Experimental study of brucite dissolution and precipitation in aqueous solutions: surface speciation and chemical affinity control

Dissolution and precipitation rates of brucite (Mg(OH)₂) were measured at 25°C in a mixed-flow reactor as a function of pH (2.5 to 12), ionic strength (10⁻⁴ to 3 M), saturation index (−12 < log Ω < 0.4) and aqueous magnesium concentrations (10⁻⁶ to 5·10⁻⁴ M). Brucite surface charge and isoelectric point (pH_IEP) were determined by surface titrations in a limited residence time reactor and electrophoretic measurements, respectively. The pH of zero charge and pH_IEP were close to 11. A two-pK, one site surface speciation model which assumes a constant capacitance of the electric double layer (5 F/m²) and lack of dependence on ionic strength predicts the dominance of >MgOH₂⁺ species at pH < 8 and their progressive replacement by >MgOH° and >MgO⁻ as pH increases to 10-12. Rates are proportional to the square of >MgOH₂⁺ surface concentration at pH from 2.5 to 12. In accord with surface speciation predictions, dissolution rates do not depend on ionic strength at pH 6.5 to 11. Brucite dissolution and precipitation rates at close to equilibrium conditions obeyed TST-derived rate laws. At constant saturation indices, brucite precipitation rates were proportional to the square of >MgOH₂⁺ concentration. The following rate equation, consistent with transition state theory, describes brucite dissolution and precipitation kinetics over a wide range of solution composition and chemical affinity:

     

On Some Simplifications of Cokriging Neighborhood

Choosing the cokriging neighborhood is often difficult. A poor choice, ignoring influent data, can result in a loss of information as well as in artifacts in simulations based on cokriging. Then it is convenient to use if possible, or to refer to models that lead to simplified cokriging neighborhood. We essentially consider the case of two stationary variables, a target variable and an auxiliary one. By examining possible simplifications, we set up a list of models (essentially models with residuals) that, in general or under specific configurations, lead to simplifications of cokriging neighborhood. Collocated, dislocated, and other types of neighborhood are identified, that are optimal in some models and configurations. Possible extensions to cokriging with unknown means, and to more variables, are included.     

ISIS IR: The first infrared fibre-fed spectrograph

ISIS IR is the first attempt to use fibre optics for near infrared spectroscopy (1.8m). It is a field spectrograph (2D spectroscopy), and can work at various resolving powers (up to 25000). It can be transported anywhere, and soon it will be used at CFHT with one NICMOS 3-based camera.Département d'Astrophysique Extragalactique et de Cosmologie     

Some comments on the limb shift of solar lines

We searched for a variation with heliographic latitude of the solar limb effect by comparing the relative wavelengths of weak and strong Fraunhofer lines. The blue shifts associated with the limb effect appear 9%±5% larger in the polar radius vector than in an equatorial radius vector at cos = 0.5. This should perhaps be interpreted as an increase with latitude of either solar convection or of convective overshoot. Recent observations of poleward meridional flows of 30m s^–1 should be corrected for this limb effect variation. This correction increases this flow velocity to 70 m s^–1. A search for a similar variation in plages and in network boundaries had negative results, the variation being +1%±5% and -1%±6% respectively.Now at the Multiple Mirror Telescope Observatory, University of Arizona, Tucson, Ariz. 85721, U.S.A. The MMTO is jointly operated by the University of Arizona and the Smithsonian Institution.The Sacramento Peak Observatory is operated by the Association of Universities for Research in Astronomy, Inc. under contract AST 78-17292 with the National Science Foundation.     

