Carbonate petrography, kerogen distribution, and carbon and oxygen isotope variations in an early Proterozoic transition from limestone to iron-formation deposition, Transvaal Supergroup, South Africa

The transition zone comprises Campbellrand microbialaminated (replacing "cryptalgalaminate") limestone and shale, with minor dolomite, conformably overlain by the Kuruman Iron Formation of which the basal part is characterized by siderite-rich microbanded iron-formation with minor magnetite and some hematite-containing units. The iron-formation contains subordinate intraclastic and microbialaminated siderite mesobands and was deposited in deeper water than the limestones. The sequence is virtually unaltered with diagenetic mineral assemblages reflecting a temperature interval of about 110 degrees to 170 degrees C and pressures of 2 kbars. Carbonate minerals in the different rock types are represented by primary micritic precipitates (now recrystallized to microsparite), early precompactional sparry cements and concretions, deep burial limpid euhedral sparites, and spar cements precipitated from metamorphic fluids in close contact with diabase sills. Paragenetic pathways of the carbonate minerals are broadly similar in all lithofacies with kerogen intimately associated with them. Kerogen occurs as pigmentation in carbonate crystals, as reworked organic detritus in clastic-textured carbonate units, and as segregations of kerogen pigment around late diagenetic carbonate crystals. Locally kerogen may also be replaced by carbonate spar. Carbon isotope compositions of the carbonate minerals and kerogen are dependent on their mode of occurrence and on the composition of the dominant carbonate species in a specific lithofacies. Integration of sedimentary, petrographic, geochemical, and isotopic results makes it possible to distinguish between depositional, early diagenetic, deep burial, and metamorphic effects on the isotopic compositions of the carbonate minerals and the kerogen in the sequence. Major conclusions are that deep burial thermal decarboxylation led to 13C depletion in euhedral ferroan sparites and 13C enrichment in kerogen (organic carbon). Metamorphic sparites are most depleted in 13C. Carbonates in oxide-rich iron-formations are more depleted in 13C than those in siderite-rich iron-formation whereas the kerogens in oxide banded iron-formations (BIF) are more enriched. This implies that the siderite-rich iron-formations were not derived from oxide-rich iron-formation through reduction of ferric iron by organic matter. Organic matter oxidation by ferric iron did, however, decrease the abundance of kerogen in oxide-rich iron-formation and led to the formation of isotopically very light sparry carbonates. Siderite and calcmicrosparite both represent recrystallized primary micritic precipitates but differ in their 13C composition, with the siderites depleted in 13C by 4.6 per mil on average relative to calcmicrosparite. This means that the siderites were precipitated from water with dissolved inorganic carbon depleted in 13C by about 9 per mil relative to that from which the limestones precipitated. This implies an ocean system stratified with regard to total carbonate, with the deeper water, from which siderite-rich iron-formation formed, depleted in 13C. Iron-formations were deposited in areas of very low organic matter supply. Depletion of 13C may, therefore, derive not from degradation of organic matter but from hydrothermal activity, a conclusion which is supported by 18O composition of the carbonate minerals and trace element and rare earth element (REE) compositions of the iron-formations.     

东秦岭石窑沟斑岩钼矿床地质特征及辉钼矿Re-Os年龄

在东秦岭钼成矿带最近探明的石窑沟大型钼矿床位于近东西向马超营断裂带与北东向石窑沟-焦园断裂带的交汇部位,获得钼金属储量10余万吨,平均品位0.068%。钼矿化呈细脉-网脉状分布于花岗斑岩体及其围岩熊耳群火山岩中,与矿化有关的围岩蚀变有钾长石化、硅化、绢云母化、黄铁矿化等,具有斑岩型钼矿床的一些基本特点。在矿床中选取5件不同矿化类型的辉钼矿样品,采用ICP-MS法进行Re-Os同位素定年,获得模式年龄131.3±2.4～134.3±2.6Ma,等时线年龄135.2±1.8Ma(MSWD=0.18),形成于早白垩世,与豫西熊耳山地区雷门沟、鱼池岭等钼矿床形成时代相近。据辉钼矿Re含量(8.242×10-6～30.24×10-6)推测,矿床成矿物质主要来自于下地壳。矿床为东秦岭-大别山地区中生代第三期钼成矿作用产物,形成于早白垩世中国东部岩石圈伸展环境。     

Terminal Proterozoic mid-shelf benthic microbial mats in the Centralian Superbasin and their environmental significance.

