Dissolved organic carbon dynamics in two streams draining forested catchments at loch ard,Scotland

Dissolved organic carbon (DOC) was measured at four or eight hour intervals between mid-1989 and mid-1991 in two catchments in west central Scotland. The experimental catchment had been recently clear-felled and the control remained under forest. The amount of DOC varied during individual storm events following the stream hydro-graph. Maximum variations were found in the summer half-year and in the clear-felled catchment. There was also evidence of the exhaustion of DOC in the later events of a sequence. Differences between the catchments were related to catchment characteristics and to land-use change. The reduced magnitude of variation in DOC with discharge in the control stream was due to the influence of a wetland area through which the stream flowed. The mean DOC concentrations were similar in the two streams and annual exports were 15 g m^?2 from the control and 16g m^?2 from the felled catchment. The stream draining the clear-felled catchment had greater high flow DOC concentrations in the summer half-year, probably due to the effect of greater mean summer temperatures on DOC release and of the greater supply of organic debris in the stream channel.     

Reliability assessment of serviceability performance of braced retaining walls using a neural network approach

In urban environments, one major concern with deep excavations in soft clay is the potentially large ground deformations in and around the excavation. Excessive movements can damage adjacent buildings and utilities. There are many uncertainties associated with the calculation of the ultimate or serviceability performance of a braced excavation system. These include the variabilities of the loadings, geotechnical soil properties, and engineering and geometrical properties of the wall. A risk‐based approach to serviceability performance failure is necessary to incorporate systematically the uncertainties associated with the various design parameters. This paper demonstrates the use of an integrated neural network–reliability method to assess the risk of serviceability failure through the calculation of the reliability index. By first performing a series of parametric studies using the finite element method and then approximating the non‐linear limit state surface (the boundary separating the safe and ‘failure’ domains) through a neural network model, the reliability index can be determined with the aid of a spreadsheet. Two illustrative examples are presented to show how the serviceability performance for braced excavation problems can be assessed using the reliability index. Copyright © 2005 John Wiley & Sons, Ltd.     

The importance of oxygen isotope provenance in relation to solute content of bulk meltwaters at Imersuaq Glacier,West Greenland

Stable oxygen isotope analysis and measurement of several dissolved cations and anions of bulk meltwater samples have provided information about the hydrochemical environment of the glacial hydrological system at Imersuaq Glacier, an outlet tongue from the Greenland ice‐sheet, West Greenland. The samples were collected at frequent intervals during the period 20–28 July 2000 in a small (<20 L s^?1) englacial meltwater outlet at the glacier margin. The results document the following findings: (i) a marked diurnal variation of δ¹⁸O is related to the composition of oxygen isotope provenances, mainly near‐marginal local superimposed ice and basal up‐sheared ice further up‐glacier; (ii) a relationship is seen between all base cations (Na⁺, K⁺, Ca²⁺, Mg²⁺), SO₄^2? and δ¹⁸O, indicating that solute acquisition is provided by solid–solution contact with the up‐sheared ice—as the relationship with Cl^? is weak the influence of seasalt‐derived solutes is small in the area; (iii) when the melt rate is high, two diurnal maxima of δ¹⁸O values and solute concentrations are measured, and it is suggested that a snow meltwater component is responsible for the second maximum of δ¹⁸O—a short residence time leads to a delayed decrease in ion concentrations. Copyright © 2003 John Wiley & Sons, Ltd.     

Realisation of a celestial system based on VLBI geodynamics programs

The relative orientations of various VLBI celestial reference frames are evaluated on the basis of coordinate differences of common sources. It is shown that an accuracy better than 0.001 can be achieved. Possible regional deformations in the different catalogues are investigated; they are found to reach a few 0.001 in some restricted zones. The application of these studies to the realisation of a combined celestial reference frame consistent with the BIH Terrestrial System is outlined.     

Lagrangian diffusion equation and its application to oceanic dispersion

The Lagrangian diffusion equation appropriate for the dispersion of current followers (e. g., floats, drogues, drifters) is proposed. The analytical solution to the equation is obtained for a uniform deformation field, characterized by Lagrangian deformations and anisotropic eddy diffusivities both varying with time. Expressions are derived for the patch area and its elongation and rotation. For small values of elapsed time after the initial release the patch area can be accounted for by the exponential of the cumulative value of the horizontal divergence; the relative rate of change of the patch area can be accounted for by the horizontal divergence.     

The wadic project: A comprehensive field evaluation of directional wave instrumentation

The results of a comprehensive field trial of nearly all commercially available directional wave measurement systems at the Edda field in the North Sea during winter 1985-86 are presented. The results summarize the accuracy of the principal engineering wave parameters from each system and the dependence on sea state. Limiting factors on system performance and operational problems are also included in the assessment. Overall experience has been good with systems utilizing widely different measurement principles returning consistent results.     

Phase transitions in the ISM a source of dissipative behaviour

By considering a simple fluid model, we investigate the role of phase transitions in the ISM on the galaxy- scale gas dynamics. Cooling and heating timescales in the ISM are typically shorter than typical galactic rotation timescales, so the individual phases in the ISM can be assumed to be in temperature equilibrium with the radiation field. Using this approximation we can construct an equation of state which depends upon the average density and mass fractions in the individual phases. Previous studies suggest that there is an equilibrium phase fraction as a function of pressure. We incorporate evolution towards this equilibrium state as a relaxation term with a time to obtain equilibrium . We derive a condition in terms of a critical Mach number when one dimensional shocks should be continuous. For small values of the relaxation time we show that the relaxation term acts like a viscosity. We show with one dimensional simulations that increasing causes shocks to become smoother. This work suggests that phase changes can strongly effect the gas dynamics of the ISM across spiral arms and bars.     

