Post-collision magmatism and tectonics in northwest Anatolia

A suite of biotite-hornblende granodiorite intrusions has been emplaced into blueschist-facies metasediments in northwest Anatolia, following collision between two continental margins, now represented by the Tavanli and Sakarya zones. The ⁴⁰Ar/³⁹Ar ages of phengites and glaucophanes from the blueschists, metamorphosed under unusually high P-low T conditions (P=20±2 kbar, T=430±30° C), suggest that metamorphism apparently occurred over a period spanning at least 20 Ma from 108 to 88 Ma. Post-tectonic granodiorites were emplaced during the Eocene (53 to 48 Ma) resulting in a cordierite and andalusite-bearing thermal aureole, indicative of pressures of 3 kbar. Trace-element systematics of the granodiorites are consistent with a derivation either from mantle-derived magmas by fractional crystallisation in shallow magma chambers, or from anatexis of crustal lithologies of internediate composition at pressures <10 kbar. The preservation of high P-low T assemblages in the blueschists together with the range of ages determined for blueschist-facies metamorphism are indicative of rapid exhumation of delaminated fragments from a subducted continental margin. However decompression melting of the crust is unlikely to have been a significant cause of magmatism, both because exhumation of the blueschists from deep crustal levels predated magmatism by at least 25 Ma, and because of the small melt fraction (<0.1) that may be generated in crustal lithologies by this process. Melting in the mantle wedge is required either to generate a primary melt for the derivation of magmas of intermediate composition or to provide an advective heat source for crustal melting. The cause of melt formation in the upper mantle may be related to the termination of subduction following collision during the Mid-Eocene.     

The trace element composition of silicate inclusions in diamonds: a review

On a global scale, peridotitic garnet inclusions in diamonds from the subcratonic lithosphere indicate an evolution from strongly sinusoidal REE_N, typical for harzburgitic garnets, to mildly sinusoidal or “normal” patterns (positive slope from LREE_N to MREE_N, fairly flat MREE_N–HREE_N), typical for lherzolitic garnets. Using the Cr-number of garnet as a proxy for the bulk rock major element composition it becomes apparent that strong LREE enrichment in garnet is restricted to highly depleted lithologies, whereas flat or positive LREE–MREE slopes are limited to less depleted rocks. For lherzolitic garnet inclusions, there is a positive relation between equilibration temperature, enrichment in MREE, HREE and other HFSE (Ti, Zr, Y), and decreasing depletion in major elements. For harzburgitic garnets, relations are not linear, but it appears that lherzolite style enrichment in MREE–HREE only occurs at temperatures above 1150–1200 °C, whereas strong enrichment in Sr is absent at these high temperatures. These observations suggest a transition from melt metasomatism (typical for the lherzolitic sources) characterized by fairly unfractionated trace and major element compositions to metasomatism by CHO fluids carrying primarily incompatible trace elements. Melt and fluid metasomatism are viewed as a compositional continuum, with residual CHO fluids resulting from primary silicate or carbonate melts in the course of fractional crystallization and equilibration with lithospheric host rocks.

Eclogitic garnet inclusions show “normal” REE_N patterns, with LREE at about 1× and HREE at about 30× chondritic abundance. Clinopyroxenes approximately mirror the garnet patterns, being enriched in LREE and having chondritic HREE abundances. Positive and negative Eu anomalies are observed for both garnet and clinopyroxene inclusions. Such anomalies are strong evidence for crustal precursors for the eclogitic diamond sources. The trace element composition of an “average eclogitic diamond source” based on garnet and clinopyroxene inclusions is consistent with derivation from former oceanic crust that lost about 10% of a partial melt in the garnet stability field and that subsequently experienced only minor reenrichment in the most incompatible trace elements. Based on individual diamonds, this simplistic picture becomes more complex, with evidence for both strong enrichment and depletion in LREE.

Trace element data for sublithospheric inclusions in diamonds are less abundant. REE in majoritic garnets indicate source compositions that range from being similar to lithospheric eclogitic sources to strongly LREE enriched. Lower mantle sources, assessed based on CaSi–perovskite as the principal host for REE, are not primitive in composition but show moderate to strong LREE enrichment. The bulk rock LREE_N–HREE_N slope cannot be determined from CaSi–perovskites alone, as garnet may be present in these shallow lower mantle sources and then would act as an important host for HREE. Positive and negative Eu anomalies are widespread in CaSi–perovskites and negative anomalies have also been observed for a majoritic garnet and a coexisting clinopyroxene inclusion. This suggests that sublithospheric diamond sources may be linked to old oceanic slabs, possibly because only former crustal rocks can provide the redox gradients necessary for diamond precipitation in an otherwise reduced sublithospheric mantle.     

