Zircon U-Pb and Lu-Hf isotope constraints on Archean crustal evolution in Southeastern Guyana Shield

The southeastern Guyana Shield,northeast Amazonian Craton,in the north of Brazil,is part of a widespread orogenic belt developed during the Transamazonian orogenic cycle(2.26-1.95 Ga)that includes a large Archean continental landmass strongly reworked during the Transamazonian orogeny,named Amapa Block.It consists mainly of a high-grade metamorphic granulitic-migmatitic-gneiss complex,of Meso-to Neoarchean age and Rhyacian granitoids and supracrustal sequences.For the first time,coupled U-Pb and Lu-Hf isotope data were obtained on zircon by LA-ICP-MS from five tectono-stratigraphic units of the Archean basement and one Paleoproterozoic intrusive rock,in order to investigate the main episodes of crustal growth and reworking.Whole-rock Sm-Nd isotope data were compared to the zircon Lu-Hf data.Three main magmatic episodes were defined by U-Pb zircon dating,two in the Mesoarchean(~3.19 Ga and 2.85 Ga)and one in the Neoarchean(~2.69-2.65 Ga).SubchondriticεHf(t)values obtained for almost all investigated units indicate that crustal reworking processes were predominant during the formation of rocks that today make up the Amapa Block.Hf-TDMC model ages,ranging from2.99 Ga to 3.97 Ga,indicate that at least two important periods of mantle extraction and continental crust formation occurred during the Archean in southeastern Guyana Shield,an older one in the Eoarchean(~4.0 Ga)and a younger one in the Mesoarchean(~3.0-3.1 Ga).The latter is recognized as an important period of crustal accretion worldwide.The recognition of an Eoarchean episode to the southeastern most part of the Guyana Shield is unprecedented and was not recorded by whole-rock Sm-Nd data,which were restricted to the Meso-Paleoarchean(2.83 Ga to 3.51 Ga).This finding reveals t hat continental crust generation in the Amazonian Craton began at least 500 Ma earlier than previously suggested by the SmNd systematics.     

松辽盆地徐家围子营城组流纹岩地球化学特征及构造指示意义

松辽盆地徐家围子营城组发育一套以流纹岩为主的中酸性火山岩。岩石薄片观察和主量、微量元素研究发现,后期热液蚀变、区域埋深及低温水合作用对流纹岩的Si、K、Rb等元素含量产生一定影响; 流纹岩明显富集Rb、Th、U、Pb等强不相容元素,Ba、Sr、Ti、Eu、P 负异常,暗示其经历了斜长石、磷灰石和钛铁矿分离结晶作用。流纹岩的(⁸⁷Sr/⁸⁶Sr)_i(0.705265 ~ 0.711895)值变化范围较大,大多数ε_Nd(t)为正值(1.83 ~ 3.38),Pb同位素比值相对集中,(²⁰⁶Pb/²⁰⁴Pb)_i=18.09～18.32,(²⁰⁷Pb/²⁰⁴Pb)_i=15.50 ~ 15.54,(²⁰⁸Pb/²⁰⁴Pb)_i=37.80 ~ 38.10。研究表明,岩石的源区为大比例年轻成分与少量古老地壳的混合部分熔融,其演化过程中经历了不同程度的地壳混染。松辽盆地早白垩世火山岩为板内伸展环境喷发的产物,可能与太平洋板块俯冲导致的中国东部岩石圈减薄、软流圈上涌密切相关。