Modelling chemistry in the nocturnal boundary layer above tropical rainforest and a generalised effective nocturnal ozone deposition velocity for sub-ppbv NOx conditions

Measurements of atmospheric composition have been made over a remote rainforest landscape. A box model has previously been demonstrated to model the observed daytime chemistry well. However the box model is unable to explain the nocturnal measurements of relatively high [NO] and [O₃], but relatively low observed [NO₂]. It is shown that a one-dimensional (1-D) column model with simple O₃-NO_x chemistry and a simple representation of vertical transport is able to explain the observed nocturnal concentrations and predict the likely vertical profiles of these species in the nocturnal boundary layer (NBL). Concentrations of tracers carried over from the end of the night can affect the atmospheric chemistry of the following day. To ascertain the anomaly introduced by using the box model to represent the NBL, vertically-averaged NBL concentrations at the end of the night are compared between the 1-D model and the box model. It is found that, under low to medium [NO_x] conditions (NO_x?<?1 ppbv), a simple parametrisation can be used to modify the box model deposition velocity of ozone, in order to achieve good agreement between the box and 1-D models for these end-of-night concentrations of NO_x and O₃. This parametrisation would could also be used in global climate-chemistry models with limited vertical resolution near the surface. Box-model results for the following day differ substantially if this effective nocturnal deposition velocity for ozone is implemented; for instance, there is a 9% increase in the following days peak ozone concentration. However under medium to high [NO_x] conditions (NO_x > 1 ppbv), the effect on the chemistry due to the vertical distribution of the species means no box model can adequately represent chemistry in the NBL without modifying reaction rate coefficients.     

Abrupt CO2 experiments as tools for predicting and understanding CMIP5 representative concentration pathway projections

A fast simple climate modelling approach is developed for predicting and helping to understand general circulation model (GCM) simulations. We show that the simple model reproduces the GCM results accurately, for global mean surface air temperature change and global-mean heat uptake projections from 9 GCMs in the fifth coupled model inter-comparison project (CMIP5). This implies that understanding gained from idealised CO₂ step experiments is applicable to policy-relevant scenario projections. Our approach is conceptually simple. It works by using the climate response to a CO₂ step change taken directly from a GCM experiment. With radiative forcing from non-CO₂ constituents obtained by adapting the Forster and Taylor method, we use our method to estimate results for CMIP5 representative concentration pathway (RCP) experiments for cases not run by the GCMs. We estimate differences between pairs of RCPs rather than RCP anomalies relative to the pre-industrial state. This gives better results because it makes greater use of available GCM projections. The GCMs exhibit differences in radiative forcing, which we incorporate in the simple model. We analyse the thus-completed ensemble of RCP projections. The ensemble mean changes between 1986–2005 and 2080–2099 for global temperature (heat uptake) are, for RCP8.5: 3.8 K (2.3 × 10²⁴ J); for RCP6.0: 2.3 K (1.6 × 10²⁴ J); for RCP4.5: 2.0 K (1.6 × 10²⁴ J); for RCP2.6: 1.1 K (1.3 × 10²⁴ J). The relative spread (standard deviation/ensemble mean) for these scenarios is around 0.2 and 0.15 for temperature and heat uptake respectively. We quantify the relative effect of mitigation action, through reduced emissions, via the time-dependent ratios (change in RCPx)/(change in RCP8.5), using changes with respect to pre-industrial conditions. We find that the effects of mitigation on global-mean temperature change and heat uptake are very similar across these different GCMs.     

The effects of aggressive mitigation on steric sea level rise and sea ice changes

With an increasing political focus on limiting global warming to less than 2 °C above pre-industrial levels it is vital to understand the consequences of these targets on key parts of the climate system. Here, we focus on changes in sea level and sea ice, comparing twenty-first century projections with increased greenhouse gas concentrations (using the mid-range IPCC A1B emissions scenario) with those under a mitigation scenario with large reductions in emissions (the E1 scenario). At the end of the twenty-first century, the global mean steric sea level rise is reduced by about a third in the mitigation scenario compared with the A1B scenario. Changes in surface air temperature are found to be poorly correlated with steric sea level changes. While the projected decreases in sea ice extent during the first half of the twenty-first century are independent of the season or scenario, especially in the Arctic, the seasonal cycle of sea ice extent is amplified. By the end of the century the Arctic becomes sea ice free in September in the A1B scenario in most models. In the mitigation scenario the ice does not disappear in the majority of models, but is reduced by 42 % of the present September extent. Results for Antarctic sea ice changes reveal large initial biases in the models and a significant correlation between projected changes and the initial extent. This latter result highlights the necessity for further refinements in Antarctic sea ice modelling for more reliable projections of future sea ice.     

