Lake Torfadalsvatn: a high resolution record of the North Atlantic ash zone I and the last glacial-interglacial environmental changes in Iceland

High resolution environmental records with a refined chronology are essential to understand, reconstruct and model the climate dynamics of the last glacial-interglacial transition. Sediments from Lake Torfadalsvatn in northern Iceland contain at least four primary volcanic tephras that belong to ash zone I in the North Atlantic deep-sea cores. We chemically define these basaltic/rhyolitic tephras and the high resolution allows us to date them to about 10,800, 10,600, 9300 and 8900 BP. This detailed tephrostratigraphy will act as a refined dating and correlation tool in the North Atlantic region and enable calibration between different absolute chronologies. The pollen stratigraphy of the sediments suggests that by 10,400 ¹⁴C years BP plant colonization of coastal north Iceland had begun. The pollen stratigraphy shows a succession of pioneer plants, from open tundra vegetation towards birch-juniper woodland, which probably also reflects a transition from a cool climate at 10,400 BP to conditions similar to today's sub-polar oceanic climate around 9200 BP. Diatom data largely concur with the climatic information from pollen, indicating gradually increasing productivity in the lake.     

Microspar development during early marine burial diagenesis: a comparison of Pliocene carbonates from the Bahamas with Silurian limestones from Gotland (Sweden)

Comparison of ultrastructures in Pliocene periplatform carbonates from the Bahamas with Silurian limestones from Gotland (Sweden) reveals that despite the differences in primary sediment composition and age, they reflect a similar mechanism of lithification. In both sequences calcite microspar was formed as a primary cement at an early stage of marine burial diagenesis. Neither significant compression nor meteoric influence are necessary for the formation of calcite microspar. A model is proposed for the process of microsparitic cementation of fine-grained aragonite needle muds comprising four stages: (1) unconsolidated, aragonite-dominated carbonate mud; (2) precipitation of microspar that engulfs aragonite needles; (3) dissolution of aragonite, resulting in pitted surfaces of the microspar crystals; and (4) slight recrystallization. Our results contradict the widespread opinion that microspar necessarily is a product of secondary recrystallization of a previously lithified micrite.     

The Stonyford Volcanic Complex: a Forearc Seamount in the Northern California Coast Ranges

Jurassic age volcanic rocks of the Stonyford volcanic complex(SFVC) comprise three distinct petrological groups based ontheir whole-rock geochemistry: (1) oceanic tholeiites; (2) transitionalalkali basalts and glasses; (3) high-Al, low-Ti tholeiites.Major and trace element, and Sr–Nd–Pb isotopic dataindicate that the oceanic tholeiites formed as low-degree partialmelts of normal mid-ocean ridge basalt (N-MORB)-source asthenospheresimilar in isotope composition to the East Pacific Rise today;the alkalic lavas were derived from an enriched source similarto that of E-MORB. The high-Al, low-Ti lavas resemble second-stagemelts of a depleted MORB-source asthenosphere that formed bymelting spinel lherzolite at low pressures. Trace element systematicsof the high-Al, low-Ti basalts show the influence of an enrichedcomponent, which overprints generally depleted trace elementcharacteristics. Tectonic discrimination diagrams show thatthe oceanic tholeiite and alkali suites are similar to present-daybasalts generated at mid-oceanic ridges. The high-Al, low-Tisuite resembles primitive arc basalts with an enriched, alkalibasalt-like overprint. Isotopic data show the influence of recycledcomponents in all three suites. The SFVC was constructed ona substrate of normal Coast Range ophiolite in an extensionalforearc setting. The close juxtaposition of the MORB-like olivinetholeiites with alkali and high-Al, low-Ti basalts suggestsderivation from a hybrid mantle source region that includedMORB-source asthenosphere, enriched oceanic asthenosphere, andthe depleted supra-subduction zone mantle wedge. We proposethat the SFVC formed in response to collision of a mid-oceanridge spreading center with the Coast Range ophiolite subductionzone. Formation of a slab window beneath the forearc duringcollision allowed the influx of ridge-derived magmas or themantle source of these magmas. Continued melting of the previouslydepleted mantle wedge above the now defunct subduction zoneproduced strongly depleted high-Al, low-Ti basalts that werepartially fertilized with enriched, alkali basalt-type meltsand slab-derived fluids. KEY WORDS: CRO; oceanic basalts; California     

