Geochemistry of overbank and high-order stream sediments in Belgium and Luxembourg: a way to assess environmental pollution

A geochemical survey of Belgium and Luxembourg was carried out as part of an international research project entitled ‘Regional geochemical mapping of Western Europe towards the year 2000'. The aim of this research was to map regional background geochemical patterns based on pristine or at least pre-industrial overbank samples and to deduce regional information on the degree of environmental pollution of floodplain and present-day river sediments. Over the entire study area (about 33,000 km²), 66 overbank sites have been sampled. Catchment areas range between 60 and 600 km². At each site an overbank profile has been dug out in the immediate vicinity of the river and described in detail. A first composite sample was taken 5–25 cm below the surface. This sample is supposed to represent deposition over the last centuries. Human interferences in this interval are often inferable based on changed sedimentary characteristics and the presence of anthropogenic particles such as charcoal, slags and brick fragments. A second composite sample was taken at depth, usually >1.5 m below the surface over an interval of about 20 cm. In most sites, the profile characteristics allowed to assume pre-industrial or even pristine conditions for this lower overbank sample. In some profiles this was confirmed by ¹⁴C-dating and/or by the absence of anthropogenic particles. Finally, a present-day stream sediment was sampled on the site to infer the actual pollution status. After drying at 80°C, disaggregation and sieving, the <125 μm fractions of the three sediment samples were analysed by XRF for major elements and several trace elements. Lower overbank samples generally show a direct link with the geological substrate and allow to assess natural background concentrations. Results from the mapping exercise as well as from the statistical analyses display a clear contrast between the northern part of Belgium where Cenozoic unconsolidated sandy and silty formations dominate which are especially vulnerable for erosion, and the southern part of Belgium and Luxembourg where Paleozoic and Mesozoic sandstones, carbonates, marls and shales are the prevalent lithologies. Here the shales are the most intensively eroded lithologies. This is especially reflected in the element patterns of Al₂O₃, MgO, K₂O, Ga, Ni, Rb, Sc and V which negatively correlate with SiO₂. Despite the human related pollution, the geological contrast between north and south Belgium is still recognisable in the geochemical pattern of the upper overbank and present-day stream sediment samples for the above-mentioned elements. Furthermore there is a clear increase in heavy metal contents (Zn, Cd, Pb, Cu), As and in certain locations in Ba from the lower to the upper overbank sediment, as well as to the present-day stream sediment. The relative increase in element content allows to assess the degree of pollution and helps to define those drainage areas where more detailed research is needed.     

High-frequency ocean radar derived characteristics of sea surface currents in the Ariake Sea,Japan

Composite analysis was conducted using high-frequency radar data obtained during 2006–2015 in order to gain a better understanding of the current field in the Ariake Sea. The seasonally averaged surface current in the Ariake Sea was directed southward in all seasons, except around river mouths during summer. Heavy rainfall enhanced the outflow along the eastern coast of the Shimabara Peninsula from Isahaya Bay to the southern area 2–5 days after heavy rainfall. Spring–neap differences were clearly seen in the southward current along the Shimabara Peninsula. Interannual variation in the M₂ tidal current amplitude was synchronized with the lunar nodal cycle.     

Coastal processes and environmental hazards: the Buenos Aires (Argentina) and Venetian (Italy) littorals

The Buenos Aires (Argentina) and Venice (Italy) coastlands have experienced significant saltwater contamination of the phreatic aquifer, coastal erosion, hydrodynamic changes and relative sea level rise processes due to natural and man-induced factors. These factors expose coastal areas to morpho-hydro-geological hazards, such as soil desertification, frequency and degree of flooding, littoral erosion, and the silting of river mouths and channels. Man-made interventions and actions, such as beach mining, construction of coastal structures and exploitation of aquifers without an adequate knowledge of the hydrology setting and an adequate management program, worsen these natural hazards. Uncontrolled human activity induces environmental damage to the overall coastal plains. The coastal plains play an important role in the social/economic development of the two regions based on land use, such as agriculture, horticulture, breeding, and tourism, as well as industry. Results of investigations on saltwater contamination, sea level rise and morphological changes recently performed in these two coastal areas are presented here.     

