Crystallization and resorption in plutonic plagioclase: Implications on the evolution of granodiorite magma (Gęsiniec granodiorite, Strzelin Crystalline Massif, SW Poland)

Granodiorite from the Gęsiniec Intrusion, Strzelin Crystalline Massif, SW Poland contains complexly zoned plagioclases. Five chemically and structurally distinct zones can be correlated among crystals: ‘cores’ (25–35% An), inner mantles (40–45% An), outer mantles (40–25% An), resorption zones (35–50% An) and rims (35–30% An). Good structural and chemical (major and trace elements) correlation of zones between crystals indicates that zonation was produced by changes in conditions of crystallization on a magma chamber scale. Plagioclase, being the liquidus phase, records a time span from the beginning of crystallization to emplacement and rapid cooling of granodiorite as thin dykes.

Crystallization began with the formation of inner mantles. The paucity and different sizes of inner mantles suggests slow crystallization in high temperature magma. Normally zoned inner mantles were formed under increasing undercooling. Compositional trends in mantles suggest closed system crystallization.

The major resorption zones were caused by injection of less evolved magma as indicated by the strontium increase in plagioclase. The injection triggered a rapid rise of magma and plagioclase crystals facilitating mixing but also inducing fast, kinetically controlled growth of complex multiple, oscillatory zonation within resorption zones. The ascent of magma caused decompression melting of plagioclase and produced melt inclusions within inner mantles—the ‘cores’. The decompression range is estimated at a minimum of 2 kbar. Emplacement of granodiorite as thin dykes allow rapid cooling and preservation of magmatic zonation in plagioclases. Melt inclusions crystallized completely during post-magmatic cooling.

The zonation styles of plutonic plagioclase differ markedly from volcanic ones suggesting different magma evolution. Zones in plutonic plagioclase are well correlated indicating crystallization in quiescent magma where crystals accumulation and compositional magma stratification may occur. Crystals probably did not travel between different regimes. Resorption occurred but as single albeit complex episodes. Good correlation of zones in plutonic plagioclases allows a distinction between the main processes controlling zonation and superimposed kinetic effects.     

Comparison of migration‐based location and detection methods for microseismic events

Microseismic monitoring in the oil and gas industry commonly uses migration‐based methods to locate very weak microseismic events. The objective of this study is to compare the most popular migration‐based methods on a synthetic dataset that simulates a strike‐slip source mechanism event with a low signal‐to‐noise ratio recorded by surface receivers (vertical components). The results show the significance of accounting for the known source mechanism in the event detection and location procedures. For detection and location without such a correction, the ability to detect weak events is reduced. We show both numerically and theoretically that neglecting the source mechanism by using only absolute values of the amplitudes reduces noise suppression during stacking and, consequently, limits the possibility to retrieve weak microseismic events. On the other hand, even a simple correction to the data polarization used with otherwise ineffective methods can significantly improve detections and locations. A simple stacking of the data with a polarization correction provided clear event detection and location, but even better results were obtained for those data combined with methods that are based on semblance and cross‐correlation.     

Seismic Monitoring of Poland–Description and Results of Temporary Seismic Project with Mobile Seismic Network

The paper describes a temporary seismic project aimed at developing the national database of natural seismic activity for seismic hazard assessment, officially called “Monitoring of Seismic Hazard of Territory of Poland” (MSHTP). Due to low seismicity of Poland, the project was focused on events of magnitude range 1–3 in selected regions in order to maximize the chance of recording any natural event. The project used mobile seismic stations and was divided into two stages.Five-year measurements brought over one hundred natural seismic events of magnitudes M_L range 0.5–3.8. Most of them were located in the Podhale region in the Carpathians. Together with previously recorded events this made it possible to conduct a preliminary study on ground motion prediction equation for this region. Only one natural event, of magnitude M_L = 3.8, was recorded outside the Carpathians in a surprising location in central-west Poland.     

