Prediction of hydrothermal copper, gold, silver and lead-zinc in northwestern Yunnan using weight of evidence model

This paper discusses the application of the model in predicting for hydrothermal Cu, Ag, Au and Pb-Zn occurrences in northwestern Yunnan. Geochemical, lineament and lithology data were the selected recognition criteria. The mentioned criteria varied against 75 known hydrothermal occurrences; the geochemical data had a weight of （W^＋= 1. 209 7, W^- =-0. 748 1） being the maximum among the three and the rest lineament and lithology have （W^＋= 0.7424, W^-= -0.449 6）, （W^＋= 0.378 7,W^-=-0.6243） respectively. The application was successful since the predicted results covers about 70% of the known deposits and predicted unknown areas.     

Oxidation state of iron and extensive redistribution of sulfur in thermally modified Stardust particles

Two representative thermally modified Stardust samples were investigated by analytical transmission electron microscopy in order to decipher their iron oxidation state after the strong thermal episode due to the capture in aerogel. Their dominant microstructure consists of evenly distributed rounded Fe-Ni-S nano-droplets within a silica-rich glassy matrix. The mineralogy and associated redox state of iron is assessed using a Fe-Mg-S ternary diagram on which ferromagnesian silicates, sulfides and metal can be represented and potentially compared with any other extraterrestrial material. In this diagram, all the data (bulk and local analysis of silicates, sulfide + metal) scatter along a mixing line between the Mg corner and the average composition of the iron-sulfide. There is an obvious genetic relationship between the different phases observed in such samples, further supported by the very low concentration of iron in the glassy matrix. Silicate glasses contain a significant concentration of dissolved sulfur probably present as MgS complexes. This chemical signature is typical of highly reduced environments. These secondary microstructures were established during the high temperature stage of the capture. A significant part of the Fe-droplets formed in situ by reduction at high temperature of ferromagnesian silicates (olivine and pyroxenes) during the impact. At this stage, the indigenous sulfides destabilized and sulfur readily volatilized as S₂, diffused into molten materials and condensed later onto the Fe-precipitates that formed in the silicate melt. This scenario is supported by the structure of Fe-Ni-S beads with a metal core and a sulfide rim. It will be difficult to derive reliable information on the redox state of 81P/Wild 2 particles based on bulk analyses of whole tracks because particles found along the walls of tracks suffered strong reduction reactions, contrary to terminal particles that may have preserved their pristine redox state. The capture effect must be taken into account for comparison of Wild 2 particles with other chondritic material.     

A method for using a fully coupled climate system model to generate detailed surface boundary conditions for paleoclimate modeling investigations: an early Paleogene example

Although fully coupled models of the earth system are now common, simpler model architectures maintain significant utility, and scientific investigations aimed at understanding paleoclimates are frequently conducted with fixed sea surface temperature (SST) or slab ocean modeling experiments. One of the challenges facing the paleoclimate community is that the proxy data used to generate SST boundary conditions exist at a finer resolution and with very limited spatial coverage when compared to a climate model. In addition, SST proxy estimates often represent a single season or annual average conditions. This mismatch in coverage and resolution frequently results in paleoclimate modelers using SST distributions that have very limited spatial and temporal variability. In many regions, a spatially and temporally detailed SST distribution may be necessary for the accurate reproduction of paleoclimatic conditions. Here we borrow from the concept of flux correction and, using available proxy estimates of SST as our guide, force a fully coupled earth system model to produce a spatially and temporally detailed SST distribution for the paleoclimate of the early Paleogene (45–65 Ma). The SST values we produce represent a conservative estimate of early Paleogene high latitude SSTs and match tropical temperatures for this time period well. In addition to matching proxy estimates, our model-derived SST distribution has spatial and temporal variability that meshes well with global climate model resolution. This detailed SST distribution is now available to us as we investigate the causes and sensitivities of early Paleogene climate in fixed SST and slab ocean modeling experiments. The method we used to generate this spatially and temporally detailed SST distribution may prove useful for those investigating other time periods in the past, or the future, for which detailed model boundary conditions are unavailable.     

Highly pure placer gold formation in the Nilambur Valley,Wynad Gold Field,southern India

Placer gold grains in the Nilambur Valley of Wynad Gold Field in southern India are characterized by very high purity levels (985–1000). Their Ag-depleted core compositions, enhanced grain size and microscale growth patterns correlate with gold grains associated with laterite profiles in the weathering fronts. From the morphological and chemical evolution of gold grains associated with primary, supergene and secondary deposits in this region, we identified a two-stage process for the evolution of the highly pure placers, which shows that gold in the primary veins was mobilized, chemically purified, and reconcentrated in the laterite profiles, effecting enhanced purity and grain growth before transfer to the fluvial system. Further refinement was achieved during fluvial transport, generating natural concentrations of pure gold in the placers.     

The ubiquitous nature of accessory calcite in granitoid rocks: Implications for weathering, solute evolution, and petrogenesis

Calcite is frequently cited as a source of excess Ca, Sr and alkalinity in solutes discharging from silicate terrains yet, no previous effort has been made to assess systematically the overall abundance, composition and petrogenesis of accessory calcite in granitoid rocks. This study addresses this issue by analyzing a worldwide distribution of more than 100 granitoid rocks. Calcite is found to be universally present in a concentration range between 0.028 to 18.8 g kg⁻¹ (mean = 2.52 g kg⁻¹). Calcite occurrences include small to large isolated anhedral grains, fracture and cavity infillings, and sericitized cores of plagioclase. No correlation exists between the amount of calcite present and major rock oxide compositions, including CaO. Ion microprobe analyses of in situ calcite grains indicate relatively low Sr (120 to 660 ppm), negligible Rb and ⁸⁷Sr/⁸⁶Sr ratios equal to or higher than those of coexisting plagioclase. Solutes, including Ca and alkalinity produced by batch leaching of the granitoid rocks (5% CO₂ in DI water for 75 d at 25°C), are dominated by the dissolution of calcite relative to silicate minerals. The correlation of these parameters with higher calcite concentrations decreases as leachates approach thermodynamic saturation. In longer term column experiments (1.5 yr), reactive calcite becomes exhausted, solute Ca and Sr become controlled by feldspar dissolution and ⁸⁷Sr/⁸⁶Sr by biotite oxidation. Some accessory calcite in granitoid rocks is related to intrusion into carbonate wall rock or produced by later hydrothermal alteration. However, the ubiquitous occurrence of calcite also suggests formation during late stage (subsolidus) magmatic processes. This conclusion is supported by petrographic observations and ⁸⁷Sr/⁸⁶Sr analyses. A review of thermodynamic data indicates that at moderate pressures and reasonable CO₂ fugacities, calcite is a stable phase at temperatures of 400 to 700°C.