Determination of some carcinogenic PAHs with toxic equivalency factor along roadside soil within a fast developing northern city of India

The objective of the present study was to ascertain contamination levels, distribution behaviour and PAHs exposure during summer, winter and autumn during 2011–2012 in one of the developing cities of northern India. Average PAHs concentration was found to be 18.17, 4.04 and 16.38 μg g ^?1, whereas, concentration of 16 individual PAHs was found to vary between 0.02 and 200.23, 0.008 and 28.4 μg g ^?1, and 0.01 and 252.55 μg g ^?1 during summer, winter and autumn seasons, respectively. The average concentration of low and high carcinogenic PAHs during summer, winter and autumn was found to be 5.1 and 31.29, 2.1 and 6.4, 4.74 and 35.08 μg g ^?1 at most intercepts. The average ratio of low to high carcinogenic PAHs was found to be 1:6, 1:3, 1:7.6 during summer, winter and autumn, respectively. Five ringed PAHs were found in higher concentration in all seasons. Dib(ah)A and B(a)P were the two individual PAHs found in highest concentration during summer, winter and autumn seasons. Two tailed T-test was applied for authenticity of the results. Toxic equivalency factor of B(a)P and Dib(ah)A was maximum as compared to other PAHs. The study could be of great significance for the planners while considering environmental remedial measures.     

TRANSFORMATION OF DIPOLE TO SCHLUMBERGER SOUNDING CURVES BY MEANS OF DIGITAL LINEAR FILTERS*

Linear relationship between dipole and Schlumberger sounding resistivities leads to the use of digital filters to transform the former to the latter. This transformation is of importance from the viewpoint that Schlumberger interpretational techniques and know-how could then be applied to the pseudo-Schlumberger field curve. Filters for this transformation are presented for the radial, perpendicular, and parallel (30°) dipole method. The characteristics of these filters are similar to the ones for transforming dipole data to the kernel and are favourable in that they do not amplify noise. A sampling interval of (In 10) /6 has been used in determining the filter yielding good accuracy. Like previous filters the present one is handy and fast in operation.     

THE CORRELATION REFRACTION METHOD AS APPLIED TO WEATHERED ZONE STUDIES IN A GRANITE TERRAIN*

The combined observation of first and later arrivals in shallow seismic refraction surveys, particularly on hard rock terrains, is discussed. Details of experimental weathered-zone investigations by the correlation refraction method in a granite terrain (i.e. field procedure, seismograms obtained, plotting of the data, and identification of the waves are presented). Complete travel time data and interpreted subsurface sections of a few test refraction surveys are included. In one instance the interpreted results of normal and converted refracted wave data have been tested by drilling at three points along a 220 m long profile.     

Evolution of Quaternary alluvial fans and terraces in the intramontane Pinjaur Dun, Sub-Himalaya, NW India: interaction between tectonics and climate change

Quaternary alluvial fans in the tectonically active Pinjaur Dun, an intramontane valley in the Sub‐Himalaya, were deposited in front of the Nalagarh Thrust and were influenced both by tectonics and glacial climate fluctuations. The surface morphology indicates that an earlier set of first‐order fans (Qf1) became entrenched and onlapped by a series of second‐order fans (Qf2). The younger fan segments were then cut by a pair of terraces (T1 and T2). Quartz optically stimulated luminescence dating establishes that the Qf1 aggradational phase was initiated before 96·5 ± 25·3 ka and terminated after 83·7 ± 16·3 ka. This was followed by a period of incision, before Qf2 fan deposition started at 72·4 ± 13·4 ka and continued until 24·5 ± 4·9 ka. Sediment was deposited on the T1 (upper) and T2 (lower) terraces at 16·3 ± 2·1 and 4·5 ka, respectively, recording a return to overall degradation punctuated by minor deposition on terraces. The period of incision separating the younger and older fan deposits coincided with enhanced SW monsoon precipitation. The subsequent development of the Qf2 fans and their progradation until 20 ka suggest erosional unloading of the thrust hangingwall during a tectonically quiescent phase. Toe cutting, deposition of axial river and lacustrine facies, and retreat of Qf2 around 45 ka, indicate fanward shift of the axial river due to tilting of the valley towards the NE in response to reactivation of the Nalagarh Thrust. The cessation of Qf2 deposition around 20 ka and the onset of through‐fan entrenchment suggest reduced sediment supply but relatively high stream power during the last glacial maxima (LGM). The prolonged stream incision since the cessation of Qf2 deposition, with only minor depositional phases at 16·3 ± 2·1 and 4·5 ka, resulted from high water discharge and low sediment input during intensification of the SW monsoon and vegetation changes in the hinterland.     