Modeling the Population Effects of Hypoxia on Atlantic Croaker (<Emphasis Type="Italic">Micropogonias undulatus</Emphasis>) in the Northwestern Gulf of Mexico: Part 1—Model Description and Idealized Hypoxia

We developed a spatially explicit, individual-based model to analyze how hypoxia effects on reproduction, growth, and mortality of Atlantic croaker in the northwestern Gulf of Mexico lead to population-level responses. The model follows the hourly growth, mortality, reproduction, and movement of individuals on a 300 × 800 spatial grid of 1-km² cells for 140 years. Chlorophyll-a concentration, water temperature, and dissolved oxygen (DO) were specified daily for each grid cell and repeated for each year of the simulation. A bioenergetics model was used to represent growth, mortality was assumed stage- and age-dependent, and the movement behavior of juveniles and adults was modeled based on temperature and avoidance of low DO. Hypoxia effects were imposed using exposure effect submodels that converted time-varying exposures to low DO to reduced hourly growth, increased hourly mortality, and reduced annual fecundity. Results showed that 100 years of either mild or intermediate hypoxia produced small reductions in population abundance, while repeated severe hypoxia caused a 19% reduction in long-term population abundance. Relatively few individuals were exposed to low DO each hour, but many individuals experienced some exposure. The response was dominated by a 5% average reduction in annual fecundity of individuals. Under conditions of random sequences of mild, intermediate, and severe hypoxia years occurring in proportion to their historical frequency, the model predicted a 10% decrease in the long-term population abundance of croaker. A companion paper substitutes hourly DO values from a three-dimensional water quality model for the idealized hypoxia and results in a more realistic population reduction of about 25%.     

Seasonally and spatially referenced estimates of recreational shore-angling effort,catch composition,catch rates and total catch in the Goukamma Marine Protected Area,South Africa

A roving creel survey of the recreational shore fishery along the 16.4-km coastline in the Goukamma Marine Protected Area on the south coast of South Africa was conducted from 2009 to 2011. Some 838 patrols were stratified equally among months, areas and years, but intentionally biased towards weekends. Angler densities at Buffalo Bay and Groenvlei were 0.59 and 0.28 anglers km?1, respectively. Weekend densities were double to quadruple weekday densities and fishing during winter was more popular than during summer. Area, habitat and distance to access points explained variation in angler densities. Shannon–Wiener diversity in catches declined from 2.18 in an earlier (1993–2002) survey to 1.79. Although the order of species abundance in the catches remained largely unchanged, blacktail Diplodus capensis dominance increased to 57.3% by number, at the expense of galjoen Dichistius capensis. Habitat explained 27% of the variance in catch composition. The catch per unit effort (CPUE) for the top nine species ranged from 0.19 to 6.35 fish 100-h?1. The CPUE of all species, except spotted grunter Pomadasys commersonnii, declined. Blacktail and galjoen CPUE declined by 17% and 77%, respectively. The total catch estimate was 2 986 fish y?1. Transgressions of size limits were common. The results suggest that the fishery is overexploited and that catch rates are declining.     

Effects of long-term medieval agriculture on soil properties: A case study from the Kislovodsk basin,Northern Caucasus,Russia

The chemical properties and biological activities of soils were studied in the vicinity of the medieval settlement Podkumskoe-3 in the Kislovodsk basin (Northern Caucasus, Russia). Between the 5th and 8th centuries this area was ploughed regularly, but it was then abandoned up to the present day. It has been established that past human activity leads to soil undergoing significant transformations in terms of microbial communities and enzyme activity, and that such changes are maintained over long periods. Long-term manuring in the middle of the first millennium AD led to an increase in organic carbon content and the accumulation of nitrate nitrogen. Soils of ancient abandoned fields are associated with increases in microbial biomass, number of saprotrophic bacteria, urease activity, and fungal mycelium biomass. The observed changes in the microbiological and biochemical properties of soil were conditioned by secondary anthropogenically induced succession after the abandonment of arable lands.     

