Site characterization in densely fractured dolomite: comparison of methods

One of the challenges in characterizing fractured-rock aquifers is determining whether the equivalent porous medium approximation is valid at the problem scale. Detailed hydrogeologic characterization completed at a small study site in a densely fractured dolomite has yielded an extensive data set that was used to evaluate the utility of the continuum and discrete-fracture approaches to aquifer characterization. There are two near-vertical sets of fractures at the site; near-horizontal bedding-plane partings constitute a third fracture set. Eighteen boreholes, including five coreholes, were drilled to a depth of approximately 10.6 m. Borehole geophysical logs revealed several laterally extensive horizontal fractures and dissolution zones. Flowmeter and short-interval packer testing identified which of these features were hydraulically important. A monitoring system, consisting of short-interval piezometers and multilevel samplers, was designed to monitor four horizontal fractures and two dissolution zones. The resulting network consisted of >70 sampling points and allowed detailed monitoring of head distributions in three dimensions. Comparison of distributions of hydraulic head and hydraulic conductivity determined by these two approaches suggests that even in a densely fractured-carbonate aquifer, a characterization approach using traditional long-interval monitoring wells is inadequate to characterize ground water movement for the purposes of regulatory monitoring or site remediation. In addition, traditional multiwell pumping tests yield an average or bulk hydraulic conductivity that is not adequate for predicting rapid ground water travel times through the fracture network, and the pumping test response does not appear to be an adequate tool for assessing whether the porous medium approximation is valid.     

Chronology of Sediment Deposition in Upper Klamath Lake, Oregon

A combination of tephrochronology and ¹⁴C, ²¹⁰Pb, and ¹³⁷Cs measurements provides a robust chronology for sedimentation in Upper Klamath Lake during the last 45 000 years. Mixing of surficial sediments and possible mobility of the radio-isotopes limit the usefulness of the ¹³⁷Cs and ²¹⁰Pb data, but ²¹⁰Pb profiles provide reasonable average sediment accumulation rates for the last 100–150 years. Radiocarbon ages near the top of the core are somewhat erratic and are too old, probably as a result of detrital organic carbon, which may have become a more common component in recent times as surrounding marshes were drained. Below the tops of the cores, radiocarbon ages in the center of the basin appear to be about 400 years too old, while those on the margin appear to be accurate, based on comparisons with tephra layers of known age.Taken together, the data can be combined into reasonable age models for each site. Sediments have accumulated at site K1, near the center of the basin, about 2 times faster than at site CM2, on the margin of the lake. The rates are about 0.10 and 0.05 cm/yr, respectively. The chronological data also indicate that accumulation rates were slower during the early to middle Holocene than during the late Holocene, consistent with increasing wetness in the late Holocene.     

Neoformation of Ni phyllosilicate upon Ni uptake on montmorillonite: A kinetics study by powder and polarized extended X-ray absorption fine structure spectroscopy

Wet chemistry kinetics and powder and polarized extended X-ray absorption fine structure (EXAFS and P-EXAFS) spectroscopy were combined to investigate the mechanism of Ni uptake on montmorillonite, at pH 8, high ionic strength (0.2 M Ca(NO₃)₂), initial Ni concentration of 660 μM, and solid concentration of 5.3 g/L. Approximately 20% of Ni sorbed within the first 24 h; thereafter, the Ni uptake rate slowed, and 12% of the initial Ni concentration remained in solution after 206 d of reaction time. Powder EXAFS spectra collected on wet pastes at 1, 14, 90, and 206 d showed the presence of Ni-Ni pairs at ∼3.08 Å in an amount that gradually increased with time. Results were interpreted by the nucleation of a Ni phase having either an α-Ni-hydroxide- or a Ni-phyllosilicate-like local structure. The latter possibility was confirmed by recording P-EXAFS spectra of a highly textured, self-supporting montmorillonite film prepared in the same conditions as the wet samples and equilibrated for 14 d. The orientation distribution of the c*-axes of individual clay particles off the film plane, as measured by quantitative texture analysis, was 32.8° full width at half maximum, and this value was used to correct from texture effect the effective numbers of Ni and Si nearest neighbors determined by P-EXAFS. Ni atoms were found to be surrounded by 2.6 ± 0.5 Ni atoms at 3.08 Å in the in-plane direction and by 4.2 ± 0.5 Si atoms at 3.26 Å in the out-of-plane direction. These structural parameters, but also the orientation and angular dependence of the Ni and Si shells, strongly support the formation of a Ni phyllosilicate having its layers parallel to the montmorillonite layers. The neoformation of a phyllosilicate on metal uptake on montmorillonite, documented herein for the first time, has important geochemical implications because this dioctahedral smectite is overwhelmingly present in the environment. The resulting sequestration of sorbed trace metals in sparingly soluble phyllosilicate structure may durably decrease their migration and bioavailability at the Earth’s surface and near surface.     

