Glacial flood pulse effects on benthic fauna in equatorial high‐Andean streams

Equatorial glacier‐fed streams present unique hydraulic patterns when compared to glacier‐fed observed in temperate regions as the main variability in discharge occurs on a daily basis. To assess how benthic fauna respond to these specific hydraulic conditions, we investigated the relationships between flow regime, hydraulic conditions (boundary Reynolds number, Re*), and macroinvertebrate communities (taxon richness and abundance) in a tropical glacier‐fed stream located in the high Ecuadorian Andes (> 4000 m). Both physical and biotic variables were measured under four discharge conditions (base‐flow and glacial flood pulses of various intensities), at 30 random points, in two sites whose hydraulic conditions were representative to those found in other streams of the study catchment. While daily glacial flood pulses significantly increased hydraulic stress in the benthic habitats (appearance of Re* > 2000), low stress areas still persisted even during extreme flood events (Re* < 500). In contrast to previous research in temperate glacier‐fed streams, taxon richness and abundance were not significantly affected by changes in hydraulic conditions induced by daily glacial flood pulses. However, we found that a few rare taxa, in particular rare ones, preferentially occurred in highly stressed hydraulic habitats. Monte‐Carlo simulations of benthic communities under glacial flood reduction scenarios predicted that taxon richness would be significantly reduced by the loss of high hydraulic stress habitats following glacier shrinking. This pioneer study on the relationship between hydraulic conditions and benthic diversity in an equatorial glacial stream evidenced unknown effects of climate change on singular yet endangered aquatic systems. Copyright © 2013 John Wiley & Sons, Ltd.     

Glacial stratigraphy of East and Central Jutland

Glaciostratigraphic investigations at one key locality (Haldum), 9 major and about 160 minor localities in East and Central Jutland, Denmark, together with laboratory work, have led to the establishment of a stratigraphy consisting of 10 till units, usually separated by meltwater deposits. The stratigraphy is in some degree supported by thermoluminescence datings. The complete sequence includes one till unit with associated meltwater deposits of Menapian age, three till units with intercalated meltwater deposits of Elsterian age, marine sediments deposited during the Holsteininan, and three till units with intercalated of Elsterian age, marine sediments deposited during the Holsteinian, and three till units with intercalated glaciofluvial sedimants of Saalian age. Eemian deposits are present above this level, and the whole sequence is capped by till and meltwater deposits related to three glacial advances during the Weichselian.     

Performance of Full‐Scale Enhanced Reductive Dechlorination in Clay Till

At a low permeability clay till site contaminated with chlorinated ethenes (Gl. Kongevej, Denmark), enhanced reductive dechlorination (ERD) was applied by direct push injection of molasses and dechlorinating bacteria. The performance was investigated by long‐term groundwater monitoring, and after 4 years of remediation, the development of degradation in the clay till matrix was investigated by high‐resolution subsampling of intact cores. The formation of degradation products, the presence of specific degraders Dehalococcoides spp. with the vinyl chloride (VC) reductase gene vcrA, and the isotope fractionation of trichloroethene, cis‐dichloroethene (cis‐DCE), and VC showed that degradation of chlorinated ethenes occurred in the clay till matrix as well as in sand lenses, sand stringers, and fractures. Bioactive sections of up to 1.8 m had developed in the clay till matrix, but sections, where degradation was restricted to narrow zones around sand lenses and stringers, were also observed. After 4 years of remediation, an average mass reduction of 24% was estimated. Comparison of the results with model simulation scenarios indicate that a mass reduction of 85% can be obtained within approximately 50 years without further increase in the narrow reaction zones if no donor limitations occur at the site. Long‐term monitoring of the concentration of chlorinated ethenes in the underlying chalk aquifer revealed that the aquifer was affected by the more mobile degradation products cis‐DCE and VC generated during the remediation by ERD.     