Integrating X‐ray mapping and microtomography of garnet with thermobarometry to define the P–T evolution of the (near) UHP Międzygórze eclogite,Sudetes, SW Poland

Detailed X‐ray compositional mapping and microtomography have revealed the complex zoning and growth history of garnet in a kyanite‐bearing eclogite. The garnet occurs as clusters of coalesced grains with cores revealing slightly higher Ca and lower Mg than the rims forming the coalescence zones between the grains. Core regions of the garnet host inclusions of omphacite with the highest jadeite, and phengite with the highest Si, similar to values in the cores of omphacite and phengite located in the matrix. Therefore, the core compositions of garnet, omphacite, and phengite have been chosen for the peak pressure estimate. Coupled conventional thermobarometry, average P–T, and phase equilibrium modelling in the NCKFMMnASHT system yields P–T conditions of 26–30 kbar at 800–930°C. Although coesite is not preserved, these P–T conditions partially overlap the coesite stability field, suggesting near ultra‐high–pressure (UHP) conditions during the formation of this eclogite. Therefore, the peak pressure assemblage is suggested to have been garnet–omphacite–kyanite–phengite–coesite/quartz–rutile. Additional lines of evidence for the possible UHP origin of the Mi?dzygórze eclogite are the presence of rod‐shaped inclusions of quartz parallel to the c‐axis in omphacite as well as relatively high values of Ca‐Tschermak and Ca‐Eskola components. Late zoisite, rare diopside–plagioclase symplectites rimming omphacite, and minor phlogopite–plagioclase symplectites replacing phengite formed during retrogression together with later amphibole. These retrograde assemblages lack minerals typical of granulite facies, which suggests simultaneous decompression and cooling during exhumation before the crustal‐scale folding that was responsible for final exhumation of the eclogite.     

European forest cover mapping with high resolution satellite data: The Carpathians case study

The aim of the study was to elaborate a methodology for forest mapping based on high resolution satellite data, relevant for reporting on forest cover and spatial pattern changes in Europe. The Carpathians were selected as a case study area and mapped using 24 Landsat scenes, processed independently with a supervised approach combining image segmentation, knowledge-based rules to extract a training set and the maximum likelihood decision rule. Validation was done with available very high resolution imagery. Overall accuracies per scene ranged from 93 to 96%. The labelling disagreement in overlapping areas of adjacent scenes was 6.8% on average.     

Surficial patterns of debris flow deposition on alluvial fans in Death Valley, CA using airborne laser swath mapping data

Debris flows are a common event in mountainous environments. They often possess the greatest potential for destruction of property and loss of lives in these regions. Delimiting the spatial extent of potential damage from debris flows relies on detailed studies of the location of depositional zones. Current research indicates debris flow fans have two distinct depositional zones. However, the two zones were derived from studies containing detailed analyses of only a few fans. High resolution airborne laser swath mapping (ALSM) data is used to calculate profile curvature and surface gradient on 19 debris flow fans on the eastern side of Death Valley. The relationship between these parameters is assessed to 1) identify if debris flow fans are accurately represented by two depositional zones, and 2) to assess how these terrain parameters relate to one another at the individual fan scale. The results show at least three zones of deposition exist within the sampled fans. These zones do not hold consistent when individual fan morphometry is analyzed in conjunction with localized fan surface gradients. Fans with consistently shallower gradients exhibit numerous depositional zones with more subtle changes in profile curvature. Steeper gradient fans exhibit significantly fewer zones with more pronounced local changes in profile curvature. The surface complexity of debris flow fans is evident from these analyses and must be accounted for in any type of hazard studies related to these features.     

