The Vendian record of Sr and C isotopic variations in seawater: Implications for tectonics and paleoclimate

New Sr and C isotopic data, both obtained on the same samples of marine carbonates, provide a relatively detailed record of isotopic variation in seawater through the latest Proterozoic and allow, for the first time, direct correlation of these isotopic changes in the Vendian ( 540–610 Ma). The strong isotope variations determined in this study record significant environmental and tectonic changes. Together with a fairly poorly constrained Nd isotopic record, the Sr and C isotopic records can be used to constrain rates of erosion, hydrothermal alteration and organic C burial. Further, comparison of these records with those of the Cenozoic permit investigation of the general relationship between global tectonics and continental glaciation. In particular, results of this study show a very large change in the ⁸⁷Sr/⁸⁶Sr of marine carbonates from low pre-Vendian ( > 610 Ma) values ( 0.7066) to high Middle Cambrian values ( 0.7090). This change is greater in magnitude than the significant increase in seawater ⁸⁷Sr/⁸⁶Sr through the Cenozoic. Both changes are attributed to high erosion rates associated with continent-continent collisions (Pan-African and Himalayan-Tibetan). In the latest Proterozoic these high erosion rates, probably coupled with high organic productivity and anoxic bottom-water conditions, contributed to a significant increase in the burial rate of organic C. Ice ages mark both the Neoproterozoic and Cenozoic, but different stratigraphic relationships between the Sr isotopic increase and continental glaciation indicate that uplift-driven models proposed to explain Cenozoic climatic change cannot account for the latest Proterozoic ice ages.     

REE in the Great Whale River estuary, northwest Quebec

We report rare earth element (REE) concentrations of a longitudinal profile within the estuary of the Great Whale River in northwest Quebec and in Hudson Bay. All of the measured REE have concentrations less than those predicted by conservative mixing of seawater and river water, demonstrating removal of the REE from solution. REE removal is rapid, occurring primarily at salinities less than 2‰. Removal of the REE is greatest for the light REE, and ranges from about 7% for the light REE to no more than 40% for the heavy REE. Fe removal is essentially complete at low salinity. The shape of the Fe and REE vs. salinity profiles is not consistent with a simple model of destabilization and coagulation of iron and REE-bearing colloidal material. A linear relationship between the activity of free ion REE³⁺ and pH is consistent with a simple ion-exchange model for REE removal.Surface and subsurface samples of Hudson Bay seawater are characterized by high REE concentrations and high La/Yb relative to average seawater. The subsurface sample has a Nd concentration of 100 pmol/kg and an ε_Nd of −29.3 ± 0.3. These characteristics are consistent with the high REE concentration, high La/Yb, and low ε_Nd of river inputs into Hudson Bay. These results indicate that rivers draining the Canadian Shield are a major source of non-radiogenic Nd and REE to the Atlantic Ocean. We estimate that outflow of water from Hudson Bay to the Labrador Sea could supply ≈ 30% of the non-radiogenic Nd in North Atlantic Deep Water.     

POLAR 5—an electron accelerator experiment within an aurora. 2. Scattering of an artificially produced electron beam in the atmosphere

The interaction between an artificially produced narrow beam of electrons and the upper atmosphere has been studied by the POLAR 5 electron accelerator “mother”-“daughter” rocket. It is shown how the beam develops a “halo” of scattered electrons and how the low energy electron population in this “halo” is produced partly during the ionization process (at low altitudes), partly by a “wave-plasma” interaction which accelerates the ionospheric background electrons.     

Gottfried Konecny:The photogrammetric and remote sensing trend setter

PREFACE There are various publications on the 90th birthday of Gottfried Konecny.His involvement in the International Society for Photogrammetry and Remote Sensing(ISPRS)is particularly described by others.Here,his forward-oriented impulses in research and development at the former Institute for Photogrammetry and Engineering Survey of the(Technical)University of Hannover,today Institute for Photogrammetry and Geoinformation,Leibniz University Hannover,and some of his activities supporting developing and other countries by given short-term courses are highlighted.Gottfried Konecny was always one of the first in pushing new technologies.With the analytical plotter AP/C-3,he introduced analytical photogrammetry in Germany.Based on his experience with this not really operational version,he induced the company Zeiss to develop the first really operational analytical plotter Planicomp,which resulted in the end of analog photogrammetric devices and their limitations.At the invitation of Gilbert Hobrough,a mainly hardware-based image correlator was developed for the AP/C-3 in Hannover which anticipated many of today's applications.Gottfried Konecny initiated remote sensing in Germany.Based on his proposal with the Metric Camera Flight on Spacelab,the then highest resolution civil stereoscopic space images available were generated.Despite limited computer performance at his institute,a digital stereo plotter was developed,using hardware components from the cooperating Swedish company Context Vision,long before digital stereo workstations with increased and affordable computer capacity were possible.Also,in the area of GIS,he too,pushed development in collaboration with companies and administrations.Shortly before the end of his time as head of the institute,and more so after he became emeritus professor,he started a series of educational workshops,particularly in developing countries,but also other countries,to support the development of photogram-metry,remote sensing and GIS.He promoted the use of space imagery for mapping to improve the situation of poorly updated topographic maps.     

