Effect of chlorine on near‐liquidus crystallization of olivine‐phyric shergottite NWA 6234 at 1 GPa: Implication for volatile‐induced melting of the Martian mantle

Martian magmas are thought to be rich in chlorine compared with their terrestrial counterparts. Here, we experimentally investigate the effect of chlorine on liquidus depression and near‐liquidus crystallization of olivine‐phyric shergottite NWA 6234 and compare these results with previous experimental results on the effect of chlorine on near‐liquidus crystallization of the surface basalts Humphrey and Fastball. Previous experimental results showed that the change in liquidus temperature is dependent on the bulk composition of the basalt. The effect of chlorine on liquidus depression is greater for lower SiO₂ and higher Al₂O₃ magmas than for higher SiO₂ and lower Al₂O₃ magmas. The bulk composition for this study has lower Al₂O₃ and higher FeO contents than previous work; therefore, we provide additional constraints on the effect of the bulk composition on the influence of chlorine on near‐liquidus crystallization. High pressure and temperature crystallization experiments were performed at 1 GPa on a synthetic basalt, of the bulk composition of NWA 6234, with 0–4 wt% Cl added to the sample as AgCl. The results are consistent with previous notions that with increasing wt% Cl in the melt, the crystallization temperature decreases. Importantly, our results have a liquidus depression ?T (°C) from added chlorine that is consistent with the difference in bulk composition and suggest a dependence on both the bulk Al₂O₃ and FeO content. Our results suggest that the addition of chlorine to the Martian mantle may lower magma genesis temperatures and potentially aid in the petrogenesis of Martian magmas.     

Terpenoid composition and origin of amber from the Cape York Peninsula,Australia

The terpenoid composition of fossil resin from the Cape York Peninsula, Australia has been analysed by pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS) to determine its origin. The pyrolysis products were dominated by cadalene-based C₁₅ bicyclic sesquiterpenoids including some C₃₀–C₃₁ bicadinanes and bicadinenes typical of Class II resin derived from angiosperm plants of Dipterocarpaceae. This observation contrasts with the Araucariaceae (Agathis sp.) source previously suggested for the resin based on Fourier transform infrared (FTIR) analyses. Dipterocarpaceae are not known in Australian vegetation but grow abundantly in Southeast Asia including New Guinea, indicating that the geological origin of the amber is not the Australian mainland but could be traced to Southeast Asia.     

Desiccation-Induced Volumetric Shrinkage of Compacted Foundry Sand Treated with Cement Kiln Dust

Foundry sand, an industrial waste, was treated with up to 12 % cement kiln dust content at comparative energy levels of British standard light, West African standard or “intermediate” (WAS) and British standard heavy (BSH) efforts at molding water contents ?2, 0, 2, 4 and 6 % of optimum moisture content. Samples were extruded from the compaction molds and allowed to air dry in the laboratory in order to assess the effect of desiccation-induced shrinkage on the material for use as a hydraulic barrier in waste containment application. Results recorded show that volumetric shrinkage strain (VSS) values were large within the first 5 days of drying; VSS values increased with higher molding water content, water content relative to the optimum moisture content. VSS generally increased with higher initial degree of saturation for all compactive efforts, irrespective of the level of cement kiln dust (CKD) treatment. A compaction plane of acceptable zones for VSS based on the regulatory value is ≤4 %. The influence of CKD treatment generally showed a decrease in the desiccation-induced volumetric shrinkage strain with increasing CKD content. This is largely due to the pozzolanic input of CKD. Finally, only the BSH compactive effort gave successful results of volumetric shrinkage strain at CKD treatment content of between 4 and 8 %, while 12 % CKD content produced successful volumetric shrinkage strain results at WAS and BSH compactive effort, respectively.     

