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排序方式: 共有116条查询结果,搜索用时 15 毫秒
1.
Jaap Tinbergen 《Astrophysics and Space Science》2003,288(1-2):3-14
Measurement of circular polarization is mostly looked upon as a specialist craft, applied by polarization freaks to answer uninteresting questions. This paper attempts to correct that view: some important questions can only be tackled by circular polarimetry, there is nothing very special about Stokes V and its measurement is entirely analogous to that of Q and U.Radio and optical polarimetry are covered, using both single telescopes and interferometers. 相似文献
2.
Jaap S. Sinninghe Damst Marcel M.M. Kuypers Richard D. Pancost Stefan Schouten 《Organic Geochemistry》2008,39(12):1703
The stable carbon isotopic compositions of free and sulfur (S)-bound biomarkers derived from algae, (cyano)bacteria, archaea and higher plants and total organic carbon (TOC) during the first phase of the late Cenomanian/Turonian oceanic anoxic event (OAE) were measured in black shales deposited in the southern proto-Atlantic Ocean in the Cape Verde basin (DSDP Site 367) to determine the response of these organisms to this major perturbation of the global carbon cycle resulting from widespread burial of marine organic matter. The average positive isotope excursions of TOC and biomarkers varied from 5.1‰ to 8.3‰. The δ13C values were cross correlated to infer potential common sources of biomarkers. This revealed common sources for C31 and C32 hopanes but no 1:1 relationship for pristane and phytane. The correlation of δ13CTOC with the δ13C value of sulfur (S)-bound phytane is the strongest. This is because S-bound phytane is derived from phytol that originates from all marine primary producers (algae and cyanobacteria) and thus represents a weighted average of their carbon isotopic compositions. The δ13C values of S-bound phytane and C35 hopane were also used to estimate pCO2 levels. Before the OAE burial event, pCO2 levels are estimated to be ca. 1300 ppmv using both biomarkers and the independent maximum Rubisco fractionation factors. At times of maximum organic carbon burial rates during the OAE, reconstructed pCO2 levels are estimated to be ca. 700 ppmv. However, compared to other C/T OAE sections the positive isotope excursion of S-bound phytane is also affected by an increased production during the OAE. When we compensate for this, we arrive at pCO2 levels around 1000 ppmv, a reduction of ca. 25%. This indicates that burial of organic matter can have a large effect on atmospheric CO2 levels. 相似文献
3.
Andrea Jaeschke Michael D. Lewan Ellen C. Hopmans Stefan Schouten Jaap S. Sinninghe Damst 《Organic Geochemistry》2008,39(12):1735
Anaerobic ammonium oxidation (anammox) has been recognized as a major process resulting in loss of fixed inorganic nitrogen in the marine environment. Ladderane lipids, membrane lipids unique to anammox bacteria, have been used as markers for the detection of anammox in marine settings. However, the fate of ladderane lipids after sediment burial and maturation is unknown. In this study, anammox bacterial cell material was artificially matured by hydrous pyrolysis at constant temperatures ranging from 120 to 365 °C for 72 h to study the stability of ladderane lipids during progressive dia- and catagenesis. HPLC-MS/MS analysis revealed that structural alterations of ladderane lipids already occurred at 120 °C. At temperatures >140 °C, ladderane lipids were absent and only more thermally stable products could be detected, i.e., ladderane derivatives in which some of the cyclobutane rings were opened. These diagenetic products of ladderane lipids were still detectable up to temperatures of 260 °C using GC-MS. Thus, ladderane lipids are unlikely to occur in ancient sediments and sedimentary rocks, but specific diagenetic products of ladderane lipids will likely be present in sediments and sedimentary rocks of relatively low maturity (i.e., C31 hopane 22S/(22S + 22R) ratio <0.2 or ββ/(αβ + βα + ββ) ratio of >0.5). 相似文献
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Aoibheann A. Kilfeather Colm Ó Cofaigh Julian A. Dowdeswell Jaap J. M. van der Meer David J. A. Evans 《Geo-Marine Letters》2010,30(2):77-97
