Electrochemistry of reduced sulfur species in natural waters—I. The H2S-H2O system

Careful measurements of rest potentials of platinum electrodes (Eh) in the H₂S-H₂O system were made together with measurements of the pH and the potentials of Ag-Ag₂S electrodes (E_s^2?). The potentials of the platinum electrode are characteristic of H₂S chemisorption followed by H₂S discharge on the platinum. The relations between Eh, E_s^2? and pH are characteristic of the H₂S-H₂O system and of the hydrogen sulfide concentration. Thus these parameters can be employed to distinguish H₂S-H₂O systems from H₂S-S₈-H₂O systems. Field measurements on hot sulfurous springs are in agreement with laboratory data.     

Garnet zoning and orthopyroxene + plagioclase coronitisation

A very uncommon garnet-zoning—Ca poor centre and Ca rich margin—has been observed, in a granulite facies rock. Calculation of equilibrium at each stage of the garnet growth led to apply in this particular case, as well as for the most garnet-zoning instances, the Rayleigh fractionation model, the fractionation factor Ca being less than 1 at the beginning of the crystallization. Subsequent coronitisation, at lower P and/or higher T, involved the development of orthopyroxene and plagioclase in equilibrium with a thin (15 thick) Ca-Mg poor and Fe rich outer cuticle of the garnet: thus the garnet lattice appears to be not so refractory as previously admitted, and in most coronitisation processes involving garnet such an outer cuticle must be considered as a component of the new mineral assemblage.     

On the merger of subsurface isolated vortices

Vortex merger is a phenomenon characterizing the whole class of geophysical vortices, from atmospheric storms and large oceanic eddies up to small scale turbulence. Here we focus on the merger of subsurface oceanic anticyclones in an idealized primitive equations model. This study has been motivated by past and recent observations of colliding lens-like anticyclones off of Gibraltar Strait. The critical conditions for merger (critical merger distance and time needed for merger) are determined. We will show that the predictions of classical two-dimensional merger are not verified for subsurface isolated vortices. For instance, critical merger distances will be reduced because of the vortex potential vorticity (PV) structure. The post-merger characteristics of the vortex (radius, extension and PV), are also determined. Merger-related effects, like production of peripheral filaments and small-scale eddies are also investigated and suggest the contribution of merger in both direct and inverse energy cascades.     

An overview of the ACE‐2 CLOUDYCOLUMN closure experiment

CLOUDYCOLUMN is one of the 6 ACE‐2 projects which took place in June‐July 1997, between Portugal and the Canary Islands. It was specifically dedicated to the study of changes of cloud radiative properties resulting from changes in the properties of those aerosols which act as cloud condensation nuclei. This process is also refered to as the aerosol indirect effect on climate. CLOUDYCOLUMN is focused on the contribution of stratocumulus clouds to that process. In addition to the basic aerosol measurements performed at the ground stations of the ACE‐2 project, 5 instrumented aircraft carried out in situ characterization of aerosol physical, chemical and nucleation properties and cloud dynamical and microphysical properties. Cloud radiative properties were also measured remotely with radiometers and a lidar. 11 case studies have been documented, from pure marine to significantly polluted air masses. The simultaneity of the measurements with the multi‐aircraft approach provides a unique data set for closure experiments on the aerosol indirect effect. In particular CLOUDYCOLUMN provided the 1st experimental evidence of the existence of the indirect effect in boundary layer clouds forming in polluted continental outbreacks. This paper describes the objectives of the project, the instrumental setup and the sampling strategy. Preliminary results published in additional papers are briefly summarized.     

Rare anthropogenic and natural particles suspended in deep ocean waters

Four hundred membrane filters from the Atlantic and Pacific deep waters have been scanned for coloured and opaque particles by a method integrating the light and the scanning electron microscopes, the electron microprobe and the micro-X-ray diffraction camera. About 40 different types of particles have been found. A tentative classification of the particles and of their morphological and chemical varieties is presented, according to their anthropogenic or natural origins. From this point of view, the particles fall into five groups: (1) particle species exclusively produced by man's activities (like brass, cobalt aluminate); (2) particles exclusively produced by natural processes (like amphibole, ilmenite); (3) particles rarely produced by natural processes, but massively so by man (like metallic copper, chromium oxide); (4) a large group of particles massively produced by nature and by man (like magnetite spherules, malachite); (5) a very small group of particles whose origin could not be attributed at present. Very few entirely new compounds from the point of view of continental mineralogy have been encountered.     

Vanadiferous minerals from the Nereus Deep, Red Sea

The chemical analysis by EMPEDS of 140 samples in cores from six Red Sea troughs and basins has led to the discovery in the Nereus Deep of high vanadium concentrations (up to 1.3% V₂O₃) in several bulk samples, and to the isolation of a major magnetite phase. This vanado-magnetite, remarkable for its high content of vanadium (mean = 1.45% V₂O₃) and its lack of titanium, is frequently zoned, the V-content decreasing toward the outer zones. Oxides with up to 42% V₂O₃, have also been found. Since the origin of the magnetite is clearly authigenic, its high vanadium and low titanium concentrations are traced back to the differential hydrothermal leaching of Fe—Ti-oxides which occur profusely in basic eruptive rock clasts, actually present in some of the overlying seams.