A land-use and water-quality history of White Rock Lake reservoir, Dallas, Texas, based on paleolimnological analyses

White Rock Lake reservoir in Dallas, Texas contains a 150-cm sediment record of silty clay that documents land-use changes since its construction in 1912. Pollen analysis corroborates historical evidence that between 1912 and 1950 the watershed was primarily agricultural. Land disturbance by plowing coupled with strong and variable spring precipitation caused large amounts of sediment to enter the lake during this period. Diatoms were not preserved at this time probably because of low productivity compared to diatom dissolution by warm, alkaline water prior to burial in the sediments. After 1956, the watershed became progressively urbanized. Erosion decreased, land stabilized, and pollen of riparian trees increased as the lake water became somewhat less turbid. By 1986 the sediment record indicates that diatom productivity had increased beyond rates of diatom destruction. Neither increased nutrients nor reduced pesticides can account for increased diatom productivity, but grain size studies imply that before 1986 diatoms were light limited by high levels of turbidity. This study documents how reservoirs may relate to land-use practices and how watershed management could extend reservoir life and improve water quality.     

San Agustin Plains, New Mexico: Age and paleoenvironmental potential reassessed

Paleomagnetic analysis of samples from the original 600-m-long core from the San Agustin Plains, New Mexico, showed an unquestionable reversal stratigraphy dating the record back to at least 1.6 my. Analysis of pollen, ostracodes, and algae of a duplicate sample section in the vicinity of the original coring site and spanning the last 18,000 yr B.P. shows a much higher resolution than the earlier results.     

Late Cenozoic lacustrine and climatic environments at Tule Lake,northern Great Basin,USA

Cores of lake sediment to a depth of 334 m in the town of Tulelake, Siskiyou County, northern California, document the late Cenozoic paleolimnologic and paleoclimatic history of the northwestern edge of the Great Basin. The cores have been dated by radiometric, tephrochronologic and paleomagnetic analyses. Lacustrine diatoms are abundant throughout the record and document a nearly continuous paleolimnologic history of the Tule Lake basin for the last 3 Myr. During most of this time, this basin (Tule Lake) was a relatively deep, extensive lake. Except for a drier (and cooler?) interval recorded by Fragilaria species about 2.4 Ma, the Pliocene is characterized by a dominance of planktonic Aulacoseira solida implying a warm monomictic lake under a climatic regime of low seasonality. Much of the Pleistocene is dominated by Stephanodiscus and Fragilaria species suggesting a cooler, often drier, and highly variable climate. Benthic diatoms typical of alkaline-enriched saline waters commonly appear after 1.0 Ma, and tephrochronology indicates slow deposition and possible hiatuses between about 0.6 and 0.2 Ma. The chronology of even-numbered oxygen isotope stages approximately matches fluctuations in the abundance of Fragilaria since 800 ka indicating that glacial periods were expressed as drier environments at Tule Lake. Glacial and interglacial environments since 150 ka were distinct from, and more variable than, those occurring earlier. The last full glacial period was very dry, but shortly thereafter Tule Lake became a deep, cool lacustrine system indicating a substantial increase in precipitation. Aulacoseira ambigua characterized the latest glacial and Holocene record of Tule Lake. Its distribution indicates that warmer and wetter climates began about 15 ka in this part of the Great Basin. Diatom concentration fluctuates at 41 000 year intervals between 3.0 and 2.5 Ma and at approximately 100 000 year intervals after 1.0 Ma. In the late Pliocene and early Pleistocene, Aulacoseira solida percentages wax and wane in an approximately 400 000 year cycle. The possible response of Tule Lake diatom communities to orbitally-induced insolation cycles underscores the importance of this record for the study of late Cenozoic paleoclimate change.     