Diamondiferous lithospheric roots along the western margin of the Kalahari Craton—the peridotitic inclusion suite in diamonds from Orapa and Jwaneng

The Orapa and Jwaneng kimberlites are located along the western margin of the Kalahari Craton and the prevalence of eclogitic over peridotitic diamonds in both mines has recently been linked to lower P-wave velocities in the deep mantle lithosphere (relative to the bulk of the craton) to suggest a diamond formation event prompted by mid-Proterozoic growth and modification of preexisting Archean lithosphere (Shirey et al. 2002). Here we study peridotitic diamonds from both mines, with an emphasis on the style of metasomatic source enrichment, to evaluate their relationship with this major eclogitic diamond formation event. In their major element chemistry, the peridotitic inclusions compare well with a world-wide database but reveal differences to diamond sources located in the interior of the Western Terrane of the Kaapvaal block, where the classical mines in the Kimberley region are located. The most striking difference is the relative paucity of low-Ca (<2 wt% CaO in garnet) harzburgites and a low ratio of harzburgitic to lherzolitic garnets (2:1). This suggests that lithospheric mantle accreted to the rim of the Zimbabwe and Kaapvaal blocks was overall chemically less depleted. Alternatively, this more fertile signature may be assigned to stronger metasomatic re-enrichment but the trace element signature of garnet inclusions is not in favor of strong enrichment in major elements. For both mines the majority of lherzolitic and harzburgitic garnet inclusions are characterized by moderately sinusoidal REE_N patterns and low Ti, Zr and Y contents, indicative of a metasomatic agent with very high LREE/HREE and low HFSE. This is consistent with metasomatism by a CHO-fluid or, as modeled by Burgess and Harte (2003), a highly fractionated, low-volume silicate melt from the MORB-source. In both cases, changes in the major element chemistry of the affected rocks will be limited. In a few garnets from Orapa preferential MREE enrichment is observed, suggesting that the percolating fluid/melt fractionated a LREE-phyllic phase (such as crichtonite). The overall moderate degree of metasomatism reflected by the inclusion chemistry is in stark contrast to lithospheric sections for Orapa and Jwaneng based on mantle xenocrysts and xenoliths, revealing extensive mantle metasomatism (Griffin et al. 2003). This suggests that the formation of peridotitic diamonds predates the intensive modification of the subcratonic lithosphere during Proterozoic rifting and compression, implying that diamonds may survive major tectonothermal events.Editorial responsibility: J. Hoefs     

ALSEP-quasar differential VLBI

A program of ALSEP-Quasar Very Long Baseline Interferometry (VLBI) is being carried out at the Jet Propulsion Laboratory. These observations primarily employ a 4-antenna technique whereby simultaneous observations with two antennas at each end of an intercontinental baseline are used to derive the differential interferometric phase between a compact extragalactic radio source (usually a quasar) and a number of ALSEP transmitters on the lunar surface. A continuous ALSEP-quasar differential phase history over a few hour period will lead to milliarcsecond angular accuracy in measuring the lunar position against the quasar reference frame if suitable calibration measurements are obtained. Development of this application of the 4-antenna technique has been underway at JPL for more than a year and is now producing high quality data utilizing Deep Space Network (DSN) stations in Australia, Spain, and Goldstone, California as well as the STDN Apollo station at Goldstone. These high accuracy observations are of value to tie the lunar ephemeris to a nearly inertial extragalactic reference frame, to test gravitational theories, and to measure the Earth-Moon tidal friction interaction.This paper presents the results of one phase of research carried out at the Jet Propulsion Laboratory, California Institute of Technology, under Contract No. NAS 7-100, sponsored by the National Aeronautics and Space Administration.     

The equilibrium figures of Phobos and other small bodies

The shape of a close planetary satellite is distorted from a self-gravitating sphere into a triaxial ellipsoid maintained by tidal and centrifugal forces. Using the family of Roche ellipsoids calculated by Chandrasekhar, it should be possible in some cases to determine the density of an inner satellite by an accurate measurement of its shape alone. The equilibrium figure of Phobos is expected to be the most extreme of any satellite. The shape of Phobos as observed by Mariner 9 approaches but appears not to be a Roche ellipsoid, although the uncertainties of measurement remain too large to exclude the possibility. In any case, Phobos is so small that even the low mechanical strength of an impact-compressed regolith is sufficient to maintain substantial departures from the equipotential figure. If larger close satellites, particularly Amalthea, are found to be Roche ellipsoids, their densities can be estimated immediately from the data presented.Asteroids of size comparable to Phobos and Deimos appear to have more irregular shapes than the Martian satellites. This may reflect the absence of a deep regolith on those asteroids due to the low effective escape velocity for impact ejecta. For Phobos and Deimos, on the other hand, ejecta will tend to remain in orbit about Mars until swept up again by the satellite, contributing to a deeper equilibrium layer of debris.     

