçant dans le faciès à zéolites; on peut raisonnablement admettre qu'il s'agissait d'andésites basaltiques.L'áge des épanchements est encore indéterminé, il doit être compris entre le Crétacé supérieur et la fin de l'Eocène. L'hypothèse la plus plausible consiste à admettre que les volcans, aujourd'hui complètement érodés se trouvaient dans la partie la plus interne du domaine pennique. Toutefois au moment du dépôt des grès de Taveyanne, les coulées ne se trouvaient plus dans leur position initiale, elles avaient glissé vers l'avant-pays sous forme d'une nappe.Il est très probable que cette activité volcanique post-ophiolitique n'est pas restreinte au segment franco-suisse des Alpes occidentales mais que des formations analogues aux grès de Taveyanne se retrouvent ailleurs, notamment en Sicile et dans les Apennins.

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The magmatic activity which gave birth to the ophiolites (diabases, gabbros, serpentinites) of the alpine geosyncline was followed by subaerial volcanism. This volcanic activity is not well known as the volcanoes were completely destroyed by erosion. Our only source of information is to be found in fragments of volcanic rocks which are part of Tertiary Flysch graywackes (Taveyanne sandstones, part of the Altorf sandstones, Champsaur sandstones).The determination of the initial composition of the lavas is further complicated by metasomatic transformations; it has been recently shown that the Taveyanne graywackes were submitted to a light regional metamorphism corresponding to the zeolitic facies ofCoombs. However, it seems that these lavas were originally basaltic andesites.The age of this volcanism is not precisely known, it cannot be later than Upper Eocene as the time of deposition of the Taveyanne sandstones is Uppermost Eocene-Lower Oligocene; it is probably post-Cenomanian. It is likely that the volcanoes were located in the southern part of the Penninic zone; however at the time of deposition of the graywackes the volcanic flows had already left their initial location, gliding toward the Foreland as part of a Nappe.Very probably, remnants of this post-ophiolitic volcanism are not restricted to the French-Swiss segment of the Western Alps, but will be found elsewhere, particularly in the Apennine Mountains and in Sicily.

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Zusammenfassung Die magmatische Tätigkeit, die Ophiolithe (Diabase, Gabbros, Serpentinite) der alpinen Geosynklinale entstehen ließ, wurde von subärischem Vulkanismus abgelöst. Diese Vulkantätigkeit ist wenig bekannt, da die Vulkane durch Erosion völlig zerstört wurden. Unsere einzige Informationsquelle findet sich in vulkanischen Gesteinsfragmenten, die Bestandteile der Tertiär-Flysch-Grauwacken sind.Die Bestimmung der ursprünglichen Zusammensetzung der Laven wird weiter durch metasomatische Umwandlungen erschwert. Kürzlich wurde gezeigt, daß die Taveyanne-Grauwacken einem regionalen Metamorphismus ausgesetzt waren, welcher der zeolithischen Fazies von Coombs entspricht. Es scheint jedoch, daß diese Laven ursprünglich basaltische Andésite waren.Das Alter dieses Vulkanismus ist nicht genau bekannt; es kann aber nicht später sein als das Obere Eozän, da die Ablagerungszeit der Taveyanne-Sandsteine Oberstes Eozän—Unteres Oligozän ist. Wahrscheinlich lagen die Vulkane im südlichen Teil der penninischen Zone; zur Zeit der Ablagerung der Grauwacken waren die Vulkanite bereits in die Überschiebungsmassen mit einbezogen.Sehr wahrscheinlich sind die Überreste dieses nach-ophiolithischen Vulkanismus nicht auf den französisch-schweizerischen Abschnitt der Westalpen beschränkt, sondern werden sich auch andernorts speziell auf dem Apennin und in Sizilien finden lassen.