Seasonal temperatures for the past ∼400 years reconstructed from diatom and chironomid assemblages in a high-altitude lake (Lej da la Tscheppa,Switzerland)

We analysed a 42 cm long sediment record from Lej da la Tscheppa, a high-altitude lake (2,616 m a.s.l.) in the Upper Engadine valley (Switzerland) for subfossil diatoms, chironomids and pollen. The chronology of the top 21 cm of the record was established using ²¹⁰Pb analysis using a constant-rate-of-supply model, and validated with ¹³⁷Cs measurements and the content of spheroidal carbonaceous particles. A tentative chronology for the lower part of the core was obtained through extrapolation of the sedimentation rates in the uppermost part of the record. Pollen assemblages in the record reflect regional changes in forestation and land-use patterns in the Upper Engadine valley and show no evidence of significant local human activity in the lake’s catchment. Diatom assemblages record a distinct increase in planktonic taxa since the early 19th century, suggesting a decrease in the duration of ice-cover. In contrast, chironomid assemblages remained stable during a large part of the record. We applied an established chironomid-based July air temperature transfer function and a newly developed diatom-based spring air temperature transfer function to reconstruct past seasonal air temperature changes at Lej da la Tscheppa. The reconstructions indicate a diatom-inferred warming trend in spring temperatures during the past ca. 400 years, whereas chironomid-inferred summer temperatures suggest a slight cooling trend. These biota-based reconstructions are in good agreement with the centennial-scale temperature trend in an independent reconstruction of regional temperatures in the Upper Engadine region based on instrumental records and documentary proxy evidence from the Alps. Our results suggest that, in high-altitude lakes, independent chironomid- and diatom-based seasonal temperature reconstruction is possible and can be successfully used to track seasonal temperature trends.     

Control strategies and experimental verifications of the electromagnetic mass damper system for structural vibration control

The electromagnetic mass damper （EMD） control system, as an innovative active control system to reduce structural vibration, offers many advantages over traditional active mass driver/damper （AMD） control systems. In this paper, studies of several EMD control strategies and bench-scale shaking table tests of a two-story model structure are described. First, two structural models corresponding to uncontrolled and Zeroed cases are developed, and parameters of these models are validated through sinusoidal sweep tests to provide a basis for establishing an accurate mathematical model for further studies. Then, a simplified control strategy for the EMD system based on the pole assignment control algorithm is proposed. Moreover, ideal pole locations are derived and validated through a series of shaking table tests. Finally, three benchmark earthquake ground motions and sinusoidal sweep waves are imposed onto the structure to investigate the effectiveness and feasibility of using this type of innovative active control system for structural vibration control. In addition, the robustness of the EMD system is examined. The test results show that the EMD system is an effective and robust system for the control of structural vibrations.     

Co–rich Mn crusts from the Magellan Seamount cluster: the long journey through time

The Magellan seamounts began forming as large submarine shield volcanoes south of the equator during the Cretaceous. These volcanoes formed as a cluster on the small Pacific plate in a period when tectonic stress was absent. Thermal subsidence of the seafloor led to sinking of these volcanoes and the formation of guyots as the seamounts crossed the equatorial South Pacific (10–0°S) sequentially and ocean surface temperatures became too high for calcareous organisms to survive. Guyot formation was completed between about 59 and 45 Ma and the guyots became phosphatized at about 39–34 and 27–21 Ma. Ferromanganese crusts began formation as proto-crusts on the seamounts and guyots of the Magellan Seamount cluster towards the end of the Cretaceous up to 55 Ma after the formation of the seamounts themselves. The chemical composition of these crusts evolved over time in a series of steps in response to changes in global climate and ocean circulation. The great thickness of these crusts (up to 15–20 cm) reflects their very long period of growth. The high Co contents of the outer parts of the crusts are a consequence of the increasing deep circulation of the ocean and the resulting deepening of the oxygen minimum zone with time. Growth of the Co-rich Mn crusts in the Magellan Seamount cluster can be considered to be the culmination of a long journey through time.     

Estimating the geostrophic velocity obtained by HF radar observations in the upstream area of the Kuroshio

A method to extract geostrophic current in the daily mean HF radar data in the Kuroshio upstream region is established by comparison with geostrophic velocity determined from the along-track altimetry data. The estimated Ekman current in the HF velocity is 1.2% (1.5%) and 48° (38°)-clockwise rotated with respect to the daily mean wind in (outside) the Kuroshio. Furthermore, additional temporal smoothing is found necessary to remove residual ageostrophic currents such as the inertial oscillation. After removal of the ageostrophic components, the HF geostrophic velocity agrees well with that from the altimetry data with rms difference 0.14 (0.12) m/s in (outside) the Kuroshio.