Heliocentric evolution of the degradation of polyoxymethylene: Application to the origin of the formaldehyde (H2CO) extended source in Comet C/1995 O1 (Hale-Bopp)

The H₂CO production rates measured in Comet C/1995 O1 (Hale-Bopp) from radio wavelength observations [Biver, N., and 22 colleagues, 2002a. Earth Moon Planets 90, 5-14] showed a steep increase with decreasing heliocentric distance. We studied the heliocentric evolution of the degradation of polyoxymethylene (formaldehyde polymers: (CH₂O)_n, also called POM) into gaseous H₂CO. POM decomposition can indeed explain the H₂CO density profile measured in situ by Giotto spacecraft in the coma of Comet 1P/Halley, which is not compatible with direct release from the nucleus [Cottin, H., Bénilan, Y., Gazeau, M.-C., Raulin, F., 2004. Icarus 167, 397-416]. We show that the H₂CO production curve measured in Comet C/1995 O1 (Hale-Bopp) can be accurately reproduced by this mechanism with a few percents by mass of solid POM in grains. The steep heliocentric evolution is explained by the thermal degradation of POM at distances less than 3.5 AU. This study demonstrates that refractory organics present in cometary dust can significantly contribute to the composition of the gaseous coma. POM, or POM-like polymers, might be present in cometary grains. Other molecules, like CO and HNC, might also be produced by a similar process.     

Central forces depending on the distance only. Case where all the bounded orbits are periodic

It is shown in this paper that the only potentials corresponding to central force for which all the bounded orbits are periodic are the potential of the harmonic oscillator and of the two body problem. A discussion is given in the case where a circular orbit exists and when the orbits near the circular orbit are periodic.We calculate in these cases the angle between pericentre and apocentre.Celestial Mechanics     

Solomon Sea circulation and water mass modifications: response at ENSO timescales

The South Pacific low latitude western boundary currents (LLWBCs) carry waters of subtropical origin through the Solomon Sea before joining the equatorial Pacific. Changes in their properties or transport are assumed to impact El Niño Southern Oscillation (ENSO) dynamics. At ENSO timescales, the LLWBCs transport tends to counterbalance the interior geostrophic one. When transiting through the complex geography of the Solomon Sea, the main LLWBC, the New Guinea Coastal Undercurrent, cannot follow a unique simple route to the equator. Instead, its routes and water mass properties are influenced by the circulation occurring in the Solomon Sea. In this study, the response of the Solomon Sea circulation to ENSO is investigated based on a numerical simulation. The transport anomalies entering the Solomon Sea from the south are confined to the top 250 m of the water column, where they represent 7.5 Sv (based on ENSO composites) for a mean transport of 10 Sv. The induced circulation anomalies in the Solomon Sea are not symmetric between the two ENSO states because of (1) a bathymetric control at Vitiaz Strait, which plays a stronger role during El Niño, and (2) an additional inflow through Solomon Strait during La Niña events. In terms of temperature and salinity, modifications are particularly notable for the thermocline water during El Niño conditions, with cooler and fresher waters compared to the climatological mean. The surface water at Vitiaz Strait and the upper thermocline water at Solomon Strait, feeding respectively the equatorial Pacific warm pool and the Equatorial Undercurrent, particularly affect the heat and salt fluxes. These fluxes can change by up to a factor of 2 between extreme El Niño and La Niña conditions.     

Meshless BEM and overlapping Schwarz preconditioners for exterior problems on spheroids

We consider the exterior Neumann problem of the Laplacian with boundary condition on spheroids. We propose to use spherical radial basis functions in the solution of the boundary integral equation arising from the Dirichlet-to-Neumann map. Our meshless approach with radial basis functions is particularly suitable for handling scattered satellite data. We also propose a preconditioning technique based on an overlapping domain decomposition method to deal with ill-conditioned matrices arising from the approximation problem.     

The international conference “Vortices and coherent structures: from ocean to microfluids”, Vladivostok,Russia, 28–31 August 2017

The international conference “Vortices and coherent structures: from ocean to microfluids” was held at the Pacific Oceanological Institute of the Russian Academy of Sciences in Vladivostok (Russia) from August 28 to August 31, 2017. The event gathered experimentalists and theoreticians, oceanographers and physicists, with a common interest in observing and modelling fluid flows in different media, from the ocean to laboratory flows. It was a fruitful idea to bring together researchers from a variety of backgrounds to benefit from a vigorous discussion of concepts across different disciplines in oceanography and hydrodynamics.