Al–Mg and Pb–Pb systematics of Allende CAIs: Canonical solar initial Al/Al ratio reinstated

The precise knowledge of the initial ²⁶Al/²⁷Al ratio [(²⁶Al/²⁷Al)₀] is crucial if we are to use the very first solid objects formed in our Solar System, calcium–aluminum-rich inclusions (CAIs) as the “time zero” age-anchor and guide future work with other short-lived radio-chronometers in the early Solar System, as well as determining the inventory of heat budgets from radioactivities for early planetary differentiation. New high-precision multi-collector inductively-coupled plasma mass spectrometry (MC-ICP-MS) measurements of ²⁷Al/²⁴Mg ratios and Mg-isotopic compositions of nine whole-rock CAIs (six mineralogically characterized fragments and three micro-drilled inclusions) from the CV carbonaceous chondrite, Allende yield a well-defined ²⁶Al–²⁶Mg fossil isochron with an (²⁶Al/²⁷Al)₀ of (5.23 ± 0.13) × 10^− 5. Internal mineral isochrons obtained for three of these CAIs (A44A, AJEF, and A43) are consistent with the whole-rock CAI isochron. The mineral isochron of AJEF with (²⁶Al/²⁷Al)₀ = (4.96 ± 0.25) × 10^− 5, anchored to our precisely determined absolute ²⁰⁷Pb–²⁰⁶Pb age of 4567.60 ± 0.36 Ma for the same mineral separates, reinstate the “canonical” (²⁶Al/²⁷Al)₀ of 5 × 10^− 5 for the early Solar System. The uncertainty in (²⁶Al/²⁷Al)₀ corresponds to a maximum time span of ± 20 Ka (thousand years), suggesting that the Allende CAI formation events were culminated within this time span. Although all Allende CAIs studied experienced multistage formation history, including melting and evaporation in the solar nebula and post-crystallization alteration likely on the asteroidal parent body, the ²⁶Al–²⁶Mg and U–Pb-isotopic systematics of the mineral separates and bulk CAIs behaved largely as closed-system since their formation. Our data do not support the “supra-canonical” ²⁶Al/²⁷Al ratio of individual minerals or their mixtures in CV CAIs, suggesting that the supra-canonical ²⁶Al/²⁷Al ratio in the CV CAIs may have resulted from post-crystallization inter-mineral redistribution of Mg isotopes within an individual inclusion. This redistribution must be volumetrically minor in order to satisfy the mass balance of the precisely defined bulk CAI and bulk mineral data obtained by MC-ICP-MS.The radiogenic ²⁰⁸Pb/²⁰⁶Pb ratio obtained as a by-product from the Pb–Pb age dating is used to estimate time-integrated ²³²Th/²³⁸U ratio (κ value) of CAIs. Limited κ variations among the minerals within a single CAI, contrasted by much larger variations among the bulk CAIs, suggest Th/U fractionation occurred prior to crystallization of igneous CAIs. If interpreted as primordial heterogeneity, the κ value can be used to calculate the mean age of the interstellar dust from which the CAIs condensed.     

Determining flow patterns and emplacement dynamics from tsunami deposits with no visible sedimentary structure

