Role of suspended sediments on the distribution of PCB in the Seine Estuary (France)

PCB (polychlorinated biphenyls) contamination and its relationship to SPM (suspended particulate material) have been studied in the Seine Estuary, which is heavily polluted by these persistent and hydrophobic man-made chemicals. Two sampling cruises have been performed during different freshwater discharge conditions. PCB and SPM concentrations, as well as grain-size distributions in the particulate material have been determined. Water samples have been collected at fixed positions during a tidal cycle, and along transects within the estuary.PCB concentrations vary from 2 ng 1⁻¹ in the marine zone to 250 ng 1⁻¹ within the estuary, and reach 1.3 × 10³ ng 1⁻¹ in the turbidity maximum zone. During a tidal cycle, low PCB concentrations are observed at high water, and are in the same range in February as in July. High PCB contamination is observed at low water, but PCB concentrations are about five times higher in February. SPM and PCB variations are well correlated in both periods of observations. Higher PCB contamination during February is explained by higher SPM inputs, mainly due to particles of riverine origin. The transport of PCB within the estuary depends on the quantity and the grainsize composition of suspended material, which varies according to freshwater discharge and tidal amplitude.     

Nankai Trough, Japan Trench and Kuril Trench: geochemistry of Fluids sampled by submersible “Nautile”

Deep-water samples collected during the Kaiko project are often associated with biological communities located on geological structures favorable to fluid venting. The evidence of fluid venting are the temperature anomalies, the decrease in sulfate concentrations, the content in methane and the lowC₁(C₂ +C₃) ratio of light hydrocarbons. Because of large dilution by ambiant seawater during sampling it is difficult to compute the composition of the advected end-member pore fluid. Part of this fluid should originate in the “petroleum window”, i.e. at temperature about 60°C. Modeling the upward flow of water, taking into account the anomalies of temperature measured on the seafloor and the geochemical anomalies, leads to non-steady-state advection of the pore fluid. The occurrence of a deep component in the fluid has implications for the geological and tectonic models of the subduction zones off Japan.     

Noble gas elemental and isotopic abundances in deep-sea trenches in the western Pacific

Noble gas elemental and isotopic abundances were measured in seven deep-sea water samples from five different sampling sites in the Nankai Trough, the Japan Trench and the Kuril Trench. The samples were obtained by the manned submersible “Nautile”. Most of the sampling sites are associated with clam colonies and/or fluid venting. Excesses both in³He/⁴He ratio and He concentration are observed in a seawater sample collected a few kilometers off the clam colonies which were found at a depth of 3830 m at the mouth of the Tenryu Canyon. Concentrations of noble gases (Ne, Ar, Kr and Xe) in this sample show progressive depletion from Ne to Xe relative to those in 1°C air-saturated seawater, which can be attributed to mixing of hot water ( 15°C) with cold ambient water ( 1°C). Isotopic compositions of Ne, Ar, Kr and Xe in this sample are atmospheric. These observations may reflect venting of hot pore water around the Tenryu Canyon. All the other samples show a significant excess in concentration of all noble gases relative to 1°C air-saturated seawater and the isotopic compositions are atmospheric. This excess of noble gas concentrations may appear to be air contamination in the samples. However, results of hydrocarbon analyses of the Kaiko samples imply that such large amount of air contamination is improbable. Decomposition of gas hydrate in deep-sea sediments is a more likely explanation for the observed excess of noble gas concentration.     

Tectonique cassante et champ de contraintes tertiaire en avant des Alpes orientales: le Jura souabe

Résumé La reconnaissance de la fracturation dans le Jura souabe, et son analyse qualitative et quantitative (par traitement informatique) a permis de distinguer cinq épisodes tectoniques cassants, caractérisés successivement par: une distension N-S, des compressions N-S et SW-NE, une distension E-W et une compression ESE-WNW. Ces états de contrainte au sein de la plateforme européenne, en avant de la zone de collision Afrique-Europe, traduisent les mouvements relatifs de ces plaques au cours du Tertiaire.

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Scouting of fracturation in Swabian Jura, and qualitative and quantitative (by informatical treatment) analysis allow to distinguish five breacking tectonic episodes caracterized by: (1) a N-S distension, (2) N-S and (3) NE-SW compressions, (4) a E-W distension and (5) a ESE-WNW compression. These stress fields inside the european platform, in front of collision zone Africa-Europa, attest relative motions of these plates during Tertiary.

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Zusammenfassung Im Schwäbischen Jura lassen die qualitative und die quantitative Aufnahme der Frakturierung sowie ihre EDV-Analyse fünf aufeinander folgende Phasen der tektonischen Beanspruchung (tectonique cassante) erkennen: (1) Zerrung N-S, (2) Kompression N-S und (3) SW-NE, (4) Zerrung E-W, (5) Kompression ESE-WNW. Diese Spannungszustände in der Kollisions-zone von Afrika und Europa vorgelagerten europäischen Plattform geben ein Bild der Relativbewegungen dieser beiden Kontinentalplatten im Tertiär.

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EDV 5 : 1. N-S, 2. N-S 3. SW-NE, 4. E-W, 5. ESE-WNW. .