Paleolimnology of two lakes in the Klutlan Glacier region,Yukon Territory,Canada

Lakes developed on progressively younger end moraines of the Klutlan Glacier were initially assumed to have originated shortly after moraine emplacement and to have persisted to the present. Limnological differences between lakes on old vs young moraines were thought to result from limnological maturation within the lakes and ponds themselves and in response to the development of soils and vegetation on moraine surfaces. This study represents a paleolimnological test of this hypothesis. If true, the first-formed sediments of lakes on old moraines should be comparable to sediments presently forming in lakes on young moraines. Geochemical and paleontological studies of surface sediment to a series of lakes on progressively older moraines provide baseline information for comparing successive levels of lake sediment cores from older moraines. Results indicate that the time of lake initiation seldom reflects moraine age. Even on the oldest moraine (Harris Creek), lake basins are presently forming. Their sediment character more closely relates to the rapidity of basin formation due to melting of buried ice than to age of the lake itself or of the moraine on which it is situated. Vegetation and soil development play an important but secondary role in determining the character of lake sediments; rapid subsidence can convert humic-water lakes surrounded by second-generation spruce forests into turbid-water lakes with unstable, slumping margins. A detailed paleolimnological study of two lakes, one on the unglaciated upland and another in an outwash channel penetrating the oldest moraine, revealed progressive limnologic changes through time, suggesting that their basins were stable for 1200 and 400 yr, respectively. The changes in diatom stratigraphy of these lakes appear to relate to natural limnological changes associated with lake maturation and accumulation of nutrients as well as to changes in the surrounding vegetation and soils.     

The influence of bend amplitude and planform morphology on flow and sedimentation in submarine channels

We present a series of experiments that investigate the morphology of sediment deposits within sinuous submarine channels of different sinuosity (S = 1.14–1.94) and planform (symmetric and asymmetric bends), generated by bedload-dominated turbidity current flows. Flows were generated by releasing dense saline gravity currents over a mobile sediment bed through pre-formed sinuous channels. Flows had a basal-outwards helicity and produced a characteristic bed morphology with point bars downstream of the bend apex at the inside of bends and scour at the outside of bends. An increasing loss of fluid through overspill with increasing channel sinuosity results in a decreasing magnitude of cross-stream velocity downstream, a decreasing amount of erosion and deposition, and decreasing transverse slopes of in-channel deposits. Basal fluid from within the channel is transported over the outer-levee at bends, implying that proximal outer-bend levee deposits will have similar sediment composition to that within the channel. More deposition of coarse material might be expected on levees and in overbank regions close to higher amplitude bends. No simple relationship was observed between superelevation and sinuosity, probably due to changes in the relative influences of downstream velocity and bend curvature on centrifugal force and inertial run-up. In the channel with the tightest initial bend curvature, overspill fluid from Bend 1 re-entered the channel at Bend 2, dominating flow characteristics and disrupting the basal-outwards helicity observed in the other channels. Higher sinuosity channels and those with shallow regional and levee slopes are thus more likely to have a higher proportion of anomalous flow and sedimentation patterns due to the influence of overspill fluid re-entry into the channel. The results of this investigation are combined with published observations to enable the synthesis of a new model for sedimentation in sinuous submarine channels.