The origin of polygonal troughs on the Northern Plains of Mars

Viking photographs have revealed extraordinary systems of crudely polygonal troughs in three different areas of the northern plains of Mars. Trough widths average 200–800 m and average trough spacing is 5–10 km. The widest troughs have flat floors and steep sides which suggest that they are either grabens or tension cracks which have been partially filled. The following three arguments support the garben interpretation: (1) Two clear examples of vertical offsets along trough walls indicate that the troughs formed by downdropping of the floors. (2) Troughs similar in scale and morphology to those of the Martian northern plains form concentric and radial patterns in the Caloris Basin on Mercury. Most likely, they are extensional fractures or grabens resulting from uplift of the basin floor (Strom et al., 1975). The Caloris analogy suggests that the troughs on Mars are similar tectonic features related either to uplift or expansion of the planet. Fourteen rose diagrams of trough azimuths in southeastern Acidalia Planita show that locally they exhibit preferred orientations roughly parallel to the topographic contours, but overall there is no strong regional pattern. (3) The scale of tension crack systems is limited by the depth of fracturing because the extent of stress relief perpendicular to a crack is proportional to the crack depth. Observations of terrestrial tension cracks suggest a lower limit on crack depths of about one-tenth of the average spacing. Thus, if the Martian troughs are tension cracks, they would be expected to have depths of at least 500–1000 m. Mechanical considerations indicate that it is difficult to generate such deep cracks by surficial tension due to thermal cooling and contraction in permafrost, desiccation, or cooling of lava flows. Deep-seated tension of tectonic origin generally results in normal faults and not tension cracks.     

Heat flow near obstacles in the solar convection zone

Disturbances in the heat flow in the solar convection zone are calculated with a turbulent thermal diffusion coefficient based on a mixing length approximation. As a consequence of the radiative boundary condition at the surface and the strong increase of the diffusion coefficient with depth, the convection zone resembles a thermally superconducting shell enclosed between a thin surface layer and an interior core of low thermal conductivity. Thermal disturbances originating in the convection zone do not penetrate into the interior, and penetrate only weakly through the solar surface. A thermally isolating obstacle buried entirely in the convection zone casts a shadow of reduced temperature at the solar surface; the brightening surrounding this shadow is undetectable. The shadow is weak unless the object is located close to the surface (less than 2000 km). Assuming a sunspot to be an area of reduced thermal conductivity which extends a finite depth into the convection zone, the heat flow around this obstacle is calculated. The heat flux blocked below the spot (missing flux) spreads over a very extended area surrounding the spot. The brightening corresponding to this missing flux is undetectable if the reduction of the thermal conductivity extends to a depth greater than 1000 km. It is concluded that no effect other than a decrease of the convective efficiency is needed to explain the temperature change observed at the solar surface in and around a sunspot. The energy balance is calculated between magnetic flux tubes, oriented vertically in the solar surface, (magnetic elements in active regions and the quiet network) and their surroundings. Near the visible surface radiation enters the tube laterally from the surrounding convection zone. The heating effect of this influx is important for small tubes (less than a few arcseconds). Due to this influx tubes less than about 1 in diameter can appear as bright structures irrespective of the amount of heat conveyed along the tube itself. Through the lateral influx, small tubes such as are found in the quiet network act as little leaks in the solar surface through which an excess heat flux escapes from the convection zone.     

Deep drilling at the Siljan Ring impact structure: oxygen-isotope geochemistry of granite

The Siljan Ring is a 362-Ma-old impact structure formed in 1700-Ma-old I-type granites. A 6.8-km-deep borehole provides a vertical profile through granites and isolated horizontal diabase sills. Fluid-inclusion thermometry, and oxygen-isotope compositions of vein quartz, granite, diabase, impact melt, and pseudotachylite, reveal a complex history of fluid activity in the Siljan Ring, much of which can be related to the meteorite impact. In granites from the deep borehole, ¹⁸O values of matrix quartz increase with depth from near 8.0 at the surface to 9.5 at 5760 m depth. In contrast, feldspar ¹⁸O values decrease with depth from near 10 at the surface to 7.1 at 5760 m, forming a pattern opposite to the one defined by quartz isotopic compositions. Values of ¹⁸O for surface granites outside the impact structure are distinct from those in near-surface samples from the deep borehole. In the deep borehole, feldspar coloration varies from brick-red at the surface to white at 5760 m, and the abundances of crack-healing calcite and other secondary minerals decrease over the same interval. Superimposed on the overall decrease in alteration intensity with depth are localized fracture zones at 4662, 5415, and 6044 m depth that contain altered granites, and which provided pathways for deep penetration of surface water. The antithetic variation of quartz and feldspar ¹⁸O values, which can be correlated with mineralogical evidence of alteration, provides evidence for interaction between rocks and impact-heated fluids (100–300° C) in the upper 2 km of the pluton. Penetration of water to depths below 2 km was restricted by a general decrease in impact-fracturing with depth, and by a 60-m-thick diabase sill at 1500 m depth that may have been an aquitard. At depths below 4 km in the pluton, where water/rock ratios were low, oxygen isotopic compositions preserve evidence for limited high-temperature (>500° C) exchange between alkali feldspar and fluids. The high-temperature exchange may have been a post-impact event involving impact-heated fluids, or a post-magmatic event.