     

Sulfur speciation and associated trace metals (Fe,Cu) in the pore waters of Great Marsh,Delaware

The pore waters of sediments from a salt marsh along the Delaware estuary have been analyzed for sulfur species and associated trace metals. Since the sediment interface is usually in contact with the atmosphere, the sulfur species are dependent on the production of hydrogen sulfide by sulfate reduction and subsequent oxidation by diffusing oxygen. The most important species observed are hydrogen sulfide, polysulfide ions and thiosulfate. Secondary reactions of hydrogen sulfide and polysulfides with decomposing organic matter yield significant concentrations of both thiols and organic polysulfides. Upon isolation of the sediment from the atmosphere due to tidal inundation, bacterial sulfate reduction becomes the dominant process. This results in the reduction of the polysulfides in agreement with thermodynamic predictions, and suggests that the redox couple sulfide/polysulfide is a good redox indicator under such reducing environments.The concentrations of trace elements Cu and Fe in the pore waters are mainly controlled by sulfide formation. Calculations show that copper is strongly complexed probably with organo-sulfur ligands. Iron might be complexed as such sulfur species to a much lesser extent than copper.     

On the velocity of jets powering hot spots similar to those in Cygnus A

Hot spots similar to those in the radio galaxy Cygnus A can be explained by the strong shock produced by a supersonic but classical jet \(\left( {u_{jet}< c/\sqrt 3 } \right)\) . The high integrated radio luminosity (L?2×10⁴⁴ erg s^?1) and the strength of mean magnetic field (B?2×10^?4 G) suggest the hot spots are the downstream flow of a very strong shock which generates the ultrarelativistic electrons of energy ?≥20 MeV. The fully-developed subsonic turbulence amplifies the magnetic field of the jet up to 1.6×10^?4 G by the dynamo effect. If we assume that the post-shock pressure is dominated by relativistic particles, the ratio between the magnetic energy density to the energy density in relativistic particles is found to be ?2×10^?2, showing that the generally accepted hypothesis of equipartition is not valid for hot spots. The current analysis allows the determination of physical parameters inside hot spots. It is found that:

1. The velocity of the upstream flow in the frame of reference of the shock isu ₁?0.2c. Radio observations indicate that the velocity of separation of hot spots isu _sep?0.05c, so that the velocity of the jet isu _jet=u ₁+u _sep?0.25c.
2. The density of the thermal electrons inside the hot spot isn ₂?5×10^?3 e ^? cm^?3 and the mass ejected per year to power the hot spot is ?4M ₀yr^?1.
3. The relativistic electron density is less than 20% of the thermal electron density inside the hot spot and the spectrum is a power law which continues to energies as low as 30 MeV.
4. The energy density of relativistic protons is lower than the energy density of relativistic electrons unlike the situation for cosmic rays in the Galaxy.

     

Mn-oxide: a major source of easily mobilisable Co and Ni under reducing conditions in New Caledonia FerralsolsLes oxydes de Mn : une source majeure de Co et Ni facilement mobilisables en conditions réductrices dans les Ferralsols de Nouvelle-Calédonie

Chemical and bacterial reduction and dissolution of Fe and Mn-oxide and the concomitant solubilisation of Co and Ni were studied in a surface horizon of a New-Caledonia Ferralsol. Chemical extractions showed that Mn and Co were in a large part associated in Mn-oxides. The main part of Ni was associated with goethite, but a very small fraction was also associated with Mn-oxides. Anaerobic reducing bacterial activity was responsible for Fe solubilisation at a smaller extent than for Mn solubilisation and consequently for associated metal release. Submicroscopic investigations revealed the presence of a Mn-oxide containing Co, Ni and Al, close to a lithiophorite–asbolane mixed-layers Mn-oxide, which can be considered as a main source of easily available metals in this soil. To cite this article: C. Quantin et al., C. R. Geoscience 334 (2002) 273–278.     

Premières mesures françaises de gravimétrie absolue dans les régions polaires Antarctique (terre Adélie) et Arctique (Spitzberg)First French measurements of absolute gravity in the Antarctic (Terre Adélie) and Arctic (Spitsbergen) polar regions

This study is devoted to the first French determinations of absolute gravity in the Antarctic (Dumont-d'Urville, Terre Adélie) and Arctic (Ny-Alesund, Spitsbergen) polar regions. The measurements in Dumont-d'Urville were performed in 2000 with the help of the FG5#206 absolute gravimeter belonging to the French geodetic community since beginning 1997; they show a strong noise that causes an uncertainty close to 11 μGal in the determination of the mean gravity value, which will be compared, to a new determination planned for 2005. The Ny-Alesund measurements show on the contrary a noise that, although very variable in time, leads to a gravity determination of better than 5 μGal. The comparison of our value with a previous one two years before suggests a gravity decrease of about 4 μGal which is related to the vertical uplift measured by Very Large Baseline Interferometry (VLBI) at the same site. However, the uncertainty does not allow discriminating between height-to-gravity conversion factors originating from different models. To cite this article: J. Hinderer et al., C. R. Geoscience 334 (2002) 819–826.