Focused groundwater discharge of phosphorus to a eutrophic seepage lake (Lake Væng, Denmark): implications for lake ecological state and restoration

A study on Lake Væng in Denmark demonstrates a high potential for loading of phosphorous via groundwater to seepage lakes. Groundwater discharges are displayed as an important source of phosphorous to a lake due to: (1) high concentrations in the aquifer just below the lake, and (2) the main flow paths through the aquifer–lakebed interface either being overland flow through a seepage face, or focused in zones with very high discharge rates. In-lake springs have measured discharge of up to 7.45 m³ per m² of lakebed per day. These findings were based on seepage meter measurements at 18 locations, stable isotope (δ¹⁸O) analyses, temperature profiles and mapping of ice cover distribution. Groundwater–lake interaction was modelled with a 2D conceptual flow model (MODFLOW) with hydrogeology interpreted from catchment multi electrode profiling, on-lake ground-penetrating radar, well logging and borehole data. Discharge was found to be much focused and opposite to expected increase away from the shoreline. The average total phosphorus concentration in discharging groundwater sampled just beneath the lakebed was 0.162 mg TP/l and thereby well over freshwater ecological thresholds (0.043–0.612, median = 0.117 mg TP/l). The study illustrates a direct link between groundwater and lake chemistry.     

Fine‐grained material encased in microtracks of Stardust samples

Dust from comet 81P/Wild 2 was captured at high speed in silica aerogel collectors during the Stardust mission. Studies of deceleration tracks in aerogel showed that a number of cometary particles were poorly cohesive and fragmented during impact. Fragments are now scattered along the walls of impact cavities. Here, we report a transmission electron microscope study of a piece of aerogel extracted from the wall of track 10. We focused on micron‐sized secondary tracks along which fragments of a fine‐grained material are disseminated. Two populations of fragments were identified. The first is made of polycrystalline silicate assemblages (olivine, pyroxene, and spinel) that appear to be chemically related to each other. The second corresponds to silica‐rich glassy clumps characteristic of a mixture of melted cometary material and aerogel. A significant number of fragments have been found with a composition close to chondritic CI for the major elements Fe‐Mg‐S at a submicron scale. These fragments have thus never been chemically differentiated by high‐temperature processes prior to the accretion on the comet, in contrast to terminal particles, which are dominated by larger, denser, and frequently monomineralic components.     

Rethinking the regularity in mobility patterns of personal vehicle drivers: A multi-city comparison using a feature engineering approach

Large-scale trajectory data offer a finer lens into the regularity in individual mobility choices. Previous studies have exerted efforts to measure the regularity in people's location visiting patterns. However, the complexity of travel behavior at different spatial and temporal scales has not been adequately considered. To capture regularity in a more comprehensive manner, we construct human mobility profiles with interpretable features at three levels, that is, location, motif, and route, on personal vehicle drivers. A feature engineering approach is designed to analyze the extent to which individuals exhibit multi-level regularity. The analysis pipeline includes feature selection, user segmentation and profiling, and feature importance evaluation. Our empirical study analyzed over 4 million trips of 3743 personal vehicle drivers collected over a month in six metropolitan areas in the United States. The weak correlations between features confirm the validity of quantifying regularity from different aspects. We discovered five clusters of drivers (i.e., gig drivers, homebodies, movers, typical drivers, and work-focused commuters) that differ in their regularity to commute to the workplace and the inclination to participate in non-work activities. A similar driver segmentation and profiling pattern is found in all of the studied metro areas. The minor differences are interpreted from the distribution of mobility features and urban features. The proposed method using multi-level feature engineering provides a generic framework to study regularity and can be readily adapted to other mobility data sources by customizing the features. The improved understanding of mobility patterns within the built environment is valuable for innovating urban transportation solutions.     