A combined sedimentological and biogeochemical study has been conducted on several Terminal Proterozoic mid-shelf microbial mat facies from the Centralian Super-basin. Isotopic and organic geochemical analysis of the bitumen and kerogen indicated that two sources of organic matter from 'planktonic' and 'benthic microbial-mat' populations contributed to the sediment. The 'planktonic' source provided a suite of n-alkanes with C20, whereas, the 'benthic' source contributed an overlay of n-alkanes >C20 with a strong even preference, together with mid-chain methyl alkanes. Kerogen and biomarkers derived from the microbial mat were found to be depleted in 13C relative to planktonic material. Pyrite in the microbial mats was also found to be depleted in 34S compared to surrounding facies. The combination of these observations suggested that the mats may have been at least partly composed of sulfide oxidising bacteria. These organisms have specific environmental tolerances that set limits on palaeo-environment. Their requirement for oxygen indicates that the water column above the mid-shelf could not have been anoxic. Accordingly, from the results and age determinations reported here, it would appear that mid-shelf environments of the Centralian Superbasin of Australia were seeing significant levels of oxygen through the Ediacarian.     

Transport and retention of a conservative tracer in an isolated creek–marsh system

A study of tracer transport and retention in a small tidal creek and marsh system located in the southeastern US was conducted using a three-dimensional hydrodynamic model and data from a dye tracer release. The model simulated tidally driven flow, including inundation and drying out of the marshes and the dispersal of the dye tracer. Flow measurements in the tidal creek showed that the simulations appeared to generally duplicate the tidally driven flow into and out of the tidal creeks and marshes. The dye tracer experiment was conducted to test the hydrodynamic model's ability to simulate dispersal of a point release of pollutants into the creek during an incoming tide. The simulations reproduced much of the experimental measurements, but bathymetric errors and lack of resolution of the smallest arms of the tidal creeks affected the ability to faithfully reproduce the initial peak in measured dye tracer concentrations at a sampling location far from the boundary. The lack of the smallest tidal creeks led to some trapping of water and dye in the marshes. Two independent estimates of flushing time yielded values between 1.6 and 2.4 days. An uncertainty analysis indicates that model simulations are sensitive to variations in parameters such as water depth and marsh grass density. On the other hand, omission of the smallest tidal creeks in simulations may be partially offset by decreasing marsh grass density. Further improvements must rely on more accurate and detailed bathymetric data that resolves the smaller arms of the tidal creeks and includes quantitative information about the density and distribution of marsh grass.     

Correction: Geostatistical Rock Physics Inversion for Predicting the Spatial Distribution of Porosity and Saturation in the Critical Zone

Mathematical Geosciences -     

Drought triggers and declarations: science and policy considerations for drought risk management

This paper explores the value of triggers and declarations in the management of drought, bringing together two disciplinary perspectives, those of the public policy scholar and the climate scientist. These two perspectives highlight the complexity of the development and use of triggers in drought risk management by drawing on the experience of the United States, which has the most sophisticated system of drought triggers in the world, and that of Australia that has the most developed and longest standing national drought policy based on principles of risk management. The paper explores the advantages and disadvantages of triggers in managing drought, concluding that triggers are useful risk management tools at the individual level but become problematic and can lead to perverse outcomes when linked to some forms of government support programs.     

The Cold War and geography’s quantitative revolution: Some messy reflections on Barnes’ geographical underworld

A response to a recent paper by Barnes, arguing that the origins of geography’s quantitative revolution were not as monofocused as he suggests.     

