生物质燃烧颗粒物有机示踪化合物的测定和应用

使用气相色谱-质谱法对2002年7月-2003年7月的北京市大气粗、细颗粒物样品中的左旋葡聚糖等糖类化合物进行了测定。结果表明，左旋葡聚糖主要存在于细颗粒中，可以作为示踪化合物来研究生物质燃烧现象。生物质燃烧对北京市大气颗粒物有较重要的贡献。对应于12％-40％的PM2.5有机碳和10％-33％的PM10有机碳。北京市在2002年10月和11月受到明显的生物质燃烧的影响，可能由于农田秸杆焚烧和秋季落叶焚烧。2003年5月7日颗粒物样品受到直线距离约为1000km以外的内蒙古自治区呼伦贝尔市大兴安岭林区森林大火烟雾的影响。生物质燃烧事件具有突发性，可以长距离传输；生物质作为农村生物燃料的使用其燃烧排放具有经常性和持久性的特征。     

Pits,rifts and slumps: the summit structure of Piton de la Fournaise

A clear model of structures and associated stress fields of a volcano can provide a framework in which to study and monitor activity. We propose a volcano-tectonic model for the dynamics of the summit of Piton de la Fournaise (La Reunion Island, Indian Ocean). The summit contains two main pit crater structures (Dolomieu and Bory), two active rift zones, and a slumping eastern sector, all of which contribute to the actual fracture system. Dolomieu has developed over 100 years by sudden large collapse events and subsequent smaller drops that include terrace formation. Small intra-pit collapse scars and eruptive fissures are located along the southern floor of Dolomieu. The western pit wall of Dolomieu has a superficial inward dipping normal fault boundary connected to a deeper ring fault system. Outside Dolomieu, an oval extension zone containing sub-parallel pit-related fractures extends to a maximum distance of 225 m from the pit. At the summit the main trend for eruptive fissures is N80°, normal to the north–south rift zone. The terraced structure of Dolomieu has been reproduced by analogue models with a roof to width ratio of approximately 1, suggesting an original magma chamber depth of about 1 km. Such a chamber may continue to act as a storage location today. The east flank has a convex–concave profile and is bounded by strike-slip fractures that define a gravity slump. This zone is bound to the north by strike-slip fractures that may delineate a shear zone. The southern reciprocal shear zone is probably marked by an alignment of large scoria cones and is hidden by recent aa lavas. The slump head intersects Dolomieu pit and may slide on a hydrothermally altered layer known to be located at a depth of around 300 m. Our model has the summit activity controlled by the pit crater collapse structure, not the rifts. The rifts become important on the mid-flanks of the cone, away from pit-related fractures. On the east flank the superficial structures are controlled by the slump. We suggest that during pit subsidence intra-pit eruptions may occur. During tumescence, however, the pit system may become blocked and a flank eruption is more likely. Intrusions along the rift may cause deformation that subsequently increases the slump’s potential to deform. Conversely, slumping may influence the east flank stress distribution and locally control intrusion direction. These predictions can be tested with monitoring data to validate the model and, eventually, improve monitoring.     

Hydrothermal circulation beneath Mount Pelée inferred by self potential surveying. Structural and tectonic implications

Self-potential (SP) surveys were made on Mount Pelée volcano (Martinique Island, French West Indies) in 1991 and 1992 in order to recognize its hydrothermal system, the associated groundwater channeling and the main superficial structures of the massif. Almost 70 km of profiles were carried out with an average sample spacing of 50 m. Measurements essentially reveal negative SP anomalies, down to −1700 mV, with high gradients (−1.83 mV/m) due to the infiltration of meteoric water into the massif. Rims of summit calderas Morne Macouba and Etang-Sec present sharp negative SP anomalies on the western, northern, and eastern flanks. Negative SP anomalies indicate no upward water flow beneath Mount Pelée summit. On the southwestern volcano flank, a 3.5×6 km horseshoe-shaped structure corresponding to a southwest flank collapse event, older than 25,000 years BP, is clearly identified by the SP mapping. High gradients border the inner southern rim from Morne Calebasse to St Pierre town and the Caribbean Sea. Along the northern rim of the horseshoe-shaped structure the negative SP anomalies give place to a positive SP anomaly, up to 200 mV, of SW–NE trend. This zone covers the area of two active hot springs (Sources Chaudes and Puits Chaud: 40–65°C). Marine magnetic surveys and bathymetry show that the horseshoe-shaped structure spreads into the Caribbean Sea up to about 10 km from the coast. Buried structural discontinuities are evidenced inside the flank collapse structure. The upper one deviates the groundwater flow coming from the summit toward the south flank where the flow finds an indentation to expand again downwards. This discontinuity is either an old hypothetical caldera rim partly destroyed by the collapse of the south–southwestern flank and covered by recent pyroclastic deposits, or more probably the trace of a bulge landslide. A circulation model of the hydrothermal waters is proposed. Rainfall (5–6 m/year) is partly drained inside the summital calderas and the flank collapse zone through pyroclastic flows down to an impermeable basement. There the groundwater constitutes perched aquifers at the contact of the bulge landslide, or of the hypothetical old caldera rim. Along the inner northern border of the flank collapse structure the phreatic water is reheated. Warm groundwater flows along the northern avalanche structure rim and discharges near the coast in ground and marine outcrops, of medium temperature. Finally, the main part of the meteoric water is channeled along the old caldera rim, or along the bulge landslide towards the south flank of Mount Pelée, where some gaps in the rim exist. There the groundwater finds again a subhorizontal gravitational circulation along Mount Pelée slopes into the Caribbean Sea.     