Bacterial ancient DNA as an indicator of human presence in the past: its correlation with palynological and archaeological data

Palynological investigation is one of the most important tools for reconstructing past vegetation. Some plants have proved to be relatively sensitive indicators of human activity, but most of them are not specific. In this paper we propose a method which can be used for the verification of phases of anthropogenic impact on vegetation distinguished in pollen diagrams. In this work we adopted the existing molecular methods for tracking bacterial ancient DNA of Bifidobacterium and Bacteroides‐Prevotella (known as human‐ and cow‐specific genetic markers) in palynologically and archaeologically associated sediments. This method can be helpful in determining local human presence, especially in those time periods when pollen analysis has not always been very discriminating (Palaeolithic, Mesolithic) and at sites without archaeological evidence. Copyright © 2008 John Wiley & Sons, Ltd.     

Characterization of polysomatism in biopyriboles: Double-/triple-chain lamellar intergrowths

As a first step towards accurate quantification of the polysomatic states of biopyriboles, we have studied the polysomatic transformation between amphibole and hydrous triple-chain silicate (TCS) in the synthetic system Na₂O-MgO-SiO₂-H₂O (NMSH). The reaction is: 4Na₂Mg₄Si₆O₁₆(OH)₂ TCS 3Na_2.67Mg_5.33Si₈O_21.33(OH)_2.67. Amphibole We have characterised a polysomatic intergrowth of amphibole and TCS (synthesized at 2 kbar/(653° C) by X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), infrared spectroscopy and ²⁹Si magic-angle-spinning (MAS) NMR spectroscopy. The sample is a fine-scale lamellar intergrowth of double- and triple-chain structures; lamellae are 27 Å to hundreds of Ångströms wide. The ²⁹Si MAS NMR spectrum of the intergrowth is explicitly a superposition of the individual amphibole and TCS spectra. By ensuring that the recycle delay time used considers the longest spin-lattice relaxation time (ca. 900 s), the relative amounts of double- and triple-chain structures can be quantified by simple deconvolution of the spectrum. The relative amounts of double- and triple-chain structures are 42 ± 5 and 58 ± 5 mol%, respectively. With regard to quantifying populations of chain multiplicities in biopyriboles, we believe that ²⁹Si NMR is more accurate than the conventional HRTEM fringe-counting method (Maresch and Czank 1983, 1988), and is far superior to XRD and infrared spectroscopy, which suffer from high sensitivity to particle size and calibration problems. ²⁹Si MAS NMR can provide an accurate means of monitoring the progress of polysomatic reactions in biopyriboles. It is likely to be most effective for samples containing only a few different chain multiplicities (e.g. m = 1, 2, 3 and perhaps 4), such as occur in natural pyroxenes and amphiboles.     

Differential biomagnification of PCB, PBDE, Hg and Radiocesium in the food web of the European hake from the NW Mediterranean

Consumption of marine organisms represents one of the main exposure sources of contaminants for human populations. To obtain a global view of the contamination in commercial fish in the NW Mediterranean Sea, we analysed four types of priority contaminants (PCBs, PBDEs, Hg and (137)Cs) in the European hake, Merluccius merluccius, from the Gulf of Lions in relation with organism's trophic level (δ(15)N). All contaminants presented a significant increase in concentration in hake muscle with trophic level. However, obvious differences between contaminants were evidenced. Biomagnification factors (BMF and FWMF) along the hake food web were higher for Hg and CB-153 than for BDE-47 and (137)Cs, and increase in contaminant concentration with trophic level occurred at different rates depending on contaminants. Such differences of biomagnification patterns can be related to physico-chemical properties of the different contaminants.     

A GIS-based approach to multiple criteria group decision-making

Abstract

The multiple criteria group decision-making problem involves a set of feasible alternatives that are evaluated on the basis of multiple, conflicting and noncommensurate criteria by a group of individuals. This paper is concerned with developing a GIS-based approach to group decision-making under multiple criteria. The approach integrates, within a raster GIS environment, the Technique for Order Preference by Similarity to Ideal Solution (TOPSIS) and Borda's choice rule. TOPSIS orders the feasible alternatives according to their closeness to the ideal solution. It is used to derive the individual preference orderings. Borda's method combines the individual preferences into a group preference or consensus/compromise ranking. The approach is implemented within the IDRISI GIS and illustrated on a hypothetical decision situation.