Early and middle Holocene in the Aegean Sea: interplay between high and low latitude climate variability

Changes in the orbital parameters, solar output, and ocean circulation are widely considered as main drivers of the Holocene climate. Yet, the interaction between these forcings and the role that they play to produce the pattern of changes observed in different domains of the climate system remain debated. Here, we present new early to middle Holocene season-specific sea surface temperature (SST) and δ¹⁸O_seawater results, based on organic-walled dinoflagellate cyst and planktonic foraminiferal data from two sediment cores located in the central (SL21) and south-eastern (LC21) Aegean Sea (eastern Mediterranean). Today, this region is affected by high to mid latitude climate in winter and tropical/subtropical climate in summer. The reconstructed δ¹⁸O_seawater from LC21 displays a marked (～1.3%) negative shift between 10.7 and 9.7 ka BP, which represents the regional expression of the orbitally driven African monsoon intensification and attendant freshwater flooding into the eastern Mediterranean. A virtually contemporaneous shift, of the same sign and magnitude, is apparent in the δ¹⁸O_speleothem record from Soreq Cave (Northern Israel), an important part of which may therefore reflect a change in the isotopic composition of the moisture source region (Aegean and Levantine Seas). Our SST reconstructions show that Aegean winter SSTs decreased in concert with intensifications of the Siberian High, as reflected in the GISP2 nss [K⁺] record. Specifically, three distinct sea surface cooling events at 10.5, 9.5–9.03 and 8.8–7.8 ka BP in the central Aegean Sea match increases in GISP2 nss [K⁺]. These events also coincide with dry interludes in Indian monsoon, hinting at large (hemispheric) scale teleconnections during the early Holocene on centennial timescales. A prominent short-lived (～150 years) cooling event in core SL21 – centred on 8.2 ka BP – is coeval to the ‘8.2 ka BP event’ in the Greenland δ¹⁸O_ice, which is commonly linked to a melt-water related perturbation of the Atlantic Meridional Overturning Circulation and associated ocean heat transport. By deciphering the phasing between a recently published record of reduced overflow from the Nordic Seas into the northern North Atlantic, the Greenland δ¹⁸O_ice ‘8.2 ka BP event’ anomaly, and the short-lived cooling in SL21, we demonstrate severe far-field impacts of this North Atlantic event in the Aegean Sea. The Aegean is isolated from the North Atlantic oceanic circulation, so that signal transmission must have been of an atmospheric nature.     

The influence of natural variation in discharge on juvenile brown trout population dynamics in a nursery tributary of the Motueka River,New Zealand

The effects of natural flow variation on juvenile brown trout population dynamics were investigated by biannual sampling over 5.5 years in the Rainy River, a tributary of the Motueka River. A large flood in late March (50-year return period) substantially reduced the density (by 66%) and biomass (by 73%) of 0+ trout over autumn–spring, but the cohort responded with compensatory survival to achieve similar density and biomass by spring as in other years. A low-flow event in February–April (return period >8.4 years), when 7-day low flows fell to 56% of the 7-day mean annual low flow (MALF) and were less than the MALF for 46 days, had no adverse affect on the population. We found no evidence for density-dependent growth. However, there was strong evidence for a two-phase self-thinning response in density, with no self-thinning occurring over summer (i.e. the 0+ population remained below carrying capacity) until a threshold mass of 22.08 g (length=123.7 mm) was attained in autumn after which severe self-thinning took place over autumn to spring. The results indicate that over spring–autumn the population is insensitive to flow reduction and that over autumn–spring the effects of high (and probably low) flow events on local abundance and biomass are offset by compensatory (density-dependent) survival. However, effects on the contribution of migrants to the downstream population remain unknown. The study identified ecological redundancy, which could be exploited for flow allocation. Significantly, it has shown that minimum flows equivalent to the MALF (often advocated by New Zealand conservation and fisheries management organisations) are not always necessary for sustaining juvenile trout populations.