Experimental studies of sublimation of highly volatile ices in relevance to the ices of the solar system

Studies of sublimation of complex ices prepared by deposition of gaseous CO, CH₄, N₂, and NH₃ molecules on a cold plate have been performed. The low pressure and low temperature system was used: 10^?9–10^?5 mbar and the lowermost temperature 10 K. Diagnostic of composition of evaporates (at an actual temperature) was done by means of the mass spectrometer. The latter allowed following simultaneously the partial pressure of five different ions or radicals escaping from the substrate. It has been found that highly volatile molecules that were used simultaneously with the low volatile ones to form the complex ices (mixtures or clathrates) present a different sublimation pattern than the sublimation of pure high-volatile ices. In particular, the high-volatile component sublimes at two or even three different temperature regimes: At low temperature that is typical for sublimation of this component, as well as at much higher temperatures. This effect seems to be important when degassing and outbursts from cometary nuclei are considered. It can be also important for modeling of cryovolcanic processes on the icy satellites.     

Large regional variability of recent climatic change driven sub-surface temperature changes as derived from temperature logs-central Canada example

International Journal of Earth Sciences - The analysis of the warming/cooling patterns from inversion of 94 well temperature logs for the study area of Central Canada shows very high variability...     

Origin of diffuse interstellar bands: spectroscopic studies of their possible carriers

The results of astrophysical observations that provide evidence for the molecular origin of the diffuse interstellar bands (DIBs) are reviewed. It is established that molecular systems with a linear, planar or spherical carbon skeleton are good candidates as DIB carriers, and laboratory spectroscopic data concerning such systems are discussed. The characteristic features of the electronic spectra of fullerenes, polycyclic aromatic hydrocarbons, and of linear carbon chains and their ions are found to be consistent with the principal spectroscopic features of DIBs. Analysis of the astrophysical electronic spectra of several simple molecules that have so far been assigned indicates that polar molecules should be easier to detect in this way than those without a permanent electric dipole moment.     

Large ground surface temperature changes of the last three centuries inferred from borehole temperatures in the Southern Canadian Prairies, Saskatchewan

New temperature logs in wells located in the grassland ecozone in the Southern Canadian Prairies in Saskatchewan, where surface disturbance is considered minor, show a large curvature in the upper 100 m. The character of this curvature is consistent with ground surface temperature (GST) warming in the 20th century. Repetition of precise temperature logs in southern Saskatchewan (years 1986 and 1997) shows the conductive nature of warming of the subsurface sediments. The magnitude of surface temperature change during that time (11 years) is high (0.3–0.4°C). To assess the conductive nature of temperature variations at the grassland surface interface, several precise air and soil temperature time series in the southern Canadian Prairies (1965–1995) were analyzed. The combined anomalies correlated at 0.85. Application of the functional space inversion (FSI) technique with the borehole temperature logs and site-specific lithology indicates a warming to date of approximately 2.5°C since a minimum in the late 18th century to mid 19th century. This warming represents an approximate increase from 4°C around 1850 to 6.5°C today. The significance of this record is that it suggests almost half of the warming occurred prior to 1900, before dramatic build up of atmospheric green house gases. This result correlates well with the proxy record of climatic change further to the north, beyond the Arctic Circle [Overpeck, J., Hughen, K., Hardy, D., Bradley, R., Case, R., Douglas, M., Finney, B., Gajewski, K., Jacoby, G., Jennings, A., Lamourex, S., Lasca, A., MacDonald, G., Moore, J., Retelle, M., Smith, S., Wolfe, A., Zielinski, G., 1997. Arctic environmental change of the last four centuries, Science 278, 1251–1256.].     

An integrative geothermal resource assessment study for the siliciclastic Granite Wash Unit,northwestern Alberta (Canada)

This study explores the siliciclastic Granite Wash Unit in northwestern Alberta as a potential geothermal reservoir. The approach covers regional 3D structural geological modelling of a 90 km × 70 km area based on well log and legacy 2D seismic data. The fault strike was interpreted from lineaments, which were identified with the refined trend surface analysis method. The stress state of the Granite Wash reservoirs was determined by an integrated approach of 3D fault modelling, stress ratio definition based on frictional constraints, and slip tendency analysis. The results show that the best site for a geothermal application is located in the southwestern study area, where the highest temperatures (above 70 °C) coincide with the largest thickness (above 20 m) and zones of elevated porosity and permeability. The integrated stress analysis indicates an in situ stress regime from normal to strike-slip faulting maintaining a non-critically stressed reservoir or faults therein, assuming a friction coefficient of 0.7. The granite wash reservoirs could be used for heating of greenhouses, domestic warm water provision and district heating.     

Spatiotemporal distribution of copepod populations in the Gulf of Gdansk (southern Baltic Sea)

In the present study, we used a 3D Coupled Ecosystem Model of Baltic Sea version 1 (3D CEMBSv1) coupled with a copepod model to examine the spatiotemporal distribution of two representative copepod populations in the Gulf of Gdansk (southern Baltic Sea) including Acartia spp. and Pseudocalanus minutus elongatus. The annual cycles simulated for 2000 under realistic weather and hydrographic conditions were studied with the three-dimensional version of the coupled ecosystem-copepod model in the south-eastern Baltic Sea. The paper presents the comparison of simulated and observed copepod development at two stations in the Gulf of Gdansk. A validation of influential state variables gives confidence that the model is able to calculate reliably the stage development of dominant species in the southern Baltic Sea. The number of generations was one for P. m. elongatus and 3?C5 for Acartia spp.. A mean of five generations for the latter species per year were estimated in the coastal region and ca. three generations at the Gdansk Deep (in the open sea). Food concentration and temperature as the main factors controlling the development of the investigated copepods as well as salinity as a masking factor (i.e. salinity modifies the rate of their development) in the case of Pseudocalanus minutus elongatus are included in the present study.     

S-velocity structure beneath the Bohemian Massif from Monte Carlo inversion of seismic receiver function

The paper contains an analysis of S-velocity distribution in the crust and upper mantle beneath the Bohemian Massif, which is the second biggest Variscan outcrop in Europe. It occupies mainly the west part of Czech Republic and also part of south-west Poland and south-east Germany. We use data from 10 permanent stations set in the region. Some previous papers relate to the same scope but use linear methods to inverse receiver function. Our new approach involves Monte Carlo techniques for inversion procedure, which is more convenient and robust for such a non-linear task. The result of Monte Carlo inversion is compared with the previously achieved one. The obtained Moho depths vary from 29 km in the north-west part of the Bohemian Massif to 38 km in the south and south-east and are consistent with other papers. Some discrepancies occur in the middle and upper crust.