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Plio-Quaternary geodynamic evolution of a segment of the Peruvian Andean Cordillera located above the change in the subduction geometry: the Cuzco region

The Cuzco region, which is located above a change in subduction geometry, appears to be characterized by a variable Plio-Quaternary tectono-sedimentary evolution essentially located along the major fault system that separates the High Plateaux from the Eastern Cordillera. After the higher surface formation of the High Plateaux, a set of Neogene basins were filled by Miocene “ fluvio-torrential” series and by Plio-Pleistocene fluvio-lacustrine deposits. The Neogene series have been affected by compressional tectonic forces attributed to the Late Miocene. This compression is followed by roughly E-W trending syn-sedimentary extensional tectonics attributed to the Pliocene; it is related to reactivation of the pre-existing major faults, basin evolution, and volcanic activity concentrated along the faults. In the Early Pleistocene, fluvio-lacustrine deposits are affected by syn- and post-sedimentary compressional tectonism it is characterized by shortening that trends both N-S and E-W and produces folding and faulting of the sedimentary cover. Extensional tectonism trending roughly N-S has been taking place from the Middle Pleistocene to the Present; it is coeval with shoshonitic volcanic activity, and with sedimentation of fluvio-lacustrine terraces, torrential fans and moraines. Quaternary and active normal faults due to this tectonism, are located in a narrow zone more than 100 km-long between the High Plateaux and the Eastern Cordillera, and two 15 km-long fault sectors in the Eastern Cordillera. Characteristic Pleistocene scarps, 400 m or more high, are due to the cumulative normal offset, and there are also little scarps, with heights ranging between 2 and 20 m, which are related to Holocene fault reactivations. Recent fault reactivation on the Cuzco fault system, during the April 5, 1986 earthquake (m_b = 5.3), is due to the N-S trending extension. This state of stress, located at a mean elevation of roughly 3730 m, is generally homogeneous to different scales. The active Cuzco normal faults may be a consequence of adjustment between the compensated Western Cordillera and the undercompensated Eastern Cordillera, this latter being uplifted higher than its isostatic equilibrium due to compression acting on its eastern edge. The variation of the state of stress, during the Plio-Quaternary is in agreement with the variations of the compressional boundary forces. It may be explained by variation of the convergence rate or by the variation of pull-slab forces.     

The international conference “Vortices and coherent structures: from ocean to microfluids”, Vladivostok,Russia, 28–31 August 2017

The international conference “Vortices and coherent structures: from ocean to microfluids” was held at the Pacific Oceanological Institute of the Russian Academy of Sciences in Vladivostok (Russia) from August 28 to August 31, 2017. The event gathered experimentalists and theoreticians, oceanographers and physicists, with a common interest in observing and modelling fluid flows in different media, from the ocean to laboratory flows. It was a fruitful idea to bring together researchers from a variety of backgrounds to benefit from a vigorous discussion of concepts across different disciplines in oceanography and hydrodynamics.

     

Solomon Sea circulation and water mass modifications: response at ENSO timescales

The South Pacific low latitude western boundary currents (LLWBCs) carry waters of subtropical origin through the Solomon Sea before joining the equatorial Pacific. Changes in their properties or transport are assumed to impact El Niño Southern Oscillation (ENSO) dynamics. At ENSO timescales, the LLWBCs transport tends to counterbalance the interior geostrophic one. When transiting through the complex geography of the Solomon Sea, the main LLWBC, the New Guinea Coastal Undercurrent, cannot follow a unique simple route to the equator. Instead, its routes and water mass properties are influenced by the circulation occurring in the Solomon Sea. In this study, the response of the Solomon Sea circulation to ENSO is investigated based on a numerical simulation. The transport anomalies entering the Solomon Sea from the south are confined to the top 250 m of the water column, where they represent 7.5 Sv (based on ENSO composites) for a mean transport of 10 Sv. The induced circulation anomalies in the Solomon Sea are not symmetric between the two ENSO states because of (1) a bathymetric control at Vitiaz Strait, which plays a stronger role during El Niño, and (2) an additional inflow through Solomon Strait during La Niña events. In terms of temperature and salinity, modifications are particularly notable for the thermocline water during El Niño conditions, with cooler and fresher waters compared to the climatological mean. The surface water at Vitiaz Strait and the upper thermocline water at Solomon Strait, feeding respectively the equatorial Pacific warm pool and the Equatorial Undercurrent, particularly affect the heat and salt fluxes. These fluxes can change by up to a factor of 2 between extreme El Niño and La Niña conditions.