The Sulfide Capacity and the Sulfur Content at Sulfide Saturation of Silicate Melts at 1400{degrees}C and 1 bar

The solubility of sulfur as S^2– has been experimentallydetermined for 19 silicate melt compositions in the system CaO–MgO–Al₂O₃–SiO₂(CMAS)± TiO₂ ± FeO, at 1400°C and 1 bar, using CO–CO₂–SO₂gas mixtures to vary oxygen fugacity (fO₂) and sulfur fugacity(fS₂). For all compositions, the S solubility is confirmed tobe proportional to (fS₂/fO₂)^1/2, allowing the definition ofthe sulfide capacity (C_S) of a silicate melt as C_S = [S](fO₂/fS₂)^1/2.Additional experiments covering over 150 melt compositions,including some with Na and K, were then used to determine C_Sas a function of melt composition at 1400°C. The resultswere fitted to the equation     

ISLAND SOJOURNS

ABSTRACT. Islands have long held a central place in Western cultures' mythical geographies. They have been associated for centuries with heroic journeys and holy quests, imagined realms of magical transformations. Islands have also been sites of significant rites of passage, and they continue to perform this function in the modern secular world. Today, popular islomania is expressed in the frequency of seasonal sojourning on European and American archipelagos. No longer destinations of permanent residence, islands now provide access to a sense of temporal and spatial rootedness that is no longer available on mainlands. They loom large on the mental maps even of those who rarely, if ever, visit them.     

A simulation model of alluvial stratigraphy

The quantitative model presented simulates the development of a two-dimensional alluvial sedimentary succession beneath a floodplain traversed by a single major river. Several inter-related effects which influence the distribution of channel-belt sand and gravel bodies within overbank fines are accounted for. These are (a) laterally variable aggradation, (b) compaction of fine sediment, (c) tectonic movement at floodplain margins, and (d) channel avulsion. Selected experiments with the model show how the interconnectedness and areal density of channel-belt deposits decrease with increasing floodplain width/channel-belt size, mean avulsion period, and channel-belt aggradation rate. Separation of stream patterns based on interconnectedness and channel deposit density is difficult. Tectonic movements do not have a significant influence upon the successions unless a preferred direction of tilting is maintained (half-graben). Then channel-belt deposits showing offlap tendencies tend to cluster adjacent to the active floodplain margin, leaving dominantly fine-grained alluvium to accumulate on the inactive side. Individual channel-belt deposits thicken during aggradation, although a self-regulating limit to such thickening is likely to operate. ‘Multistorey’features resulting from aggradation may be difficult to tell apart from those arising through superposition of distinct channel-belt deposits of avulsive origin.     

Quantifying septic nitrogen loadings to receiving waters: Waquoit Bay,Massachusetts

Abstract

Waquoit Bay, a shallow bay on Cape Cod, Massachusetts, is exhibiting symptoms of eutrophication, largely attributed to septic nitrogen inputs. This study assessed septic nitrogen inputs by linking a three-dimensional ground-water model, a geographic information system (GIS), and a customized spatio-temporal nitrogen loading program. Owing to the slow speed of ground-water movement, the bulk of septic nitrogen entering the bay lags behind development by nearly a decade. Even if residential development is held at 1989 levels, nitrogen input from septic systems wilt increase by 36% over the current levels. At full residential build-out (i.e., development), septic nitrogen loading will eventually increase to more than twice the current levels.     

Fluid Flow During Contact Metamorphism of Ophicarbonate Rocks in the Bergell Aureole, Val Malenco, Italian Alps