Inversion for elliptically anisotropic velocity using VSP reflection traveltimes

This paper presents a traveltime inversion approach, using the reflection traveltimes from offset VSP data, to reconstruct the horizontal and vertical velocities for stratified anisotropic media. The inverse problem is reduced to a set of linear equations, and solved by the singular value decomposition (SVD) technique. The validity of this inversion scheme is verified using two sets of synthetic data simulated using a finite‐difference method, one for an isotropic model and the other for an elliptically anisotropic model. The inversion result demonstrates that our anisotropic velocity inversion scheme may be applied to both isotropic and anisotropic media. The method is finally applied to a real offset VSP data set, acquired in an oilfield in northwestern China.     

Late Paleozoic orogeny in Alaska's Farewell terrane

Evidence is presented for a previously unrecognized late Paleozoic orogeny in two parts of Alaska's Farewell terrane, an event that has not entered into published scenarios for the assembly of Alaska. The Farewell terrane was long regarded as a piece of the early Paleozoic passive margin of western Canada, but is now thought, instead, to have lain between the Siberian and Laurentian (North American) cratons during the early Paleozoic. Evidence for a late Paleozoic orogeny comes from two belts located 100–200 km apart. In the northern belt, metamorphic rocks dated at 284–285 Ma (three ⁴⁰Ar/³⁹Ar white-mica plateau ages) provide the main evidence for orogeny. The metamorphic rocks are interpreted as part of the hinterland of a late Paleozoic mountain belt, which we name the Browns Fork orogen. In the southern belt, thick accumulations of Pennsylvanian-Permian conglomerate and sandstone provide the main evidence for orogeny. These strata are interpreted as the eroded and deformed remnants of a late Paleozoic foreland basin, which we name the Dall Basin. We suggest that the Browns Fork orogen and Dall Basin comprise a matched pair formed during collision between the Farewell terrane and rocks to the west. The colliding object is largely buried beneath Late Cretaceous flysch to the west of the Farewell terrane, but may have included parts of the so-called Innoko terrane. The late Paleozoic convergent plate boundary represented by the Browns Fork orogen likely connected with other zones of plate convergence now located in Russia, elsewhere in Alaska, and in western Canada.     

Regional patterns in the paragenesis and age of inclusions in diamond, diamond composition, and the lithospheric seismic structure of Southern Africa

The Archean lithospheric mantle beneath the Kaapvaal–Zimbabwe craton of Southern Africa shows ±1% variations in seismic P-wave velocity at depths within the diamond stability field (150–250 km) that correlate regionally with differences in the composition of diamonds and their syngenetic inclusions. Seismically slower mantle trends from the mantle below Swaziland to that below southeastern Botswana, roughly following the surface outcrop pattern of the Bushveld-Molopo Farms Complex. Seismically slower mantle also is evident under the southwestern side of the Zimbabwe craton below crust metamorphosed around 2 Ga. Individual eclogitic sulfide inclusions in diamonds from the Kimberley area kimberlites, Koffiefontein, Orapa, and Jwaneng have Re–Os isotopic ages that range from circa 2.9 Ga to the Proterozoic and show little correspondence with these lithospheric variations. However, silicate inclusions in diamonds and their host diamond compositions for the above kimberlites, Finsch, Jagersfontein, Roberts Victor, Premier, Venetia, and Letlhakane do show some regional relationship to the seismic velocity of the lithosphere. Mantle lithosphere with slower P-wave velocity correlates with a greater proportion of eclogitic versus peridotitic silicate inclusions in diamond, a greater incidence of younger Sm–Nd ages of silicate inclusions, a greater proportion of diamonds with lighter C isotopic composition, and a lower percentage of low-N diamonds whereas the converse is true for diamonds from higher velocity mantle. The oldest formation ages of diamonds indicate that the mantle keels which became continental nuclei were created by middle Archean (3.2–3.3 Ga) mantle depletion events with high degrees of melting and early harzburgite formation. The predominance of sulfide inclusions that are eclogitic in the 2.9 Ga age population links late Archean (2.9 Ga) subduction-accretion events involving an oceanic lithosphere component to craton stabilization. These events resulted in a widely distributed younger Archean generation of eclogitic diamonds in the lithospheric mantle. Subsequent Proterozoic tectonic and magmatic events altered the composition of the continental lithosphere and added new lherzolitic and eclogitic diamonds to the already extensive Archean diamond suite.     

Hg and As Minerals in Fluid Inclusions from the Williams Mine,Hemlo,and Their Genetic Implications

The Hemlo mineralization is enigmatic compared to general Archean lode gold deposits based on the fact that is characterized by an exotic mineralogy containing elements such as As,Hg,Sb,Ba,V and Mo.The genetic concepts range from syngenetc to epigenetic types of mineralization.This reconnaissance study was designed to examine the relationshp of Hg-As minerals with respect of fluid inclusions in the Williams mine(formerly known as the Page Williams mine)covering the A and C ore zones.