Review of tufa deposition and palaeohydrological conditions in the White Peak,Derbyshire, UK: implications for Quaternary landscape evolution

This review considers the geological and geomorphological context of tufa barrages that occupy buried valley settings in the Wye catchment, Derbyshire. It describes the potential relationship of the tufa with locations of hypothesised river captures and inception horizon-guided groundwater flow paths. Tufa barrage development is associated with steps in the bedrock, which may be related to knick-point recession during river capture. Broad estimates of valley incision have been calculated from previously dated deposits. These support current interpretations of particularly significant effective base-level lowering during the Anglian and Devensian stages of the Quaternary and have the potential to add to the knowledge of regional uplift histories.     

Chronology of early Archaean granite-greenstone evolution in the Barberton Mountain Land, South Africa, based on precise dating by single zircon evaporation

We report precise 207Pb/206Pb single zircon evaporation ages for low-grade felsic metavolcanic rocks within the Onverwacht and Fig Tree Groups of the Barberton Greenstone Belt (BGB), South Africa, and from granitoid plutons bordering the belt. Dacitic tuffs of the Hooggenoeg Formation in the upper part of the Onverwacht Group yield ages between 3445 +/- 3 and 3416 +/- 5 Ma and contain older crustal components represented by a 3504 +/- 4 Ma old zircon xenocryst. Fig Tree dacitic tuffs and agglomerates have euhedral zircons between 3259 +/- 5 and 3225 +/- 3 Ma in age which we interpret to reflect the time of crystallization. A surprisingly complex xenocryst population in one sample documents ages from 3323 +/- 4 to 3522 +/- 4 Ma. We suspect that these xenocrysts were inherited, during the passage of the felsic melts to the surface, from various sources such as greenstones and granitoid rocks now exposed in the form of tonalite-trondhjemite plutons along the southern and western margins of the BGB, and units predating any of the exposed greenstone or intrusive rocks. Several of the granitoids along the southern margin of the belt have zircon populations with ages between 3490 and 3440 Ma. coeval with or slightly older than Onverwacht felsic volcanism, while the Kaap Valley pluton along the northwestern margin of the belt is coeval with Fig Tree dacitic volcanism. These results emphasize the comagmatic relationships between greenstone felsic volcanic units and the surrounding plutonic suites. Some of the volcanic plutonic units contain zircon xenocrysts older than any exposed rocks. These indicate the existence of still older units, possibly stratigraphically lower and older portions of the greenstone sequence itself, older granitoid intrusive rocks, or bodies of older, unrelated crustal material. Our data show that the Onverwacht and Fig Tree felsic units have distinctly different ages and therefore do not represent a single, tectonically repeated unit as proposed by others. Unlike the late Archaean Abitibi greenstone belt in Canada, which formed over about 30 Ma. exposed rocks in the BGB formed over a period of at least 220 Ma. The complex zircon populations encountered in this study imply that conventional multigrain zircon dating may not accurately identify the time of felsic volcanic activity in ancient greenstones. A surprising similarity in rock types, tectonic evolution, and ages of the BGB in the Kaapvaal craton of southern Africa and greenstones in the Pilbara Block of Western Australia suggests that these two terrains may have been part of a larger crustal unit in early Archaean times.     

Otolith Microchemistry Reveals Substantial Use of Freshwater by Southern Flounder in the Northern Gulf of Mexico

Southern flounder Paralichthys lethostigma is a recreationally and commercially important species along the western Atlantic and northern Gulf of Mexico coasts that can exhibit complex early-life habitat-use patterns. Herein, we used an otolith microchemical approach to test the conventional wisdom that juvenile southern flounder spend most of their early life in low-salinity areas of estuaries, focusing on the largely unstudied population in the Mobile-Tensaw Delta, AL. Analysis of strontium/calcium concentrations in otolith cores of age 0 juveniles demonstrated that 68% of these individuals hatched in high-salinity waters before moving into freshwater habitats, with the remaining individuals being spawned in or near freshwater habitat. Further, otolith edge Sr/Ca concentrations revealed that even juveniles used freshwater habitats, particularly during freshwater/oligohaline conditions in our study system. Otolith edge Sr/Ca ratios for fish collected during high-salinity periods differed significantly among collection regions, suggesting seasonal differences in patterns of habitat use between individuals collected upstream (i.e., freshwater habitats) vs. downstream (i.e., euryhaline habitats). These data support the hypothesis that early-life stages of a substantial portion of a coastal southern flounder population use freshwater habitat.