Contact-mctamorphic assemblages in ophicarbonate from the Bergellaureole correspond either to model isobaric invariant T-XCO₂points [Atg-Cal-Di-Tr-Fo (6 samples) and Atg-Cal-Tr-Fo-Dol (2)]or to isobaric univariant T-XCO₂, curves [Tr-Cal-Di-Atg (18),Tr-Dol-Atg-Cal (1), Atg-Cal-Fo-Di (1), and Atg-Cal-Tr-Fo (1)].Calcite-dolomite thermometry and mineral-fluid equilibria inthe invariant assemblages record T=440–540C at P=3•5kbar. Equilibrium metamorphic fluids were very H₂O rich withX CO₂,=0•001–0•027. In the invariant assemblagesTr + Fo were produced by prograde decarbonation-dehydrationreactions. In contrast, measured modes and reaction texturesin samples with univariant assemblages indicate thai Tr wasproduced by carbonation reactions. The apparent paradox of simultaneousdecarbonation reactions in the model isobaric invariant assemblagesand carbonation reactions in univariant assemblages is resolvedby local mineral-fluid equilibrium and fluid flow through ophicarbohatesin the direction of decreasing temperature as the aureole heated.Time-integrated flux (q) was computed from measured reactionprogress in 28 samples for models of both horizontal and verticaldown-temperature flow. Results are similar, with q decreasingrapidly from (0•2–5•1) 10⁵ cm³ fluid/cm² rock1•3–1•7 km from the intrusion to 0–0•610⁵cm³/cm² at 1•8–4•0 km. The decrease in q ismore consistent with vertical than horizontal flow. Variationsin time-integrated flux of more than an order of magnitude arerecorded by samples from the same outcrop. The absence of carbonatein adjacent metaperidotite indicates that flow was confinedto the ophicarbonate. Channelized, spatially heterogeneous,vertical flow can be explained by the brecciation and strongvertical foliation of the ophicarbonate relative to surroundingmassive metaperidotite. Generation of metamorphicfluids by decarbonation-dehydrationreactions within the ophicarbonates explains larger averageflux 1–2 km from the intrusion compared with more distalpoints. KEY WORDS: Bergell; contact metamorphism; fluid flow; ophicarbonate ^*Telephone: (410) 516-8121. Fax: (410) 516-7933     

An experimental study of flow, bedload transport and bed topography under conditions of erosion and deposition and comparison with theoretical models

The nature of flow, sediment transport and bed texture and topography was studied in a laboratory flume using a mixed size-density sediment under equilibrium and non-equilibrium (aggradational, degradational) conditions and compared with theoretical models. During each experiment, water depth, bed and water surface elevation, flow velocity, bed shear stress, bedload transport and bed state were continuously monitored. Equilibrium, uniform flow was established with a discharge of about 0.05 m³ s^?1, a flow depth of about 0.01 m, a flow velocity of about 0.81–0.88 m s^?1, a spatially averaged bed shear stress of about 1.7–2.2 Pa and a sediment transport rate of about 0.005–0.013 kg m^?1 s^?1 (i.e. close to the threshold of sediment transport). Such equilibrium flow conditions were established prior to and at the end of each aggradation or degradation experiment. Pebble clusters, bedload sheets and low-lying bars were ubiquitous in the experiments. Heavy minerals were relatively immobile and occurred locally in high concentrations on the bed surface as lag deposits. Aggradation was induced by (1) increasing the downstream flow depth (flume tilting) and (2) sediment overloading. Tilt-induced aggradation resulted in rapid deposition in the downstream half of the flume of a cross-stratified deposit with downstream dipping pebbles (pseudo-imbricated). and caused a slight decrease in the equilibrium mean water surface slope and total bedload transport rate. These differences between pre- and post-aggradation equilibrium flow conditions are due to a decrease in the local grain roughness of the bed. Sediment overloading produced a downstream fining and thinning wedge of sediment with upstream dipping pebbles (imbricated), whereas the equilibrium flow and sediment transport conditions remained relatively unchanged. Degradation was induced by (1) decreasing the downstream flow depth (flume tilting) and (2) cutting off the sediment feed. Tilt-induced degradation produced rapid downstream erosion and upstream deposition due to flow convergence with little change to the equilibrium flow and sediment transport conditions. The cessation of sediment feed produced degradation and armour development, a reduction in the mean water surface slope and flow velocity, an increase in flow depth, and an exponential decrease in bedload transport rate as erosion proceeded. A bedload transport model predicted total and fractional transport rates extremely well when the coarse-grained (or bedform trough) areas of the bed are used to define the sediment available to be transported. A sediment routing model, MIDAS, also reproduced the equilibrium and non-equilibrium flow conditions, total and fractional bedload transport rates and changes in bed topography and texture very well.     

An early Holocene caribou antler from northern Ellesmere Island, Canadian Arctic Archipelago

During the last glaciation of northern Ellesmere Island many areas remained ice-free. A caribou antler from deglacial-marine sediments in Clements Markham Inlet dates 8,415 ± 135 B.P. (S-2501). If locally derived it places caribou at the northern limit of their contemporary range at the onset of deglaciation in this area. Immediately to the south, on the Hazen Plateau, ice remained at its limit until c . 8,000 B.P. Therefore, this antler may indicate the presence of caribou during full glacial time.