Challenges and lessons from a wetland LiDAR project: a case study of the Okefenokee Swamp,Georgia, USA

Airborne LiDAR (Light Detection and Ranging) provides opportunities to generate high-quality digital elevation models (DEMs) even in wetland environments. Our project, performed over the Okefenokee Swamp in Georgia during the spring of 2010, shows that several, distinctive factors must be considered to ensure successful wetland LiDAR projects. Some of the challenges include selecting optimal flight times in accordance with weather variability and water levels, having effective and quality control protocols, applying and developing filtering and interpolation algorithms, breaklines in swamps and accounting for data striping and noise. While some of these issues are faced in any airborne LiDAR acquisition, many of these require special consideration in a low-slope wetland environment with water saturated soils, widespread shallow water, and sediments and extensive vegetation. An examination of these issues and how they were handled will help in ensuring the success of future LiDAR acquisitions and, in particular, will advance knowledge of producing quality DEMs in wetland environments.     

Numerical modelling of morphodynamics—Vilaine Estuary

The main objective of this paper is to develop a method to simulate long-term morphodynamics of estuaries dominated by fine sediments, which are subject to both tidal flow and meteorologically induced variations in freshwater run-off and wave conditions. The method is tested on the Vilaine Estuary located in South Brittany, France. The estuary is subject to a meso–macrotidal regime. The semi-diurnal tidal range varies from around 2.5 to 5 m at neap and spring, respectively. The freshwater input is controlled by a dam located approximately 8 km from the mouth of the estuary. Sediments are characterised as mostly fines, but more sandy areas are also found. The morphology of the estuary is highly influenced by the dam. It is very dynamic and changes in a complicated manner with the run-off from the dam, the tide and the wave forcing at the mouth of the estuary. Extensive hydrodynamic and sediment field data have been collected in the past and provide a solid scientific basis for studying the estuary. Based on a conceptual understanding of the morphodynamics, a numerical morphological model with coupled hydrodynamic, surface wave and sediment transport models is formulated. The numerical models are calibrated to reproduce sediment concentrations, tidal flat altimetry and overall sediment fluxes. Scaling factors are applied to a reference year to form quasi-realistic hydrodynamic forcing and river run-off, which allow for the simulations to be extended to other years. The simulation results are compared with observed bathymetric changes in the estuary during the period 1998–2005. The models and scaling factors are applied to predict the morphological development over a time scale of up to 10 years. The influence of the initial conditions and the sequence of external hydrodynamic forcing, with respect to the morphodynamic response of the estuary, are discussed.     

Mapping Titan's surface features within the visible spectrum via Cassini VIMS

Titan shows its surface through many methane windows in the 1–5 $\mathrm{\mu }\mathrm{m}$ region. Windows at shorter wavelengths also exist, polluted by scattering off of atmospheric haze that reduces the surface contrast. At visible wavelengths, the surface of Titan has been observed by Voyager I, the Hubble Space Telescope, and ground-based telescopes. We present here global surface mapping of Titan using the visible wavelength channels from Cassini's Visual and Infrared Mapping Spectrometer (VIMS). We show global maps in each of the VIMS-V channels extending from 0.35 to 1.05 $\mathrm{\mu }\mathrm{m}$. We find methane windows at 0.637, 0.681, 0.754, 0.827, 0.937, and $1.046\mathrm{\mu }\mathrm{m}$ and apply an RGB color scheme to the 0.754, 0.827 and $0.937\mathrm{\mu }\mathrm{m}$ windows to search for surface albedo variations. Our results show that Titan appears gray at visible wavelengths; hence scattering albedo is a good approximation of the Bond albedo. Maps of this genre have already been made and published using the infrared channels of VIMS. Ours are the first global maps of Titan shortward of $0.938\mathrm{\mu }\mathrm{m}$. We compare the older IR maps to the new VIMS-V maps to constrain surface composition. For instance Tui Regio and Hotei Regio, referred to as $5\text{‐}\mathrm{\mu }\mathrm{m}$ bright spots in previous papers, do not distinguish themselves at all visible wavelengths. The distinction between the dune areas and the bright albedo spots, however, such as the difference between Xanadu and Senkyo, is easily discernible. We employ an empirically derived algorithm to remove haze layers from Titan, revealing a better look at the surface contrast.