西秦岭勉略带陆内构造变形研究

秦岭造山带勉略缝合带是古特提斯洋盆向北俯冲形成的华北与华南最后拼接带。这个主缝合带俯冲-碰撞过程中以由北向南的一系列韧性逆冲推覆构造为特征,形成由前泥盆系、泥盆-石炭系和蛇绿混杂岩等不同构造岩片叠置的复杂构造带,碰撞时代从245Ma一直延续到230Ma左右。最近,作者对勉略缝合带内发育的韧性和脆性左行走滑剪切变形进行了研究,结果表明这些顺造山带的左行韧性走滑剪切变形带的变形时代为223±2Ma,与碰撞后花岗岩所确定的碰撞后构造环境的起始时间(225Ma)一致,显示这些韧性走滑剪切变形带是勉略带陆内变形初期变形产物。亦即华北、扬子大陆碰撞之后很快就转入陆内变形阶段,并且是以顺造山带的侧向走滑位移为主要变形方式。勉略带内顺造山带的脆性左行走滑断层的发育,表明这种顺造山带的侧向位移过程从深部到地壳浅层是一致的。因此,大陆碰撞在直接碰撞之后很快转变为顺造山带的侧向走滑位移为主的陆内变形,这种位移可能表现为两个大陆碰撞后的相对走滑,或是碰撞带中强烈变形部分顺造山带的侧向挤出,从而消减了正向碰撞所造成的地壳缩短和增厚。     

内蒙古鸡冠山斑岩钼矿床成矿时代和成矿流体研究

内蒙古鸡冠山钼矿床是西拉沐伦钼成矿带上的典型斑岩矿床。矿床产于火山侵入杂岩中,矿化类型以细脉浸染状矿化为主。对矿床5件辉钼矿样品进行了铼-锇同位素分析,获得了151.1±1.3Ma的等时线年龄,表明成矿作用发生在晚侏罗世。成矿作用可划分为三个阶段:早阶段为石英-黄铁矿阶段,发育乳白色石英和粗粒浸染状黄铁矿;中阶段包括早期石英-多金属硫化物亚阶段和晚期石英-萤石-金属硫化物亚阶段;晚阶段为石英-碳酸盐细脉,穿切早、中阶段脉体和矿物组合。鸡冠山钼矿床流体包裹体岩相学研究表明,与成矿有关的包裹体主要有六种类型:富液相、富气相、含子晶多相、含CO2三相、纯CO2及纯液相包裹体。其中,早阶段以富气和富CO2包裹体为主,中阶段多种包裹体共存,晚阶段则主要为富液包裹体。冷热台显微测温和激光拉曼显微探针(LRM)成分分析结果表明,早阶段石英中原生包裹体的均一温度480℃,盐度最高66.75%NaCleqv,包裹体气相成分富含水和CO2,液相成分则以水为主,子晶矿物有石盐、黄铜矿以及指示氧化条件的赤铁矿等,同时也说明成矿流体是富含成矿金属元素的。中阶段早期石英中的流体包裹体均一温度为320～480℃,晚期石英和萤石中的流体包裹体的均一温度为180～320℃。中阶段流体盐度介于4.65%～56.76%NaCleqv。中阶段包裹体含石盐、方解石、黄铜矿、赤铁矿等子矿物,富气相、富液相与含子晶多相包裹体共存,且具有相近的均一温度,而盐度相差悬殊,指示流体发生了沸腾。晚阶段流体的温度降低至100～180℃,盐度则低于10.86%NaCleqv,流体包裹体成分主要为水。鸡冠山钼矿成矿流体演化从早至晚为:从早阶段高温、高盐度、高氧逸度、富CO2、富成矿物质以岩浆热液为主成矿流体,演化至晚期低温、低盐度、无子晶、贫CO2、以大气降水为主的流体。沸腾作用是鸡冠山钼矿形成的重要机制。     

东秦岭石窑沟斑岩钼矿床地质特征及辉钼矿Re-Os年龄

在东秦岭钼成矿带最近探明的石窑沟大型钼矿床位于近东西向马超营断裂带与北东向石窑沟-焦园断裂带的交汇部位,获得钼金属储量10余万吨,平均品位0.068%。钼矿化呈细脉-网脉状分布于花岗斑岩体及其围岩熊耳群火山岩中,与矿化有关的围岩蚀变有钾长石化、硅化、绢云母化、黄铁矿化等,具有斑岩型钼矿床的一些基本特点。在矿床中选取5件不同矿化类型的辉钼矿样品,采用ICP-MS法进行Re-Os同位素定年,获得模式年龄131.3±2.4～134.3±2.6Ma,等时线年龄135.2±1.8Ma(MSWD=0.18),形成于早白垩世,与豫西熊耳山地区雷门沟、鱼池岭等钼矿床形成时代相近。据辉钼矿Re含量(8.242×10-6～30.24×10-6)推测,矿床成矿物质主要来自于下地壳。矿床为东秦岭-大别山地区中生代第三期钼成矿作用产物,形成于早白垩世中国东部岩石圈伸展环境。     