Hubble Space Telescope-WFPC2/Hα Observations of the Ejected Nebula M1-67

We present HST-WFPC2/Hα deep images of the ejected nebula M1-67. Our data suggest that M1-67 is the imprint of a previous, slow LBV wind ejected from the central star WR124, now a WN8 star. We find evidence that the LBV wind is highly variableand anisotropic. Some dense, persisting clumps have possibly been ejected directly from the stellar surface. This revised version was published online in July 2006 with corrections to the Cover Date.     

Spinel-olivine geothermometry in peridotites from ultramafic complexes

An empirical calibration of the spinel-olivine geothermometer (Evans and Frost, 1975) is attempted and applied to parageneses of lherzolitic rocks. In ultramafic complexes, most of the derived temperature estimates range between 700 ° and 850 °C, and appear generally lower than those given by other geothermometers, based upon Ca or Al contents of coexisting pyroxenes. A comparison of the different thermometric data in two well studied occurrences, the Ronda ultramafic complex and the San Carlos xenolith field, suggests that differential rates of diffusion and recrystalization may account for the large range of temperatures (between 700 ° and 1200 °C) determined by various mineral geothermometers in peridotites. The equilibrium exchange of Mg and Fe between spinel and olivine would be the fastest one and would continue effectively during the cooling down to relatively low temperatures, while other exchange reactions used as geothermometers in peridotites, like partitioning of Ca and Al in coexisting pyroxenes, are blocked at higher temperatures.     

Determination of crystallization temperatures in fractional crystallization series by nickel partitioning equations

Four high-quality seismic refraction profiles were recorded parallel to the structural grain in the Cuvier Basin and adjacent Wharton Basin to study the nature of the earth's crust in this area. The principal result of this experiment is that this area is generally floored with oceanic crust. No transitional velocity structure exists at the base of the continental slope. Departures from a standard oceanic crustal section are observed on an intermediate profile that are attributed to structural complications on the flank of an abandoned spreading ridge. Additional magnetic anomaly profiles in the eastern Cuvier Basin are used to correlate the lineations in that area with Early Cretaceous reversals M-5 to M-10. This correlation dates the onset of plate separation at 120–125 m.y., essentially contemporaneous with the opening of the Perth Basin to the south. However, it leaves a 220-km gap between M-4 and M-5 in the Cuvier Basin that suggests a ridge jump of that magnitude occurred nominally at 118 m.y. Early Cretaceous magnetic lineations northwest of the Exmouth Plateau suggest that spreading at the seaward edge of the Exmouth Plateau began 120 m.y. ago, while Late Jurassic marine sediments and fault structures landward of the Exmouth Plateau suggest rifting in that area at 155 m.y.     

Biotites and associated minerals as markers of magmatic fractionation and deuteric equilibration in granites

Analyses of 80 biotite, alkali feldspar, oligoclase, hornblende, Fe-Ti oxide separates from the coarse-grained granites of a late-hercynian epizonal diapir, the Ploumanac'h complex, Brittany, show that these minerals display a regular concentric cryptic layering related to fractional crystallization. The Ca, Mg, Ba, Sr, Cr, V content of minerals decreases as the Na, Fe, and Rb content increases. Biotites become more dioctahedral towards the outer residual syenogranite, with a correlative K deficiency. Trioctahedral biotites from the inner accumulative monzogranite are secondarily oxidized with a gain of Fe³⁺ and a loss of OH. This alteration id due to the percolation of exsolved fluids rich in H₂O and containing a small amount of CO₂, F, S, Cl. During this autometamorphic stage, trace elements like Rb, Sr are completely redistributed on the scale of hand specimens, with a restricted range of partition coefficients between biotite, perthite and oligoclase. This equilibration occurred at a temperature about 550 ° C and a fluid pressure about 1,000 bars, with f _H2_O probably less than 500 bars. A later stage of fluid circulation along fractures brings up a slight Li metasomatism. Biotites are a sensitive marker of both magmatic and postmagmatic stages of subsolvus or ‘wet’ plutonites.     

Infrared study of the pyrolysis products of sporopollenin and lignite

The effect of pyrolysis at increasing temperature on sporopollenin, lignite and sporopollenin oxidized at 200°C has been investigated using measured infrared band absorption coefficients.Oxidation of sporopollenin in air at 200°C is marked by a decrease in the content of saturated hydrocarbon chains and a strong increase in the concentration of carboxylic acid groups.Pyrolysis of a thick bed of sporopollenin at increasing temperatures leads to the removal of a large proportion of oxygenated functions, before the removal of hydrocarbons. For lignite and oxidized sporopollenin, the loss of both types of functional groups extends over a broader temperature range. Reorganization of the carbonaceous residue at high temperature is hindered if a sufficiently low content of oxygenated functions, carbonyl and carboxyl as well as hydroxyl and ether groups, is not reached before the elimination of hydrocarbons.