In the absence of eyewitness reports or clear sedimentary structures, it can be difficult to interpret tsunami deposits or reconstruct tsunami inundation patterns. The emplacement dynamics of two historical tsunami deposits were investigated at seven transects in Okains Bay, New Zealand, using a combined geospatial, geomagnetic and sedimentological approach. The tsunami deposits are present as layers of sand and silt intercalated between soils and become finer and thinner with distance inland. The deposits are attributed to the 1960 and possibly the 1868 tsunamis, based on radiometric dating and correlation with historical records. Measurements of Magnetic Fabric (MF: Anisotropy of Magnetic Susceptibility) and particle size were used to reconstruct the evolution of flow dynamics laterally and vertically. A combination of statistical methods, including spatial autocorrelation testing, Spearman's rank order correlation, Principal Component Analysis (PCA) and K‐means cluster analysis, was applied to examine relationships between MF parameters and sediment texture, and infer depositional hydrodynamics. Flow patterns deduced from MF show the estuary channel acted as a conduit for inundation, with flow commonly aligned sub‐perpendicular to the estuary bed. MF and sediment data suggest deposition occurred from settling during laminar flow. Evidence of both uprush and backwash deposition, as well as wave reflection from infrastructure, was found. Statistical analysis of data showed significant relationships between grain size parameters and MF parameters associated with flow speed and magnetic fabric type. PCA and cluster analysis differentiated samples into two primary hydrodynamic groups: (1) samples deposited from laminar flow; and (2) samples deposited close to the limit of inundation, which includes samples deposited further inland, those affected by flow convergence, and those in the upper part of tsunami deposits. This approach has potential as a tool for reconstructing hydrodynamic conditions for palaeotsunamis and by combining spatial and statistical analyses, large‐scale investigations can be more easily performed. Copyright © 2016 John Wiley & Sons, Ltd.     

Stable calcium isotopic compositions of Hawaiian shield lavas: Evidence for recycling of ancient marine carbonates into the mantle

We report high-precision ⁴⁴Ca/⁴⁰Ca measurements (2σ_m < 0.06‰) of Hawaiian shield stage tholeiites. Our data reveal ∼0.3‰ variation in their ⁴⁴Ca/⁴⁰Ca, which comprises ∼20% of the ⁴⁴Ca/⁴⁰Ca variation observed in global carbonates. The ⁴⁴Ca/⁴⁰Ca variation is correlated with Sr/Nb and ⁸⁷Sr/⁸⁶Sr, and this pattern is best explained by adding up to 4% ancient carbonate into the Hawaiian plume. Mass-balance calculations show that up to 40% of the Ca budget and 65% of the Sr budget in some Hawaiian (Makapuu-stage Koolau) lavas are derived from recycled carbonates. Our finding demonstrates, for the first time with the application of Ca isotopes, that ancient recycled carbonates are important components of mantle plumes which feed some of the largest terrestrial volcanoes. Thus, recycling of carbonates into the mantle is an essential part of the global Ca and C cycles.     

Invasion genetics of Pacific oyster Crassostrea gigas shaped by aquaculture stocking practices

As a result of aquaculture activities Pacific oysters Crassostrea gigas (Thunberg, 1793) have invaded the European Wadden Sea. Using a variable noncoding mitochondrial marker, we show that the invaded range is the result of two independent invasions. Haplotype frequencies point towards two separate groups, one in the southern and the other in the northern Wadden Sea. We found virtually no genetic differentiation throughout the southern range and the putative source from British Columbia, Canada, suggesting that the Southern region can be considered as a closed population. In the North, mismatch distributions, haplotype ordination and isolation-by-distance analysis suggest a stronger, persistent impact of aquaculture on invasive populations. Due to the ongoing supply of new genetic material from hatchery production the northern invasive populations can therefore be considered as an open population highlighting the importance of aquaculture practice on the genetics of this keystone invader in the Wadden Sea.     

A chronology for the long pollen record from Lake Wangoom,western Victoria (Australia) as derived from uranium/thorium disequilibrium dating

The chronology of a long pollen record from Lake Wangoom, one of the few long palaeoenvironmental records from southeastern Australia, is discussed in light of the acquisition of new uranium/thorium disequilibrium (UTD) dates. Of crucial importance has been the estimation of ages for two major pre‐Holocene phases of forest expansion recorded in the sequence, with implications for the timing of periods of high effective precipitation in the region. The new UTD ages indicate that the oldest forest phase falls within the Penultimate Interglacial whereas the later phase corresponds with the Last Interglacial. This is older than indicated by previously reported UTD and radiocarbon dates, but confirms a chronology based on direct correlation with the pollen record from marine core E55‐6. The new chronology of the Lake Wangoom sequence provides evidence that phases of sustained forest development in southeast Australia relate to interglacial periods. In comparison, interstadial periods appear to be characterised by only minor arboreal development. Marked differences in the pattern of vegetation development evident in each of the interglacials are thought to reflect varying climatic and anthropogenic influences. Copyright © 2002 John Wiley & Sons, Ltd.