Biotite dissolution and Cr(VI) reduction at elevated pH and ionic strength

The effects of elevated pH, ionic strength, and temperature on sediments in the vadose zone are of primary importance in modeling contaminant transport and understanding the environmental impact of tank leakage at nuclear waste storage facilities like those of the Hanford site. This study was designed to investigate biotite dissolution under simulated high level waste (HLW) conditions and its impact on Cr(VI) reduction and immobilization. Biotite dissolution increased with NaOH concentrations in the range of 0.1 to 2 mol L^-1. There was a corresponding release of K, Fe, Si, and Al to solution, with Si and Al showing a complex pattern due to the formation of secondary zeolite minerals. Dissolved Fe concentrations were an order of magnitude lower than the other elements, possibly due to the formation of green rust and Fe(OH)₂. The reduction of Cr(VI) to Cr(III) also increased with increased NaOH concentration. A homogeneous reduction of chromate by Fe(II)_aq released through biotite dissolution was probably the primary pathway responsible for this reaction. Greater ionic strengths increased biotite dissolution and consequently increased Fe(II)_aq release and Cr(VI) removal. The results indicated that HLW would cause phyllosilicate dissolution and the formation of secondary precipitates that would have a major impact on radionuclide and contaminant transport in the vadose zone at the Hanford site.     

Petrologic constraints on rift-zone processes

The Puu Oo eruption in the middle of Kilauea volcano's east rift zone provides an excellent opportunity to utilize petrologic constraints to interpret rift-zone processes. Emplacement of a dike began 24 hours before the start of the eruption on 3 January 1983. Seismic and geodetic evidence indicates that the dike collided with a magma body in the rift zone. Most of the lava produced during the initial episode of the Puu Oo eruption is of hybrid composition, with petrographic and geochemical evidence of mixing magmas of highly evllved and more mafic compositions. Some olivine and plagioclase grains in the hybrid lavas show reverse zoning. Whole-rock compositional variations are linear even for normally compatible elements like Ni and Cr. Leastsquares mixing calculations yield good residuals for major and trace element analyses for magma mixing. Crystal fractionation calculations yield unsatisfactory residuals. The highly evolved magma is similar in composition to the lava from the 1977 eruption and, at one point, vents for these two eruptions are only 200 m apart. Possibly both the 1977 lava and the highly evolved component of the episode 1 Puu Oo lava were derived from a common body of rift-zone-stored magma. The more mafic mixing component may be represented by the most mafic lava from the January 1983 eruption; it shows no evidence of magma mixing. The dike that was intruded just prior to the start of the Puu Oo eruption may have acted as a hydraulic plunger causing mixing of the two rift-zone-stored magmas.     

Influence of pH on mineral speciation in a bioreactor simulating acid mine drainage

Mineral precipitates formed under conditions representative of acid mine drainage were prepared by oxidizing 0.1 M FeS0₄ · 7H₂0 solutions at 24°C and pH 2.3, 2.6, 3.0, 3.3 and 3.6 using a bioreactor and a strain ofThiobacillus ferrooxidans. The oxidation of dissolved Fe²⁺ was monitored colorimetrically and was completed within 90 to 120 h at all pHs. Schwertmannite, Fe₈O₈(OH)₆SO₄, was a major component of the precipitates and was the only phase formed at pH 3.0. Jarosite, (H,Na,K)Fe₃(OH)₆(SO₄)₂, increased in abundance with decreasing pH whereas goethite, α-FeOOH, appeared at pH 3.3 and 3.6. A similar relationship between pH and mineralogy has been reported in natural specimens of mine drainage ochres.     

松辽盆地徐家围子营城组流纹岩地球化学特征及构造指示意义

松辽盆地徐家围子营城组发育一套以流纹岩为主的中酸性火山岩。岩石薄片观察和主量、微量元素研究发现,后期热液蚀变、区域埋深及低温水合作用对流纹岩的Si、K、Rb等元素含量产生一定影响; 流纹岩明显富集Rb、Th、U、Pb等强不相容元素,Ba、Sr、Ti、Eu、P 负异常,暗示其经历了斜长石、磷灰石和钛铁矿分离结晶作用。流纹岩的(⁸⁷Sr/⁸⁶Sr)_i(0.705265 ~ 0.711895)值变化范围较大,大多数ε_Nd(t)为正值(1.83 ~ 3.38),Pb同位素比值相对集中,(²⁰⁶Pb/²⁰⁴Pb)_i=18.09～18.32,(²⁰⁷Pb/²⁰⁴Pb)_i=15.50 ~ 15.54,(²⁰⁸Pb/²⁰⁴Pb)_i=37.80 ~ 38.10。研究表明,岩石的源区为大比例年轻成分与少量古老地壳的混合部分熔融,其演化过程中经历了不同程度的地壳混染。松辽盆地早白垩世火山岩为板内伸展环境喷发的产物,可能与太平洋板块俯冲导致的中国东部岩石圈减薄、软流圈上涌密切相关。     

Self-generated aperiodic behaviour in a simple climate model

Climatic variability arising from the coupling between ocean temperature and sea-ice extent is studied in a spatially distributed system. A spatial degree of freedom is crudely introduced by the coupling, through energy transfer, of two box models each of which describes a different space region. The evolution equations are cast into a normal form and some qualitative features of this general class of models are predicted. It is shown, both analytically and numerically, that internally generated complexity in the form of aperiodic behaviour can be a natural consequence of spatially distributed systems.