Glacimarine diamicts are produced by diverse processes, and genetic differentiation is often problematic using macro-sedimentological
criteria alone. Micromorphology offers a potentially helpful tool in such investigations. Macroscopically massive diamict
samples of known glacimarine origin, from the Polar North Atlantic, Antarctica and north Irish Sea, were prepared for micromorphological
analysis to (1) identify microstructures unique to different modes of sedimentation and (2) interpret genetic processes from
those structures. The samples comprised examples of debris-flow, iceberg-turbate and suspension settling deposits from late
Quaternary glacier-influenced marine environments: tidewater glacier, sub- or pro-ice shelf and continental slopes in front
of ice stream termini. Results show two significant features of debris-flow sediments: a bimodal grain fabric of near-horizontal
and -vertical grains, and laminated clay and silt coatings on sand and pebble grains. Coatings are best developed in sediments
with finer grain-size distributions and in debris-flow sediments which have had relatively long run-out distances on trough-mouth
fans, suggesting continuous rotation of grains in a buoyant, turbulent aqueous environment. This is significant because it
precludes debris-flow delivery by plug flow. The micromorphology of iceberg turbate has not been described previously. It
contains structures similar to those described in tills, so that unambiguous identification of these sediments seems unlikely
based on micromorphological criteria alone. Suspension sediments range from fine-grained massive diamicts containing microfossils
to more heterogeneous coarser sediments characterised by abrupt textural variations, from ice-distal and ice-proximal glacimarine
environments respectively. The ice-proximal sediments contain fine vertical lineations marking the trajectories of dropstones
through wet matrix. These dropstone tracks have not been reported in previous studies. 相似文献
9.
E. J. M. Bloem N. J. McNaughton D. I. Groves J. R. Ridley 《Australian Journal of Earth Sciences》2013,60(5):447-451
The Corinthia lode‐gold deposit in amphibolite‐facies greenstone belt rocks in the Southern Cross Province of the Archaean Yilgarn Block contains a largely undeformed pegmatite dyke emplaced during the last phases of movement along the Fraser's‐Corinthia shear zone. Gold mineralization and shear zone development were synchronous, and a Pb‐Pb isochron age of 2620 ±6 Ma for pegmatite emplacement either indirectly dates mineralization, or places a minimum age constraint on the timing of mineralization. This age is in accord with a broadly synchronous dominant episode of Archaean lode‐gold mineralization throughout the Yilgarn Block. 相似文献
10.
Stem wood of the Angiosperm Calluna vulgaris (Scotch heather), isolated at different depths from a selection of raised bog peat deposits, was chemically characterized using in-source pyrolysis mass spectrometry (Py-MS) and Curie-point pyrolysis gas chromatography mass spectrometry (Py-GC-MS). Light microscopy was performed to relate mass spectrometric characteristics with anatomical features. Peatified wood samples, isolated from increasing depth show a gradual decrease in carbohydrate content. This decrease in anatomically reflected in a selective removal of secondary cell wall material from the fibre-tracheids and wood parenchyma. During prolonged peatification a selective removal of hemicellulose sugars is observed, while a part of the cellulose fraction is preserved. This highly resistant cellulose is mainly located in the secondary cell walls of the vessels. The lignin macromolecule is preserved, but a gradual decrease in syringyl to guaiacyl ratio (S/G) is observed during peatification. Because no increase in catechol and phenolic compounds is observed, we conclude that S/G shifts are due to removal the of syringyl-rich secondary cell wall material and the retention of guaiacyl-rich compound middle lamella. Small chemical changes in the lignin macromolecule involve shifts in oxygen substitutions on the aliphatic side chains of the methoxyphenolics and the occurrence of aromatic acids. 相似文献