This study reports the results of the first40Ar/39Ar combined induction furnace and laser probe dating of phengites from the Mulhacen HP/LT metamorphic complex in the Betic Cordilleras, southern Spain. Laser step heating and spot fusion analyses on different halves of a split single grain were made with a continuous laser probe. Spot fusion analysis resulted in ages of about 30–31 Ma in the core and ages as low as 25–26 Ma in the rim. Laser step heating on the other half of the grain gave a spectrum with apparent ages increasing from about 25 Ma to 29.5 Ma. The age spectrum and the decreasing ages towards the rim of the grain may imply that resetting essentially occurred by volume diffusion of radiogenic40Ar due to late stage reheating resulting from extensional tectonics. Ages around 30 Ma in the core of the grain are interpreted as minimum estimates of the cooling age of the main tectono-metamorphic phaseD2.
Induction furnace step heating on phengite separates from mica schists and one gneiss resulted in two types of age spectra. Type I spectra show monotonously rising apparent ages from14.5 ± 1.9 Ma to20.7 ± 0.2 Ma, and in a second sample from16.9 ± 0.7 to29.7 ± 0.2 Ma. Type II spectra are characterized by plateaus of14.4 ± 0.1 Ma (the gneiss sample),17.3 ± 0.1 Ma and17.6 ± 0.1 Ma. Type II spectra show low temperature apparent ages significantly below the plateau age, implying resetting subsequent to initial cooling. Modelling of the age spectra demonstrated that the plateau ages are possibly the result of strong resetting (75–85% of argon loss) of an older isotope system. Total fusion of a number of phengite single grains from marbles taken close to type II mica schists yielded ages of15.4 ± 1.2 Ma and17.0 ± 0.7 Ma. The observed repeated resetting is coeval with major volcanic activity in basins adjacent to the metamorphic ranges, pointing to a resetting by advective fluid transport related to volcanism. 相似文献
The chemical compositions of synthetic paragonite-muscovitepairs were obtained by electron probe microanalysis of run productsprepared hydrothermally at 300, 400, 500, and 600 ?C and 2.07kbar. The microcrystalline run products were dispersed on polishedberyllium rods, and Na, K, and Si were determined simultaneously.Compositions were determined from K/Si and Na/Si ratios referredto standards. Tentative excess thermodynamic mixing properties of paragonite-muscovitecrystalline solutions, based on the two-phase composition dataand on X-ray diffraction data, are represented by the followingthird-order Margules formulation:
which leads to a critical temperature of 833 ?C and a criticalcomposition of 39.0 mole per cent Mu at 2.07 kbar (the criticalphase is probably metastable with respect to alkali feldsparand corundum). These results are quantitatively in agreementwith Iiyama's (1964) ion-exchange data. From relationships amongthe quantities (arctanh s)/s, In r2, and 1/T we obtain criticalconditions which are in good agreement with the above (Tc =829 ?C, N2c = 0.396). The critical curve obtained from the aboveMargules parameters is given by: Tc(?C) = 768.8 + 31.00P(kbar). The above results are complicated by polymorphism and by possiblelack of complete equilibrium between the two-mica synthesisproducts and possible substitution of hydronium for alkalies.We emphasize, therefore, that the phase diagrams and derivedmixing properties should be applied with caution to naturalmuscovite- and paragonite-bearing assemblages. 相似文献
The xenoliths of garnetclinopyroxenedisthene rocks(grospydites and associated kyanite eclogites) from the Zagadochnayakimberlite pipe in Yakutia have been studied in detail. Contraryto previous data, the presence of a continuous range in thepyrope-grossular series of garnets is shown on the basis ofnumerous X-ray data and 17 chemical analyses of garnets. Thisconclusion is confirmed by the study of separate grains withkyanite intergrowths from the kimberlite heavy fraction, whichare present in the kimberlite as the result of destruction ofgrospydite xenoliths, and possible, of garnet-kyanite rocksalso. A close connection of the calcium content in the garnetwith the sodium content in the coexisting clinopyroxes is alsoshown. An increase in the chemical potential of sodium resultsin the stability of the pryoxene-kyanite assemblage insteadof a garnet of intermediate composition (50 percent of grossular).The interval of the miscibility gap between calcium-rich andcalcium-poor garnets is increased in this way. The data of chemicalanalyses of 14 pyroxenes from the xenoliths indicate that theydiffer in the high aluminium and sodium content from other pyroxenesof eclogite-facies rocks. Chromium-rich bands with a high chromiumcontent in coexisting garnet, pyroxene, and kyantic have beenoccasionally found in the xenoliths. A study has been made ofthe chrome-kyanite with 12.86 per Cr202. The presence of chromium-richminerals in the grospydite xenoliths confrms their connectionwith ultrabasic rocks. 相似文献
Air photo interpretation along with limited field work is the basis of a compilation map of Tertiary structures in the Upper Paleozoic through Mesozoic platform cover strata of Nordenskiold Land. Permian Kapp Starostin Formation strata form a continuous marker horizon delineating both a large NE-verging fold complex, which involves the basement (Hecla Hoek sequence) through basal Tertiary strata, and somewhat smaller scale folds, some of which may have formed in association with detachments and thrusts within the platform cover sequence. The map pattern is both a function of local structural plunge and changes in fold geometry along strike. Regional considerations suggest that subsurface basement-involved thrusts exist. In S Nordenskiold Land, to the E of folded Kapp Starostin Formation strata, a 3.5 km wide zone of folding and thrusting in Triassic and Jurassic strata above a subhorizontal decollement is inferred to occur. Further E is the W limb of the central Tertiary basin syncline. 相似文献
Abstract The Palawan microcontinental block collided with the Philippine Mobile Belt in the Central Philippine region resulting in the counterclockwise rotation of Mindoro– Marinduque and clockwise rotation of Panay. The collision also brought about the clockwise rotation of north-east Negros, Cebu, north-west Masbate and Bohol (collectively called the Western Visayan block), resulting into their present-day northeast–southwest trend. This suggests a far more dramatic role of the collision than was previously recognized. Furthermore, the south-east Sulu Sea sub-basin is inferred to have also undergone collision-related clockwise rotation which can account for the observed east-west trending magnetic lineations in the basin. Aside from explaining the contrasting morphological trends of the different islands in Central Philippines, the rotation can also explain, albeit in a different way, how the belts of sedimentary basins, ophiolites and arcs in Panay and Negros can extend to Northern Luzon. Published paleomagnetic data suggest that the collision-related rotation commenced during the early to middle Miocene and had ceased by the late Miocene. 相似文献