Interpretation of Nd,Sr and Pb isotope data from Archean migmatites in Lofoten-Vesterålen,Norway

Sm-Nd data for the Archean granulite and amphibolite facies migmatites of Langøy and Hinnøy in Vesterålen are presented which indicate that their protoliths formed ～2.6 AE ago. Rubidium and U loss during a granulite facies metamorphism at ～1.8 AE caused serious disturbance of total-rock U-Pb and Rb-Sr systems. Therefore these systems do not provide any precise age information for the granulite facies migmatites. For the amphibolite facies migmatites of Vesterålen both SmNd, RbSr and PbPb total-rock systems give model ages of ～2.6 AE. The results on both granulite and amphibolite facies rocks are thus in agreement. Previous interpretations based on PbPb data, which indicated an age of 3.41 AE for the Archean terrane of Vesterålen, are not valid.One SmNd model age from the granulite facies migmatites at Moskenesøy in Lofoten indicates that the protoliths of these migmatites formed ～2.0 AE ago and are thus not related to the Vesterålen migmatites.     

Integrated chronostratigraphy of Proterozoic-Cambrian boundary beds in the western Anabar region, northern Siberia

Carbonate-rich sedimentary rocks of the western Anabar region, northern Siberia, preserve an exceptional record of evolutionary and biogeochemical events near the Proterozoic/Cambrian boundary. Sedimentologically, the boundary succession can be divided into three sequences representing successive episodes of late transgressive to early highstand deposition; four parasequences are recognized in the sequence corresponding lithostratigraphically to the Manykal Formation. Small shelly fossils are abundant and include many taxa that also occur in standard sections of southeastern Siberia. Despite this coincidence of faunal elements, biostratigraphic correlations between the two regions have been controversial because numerous species that first appear at or immediately above the basal Tommotian boundary in southeastern sections have first appearances scattered through more than thirty metres of section in the western Anabar. Carbon- and Sr-isotopic data on petrographically and geochemically screened samples collected at one- to two-metre intervals in a section along the Kotuikan River, favour correlation of the Staraya Reckha Formation and most of the overlying Manykai Formation with sub-Tommotian carbonates in southeastern Siberia. In contrast, isotopic data suggest that the uppermost Manykai Formation and the basal 26 m of the unconformably overlying Medvezhya Formation may have no equivalent in the southeast; they appear to provide a sedimentary and palaeontological record of an evolutionarily significant time interval represented in southeastern Siberia only by the sub-Tommotian unconformity. Correlations with radiometrically dated horizons in the Olenek and Kharaulakh regions of northern Siberia suggest that this interval lasted approximately three to six million years, during which essentially all 'basal Tommotian' small shelly fossils evolved.     

Late Holocene environmental changes and anthropogenic impact in Dee Why Lagoon,New South Wales

Late Holocene environmental changes were examined in Dee Why Lagoon, New South Wales, based on the sedimentological, geochemical and geochronological analysis of six cores collected from the fluvial delta and lagoon basin. The lagoon formed about 7300–7200?cal yr BP, following the post-glacial marine transgression and establishment of a sand barrier. Infilling of the lagoon occurred at a rate of 0.09–0.15?mm/yr until about 3300–3200?cal yr BP, when the barrier closed, resulting in mostly freshwater conditions, as evidenced by a change from pyrite-rich units to sediment containing little sulfur and a lack of foraminifera. Sedimentation rates increased to 0.23 then 0.43?mm/yr until about 100?years ago. Post-European land clearance led to an increase in sedimentation rates to 1.0–1.3?mm/yr on the fluvial delta, which are lower than those from other wave-dominated estuaries in New South Wales as well as those estimated by previous studies in Dee Why Lagoon. Our study shows that the fluvial delta started forming much earlier than originally thought, based on results of radiometric dating, and confirmed using sedimentological and geochemical data, as well as a critical examination of historic aerial photographs. Human impact has resulted in an increase in heavy metal (Cu, Pb, Zn) and metalloid (As) concentrations in the recent sediment, most likely attributed to stormwater discharge. Pb and As concentrations are above the ANZECC high sediment quality guideline values at the site closest to the stormwater outlet, with As-based pesticides one of the possible sources. Using the mean enrichment quotient, which is based on normalised Cu, Pb and Zn concentrations over their normalised background concentrations, we show that the surface sediments in Dee Why Lagoon are severely enriched, reflecting the recent anthropogenic impact that has also led to an increase in sedimentation rates.     

26Al‐26Mg isotope systematics of the first solids in the early solar system

High‐precision bulk aluminum‐magnesium isotope measurements of calcium‐aluminum‐rich inclusions (CAIs) from CV carbonaceous chondrites in several laboratories define a bulk ²⁶Al‐²⁶Mg isochron with an inferred initial ²⁶Al/²⁷Al ratio of approximately 5.25 × 10^?5, named the canonical ratio. Nonigneous CV CAIs yield well‐defined internal ²⁶Al‐²⁶Mg isochrons consistent with the canonical value. These observations indicate that the canonical ²⁶Al/²⁷Al ratio records initial Al/Mg fractionation by evaporation and condensation in the CV CAI‐forming region. The internal isochrons of igneous CV CAIs show a range of inferred initial ²⁶Al/²⁷Al ratios, (4.2–5.2) × 10^?5, indicating that CAI melting continued for at least 0.2 Ma after formation of their precursors. A similar range of initial ²⁶Al/²⁷Al ratios is also obtained from the internal isochrons of many CAIs (igneous and nonigneous) in other groups of carbonaceous chondrites. Some CAIs and refractory grains (corundum and hibonite) from unmetamorphosed or weakly metamorphosed chondrites, including CVs, are significantly depleted in ²⁶Al. At least some of these refractory objects may have formed prior to injection of ²⁶Al into the protosolar molecular cloud and its subsequent homogenization in the protoplanetary disk. Bulk aluminum and magnesium‐isotope measurements of various types of chondrites plot along the bulk CV CAI isochron, suggesting homogeneous distribution of ²⁶Al and magnesium isotopes in the protoplanetary disk after an epoch of CAI formation. The inferred initial ²⁶Al/²⁷Al ratios of chondrules indicate that most chondrules formed 1–3 Ma after CAIs with the canonical ²⁶Al/²⁷Al ratio.     

Organic matter from comet 81P/Wild 2, IDPs,and carbonaceous meteorites; similarities and differences

Abstract— During preliminary examination of 81P/Wild 2 particles collected by the NASA Stardust spacecraft, we analyzed seven, sulfur embedded and ultramicrotomed particles extracted from five different tracks. Sections were analyzed using a scanning transmission X‐ray microscope (SXTM) and carbon X‐ray absorption near edge structure (XANES) spectra were collected. We compared the carbon XANES spectra of these Wild 2 samples with a database of spectra on thirty‐four interplanetary dust particles (IDPs) and with several meteorites. Two of the particles analyzed are iron sulfides and there is evidence that an aliphatic compound associated with these particles can survive high temperatures. An iron sulfide from an IDP demonstrates the same phenomenon. Another, mostly carbon free containing particle radiation damaged, something we have not observed in any IDPs we have analyzed or any indigenous organic matter from the carbonaceous meteorites, Tagish Lake, Orgueil, Bells and Murchison. The carbonaceous material associated with this particle showed no mass loss during the initial analysis but chemically changed over a period of two months. The carbon XANES spectra of the other four particles varied more than spectra from IDPs and indigenous organic matter from meteorites. Comparison of the carbon XANES spectra from these particles with 1. the carbon XANES spectra from thirty‐four IDPs (<15 micron in size) and 2. the carbon XANES spectra from carbonaceous material from the Tagish Lake, Orgueil, Bells, and Murchison meteorites show that 81P/Wild 2 carbon XANES spectra are more similar to IDP carbon XANES spectra then to the carbon XANES spectra of meteorites.