Field evidences showing rapid frontal degeneration of the Kangriz glacier,western Himalayas,Jammu & Kashmir

Life cycle of glaciers in the Himalayan region has notably changed due to the climatic variability since last few decades. Glaciers across the world and specially the Himalayan glaciers have shown large scale degeneration in the last few decades. Himalayan glaciers serve as an important fresh water resource for the downstream communities, who are dependent on this water for domestic and other purposes. Therefore, glacier shrinkage and the associated hydrological changes pose a significant problem for regional-scale water budgets and resource management. These issues necessitate the regular and rigorous monitoring of the wastage pattern of the Himalayan glaciers in field and using satellite remote sensing data. In this work, we report rapid and enhanced degeneration of the frontal part of the Kangriz glacier, Jammu and Kashmir(J K), in terms of surface melting, debris cover, snout characteristics and meltwater discharge. Ablation data acquired during 2016-2017 shows the average lowering of the frontal part of the glacier to be ~148 ± 34 cm, one-third of which was found to have occurred within a 13 day time period in September, 2017. Also, the quantum of ice melt was found to be inversely influenced(r =-0.84) by the debris thickness. 15 day meltwater discharge measurement revealed its strong relationship with snout disintegration pattern, evidenced twice during the said time period. Volume of water discharged from the glacier was estimated to be 7.91×10~6 m~3 for the measurement duration. Also, mean daily discharge estimated for the 15 days interval showed good positive correction(r = 0.78) with temperature indicating the direct dependency of the former on land surface temperature conditions of the region. Besides the lowering and discharge observations, the frequent ice-block break-offs at the glacier snout further enhance its overall drastic degeneration. The study suggests that, being the largest glacier in the Suru basin, the Kangriz glacier needs to be continuously monitored in order to understand its glacio-hydrological conditions.     

Low protein variability and genetic similarity between populations of the polar bear (Ursus maritimus)

Blood samples from a total of 460 polar bears ( Ursus maritimus ) from various Arctic regions, but excluding the USSR, were collected during the period 1967-1981 to study electrophoretic variation in different proteins. Two hundred and one samples from Alaska, 48 from the Canadian Arctic, 89 from Svalbard, and 21 from Northeast Greenland were collected during the period 1967-1973 and were analysed by vertical polyacrylamide gel electrophoresis to study transferrin and hemoglobin polymorphism. Thirty-one samples collected in 1974 were analysed by starch gel electrophoresis for 14 enzyme systems in serum and red blood cells. Seventy samples collected from Alaska, the Barents Sea, and Canada in 1980-81 were studied by starch gel electrophoresis, and further analysed for protein variation by thin-layer isoelectric focusing, horizontal polyacrylamide gel electrophoresis, and two-dimensional electrophoresis. In all, about 75 loci were analysed for variation. The degree of protein and enzyme variation in the polar bear was observed to be relatively low. Starch gel electrophoresis revealed variation of an unidentified serum protein. The distribution of this protein indicates a closer connection between bears in Alaska and Canada compared to those in Greenland and Svalbard, but the differences were not significant. As in many large mammals, the information from protein variation in polar bears has limited use for management purposes. We could not find any simple system usable for identification of discrete populations. On the basis of protein variation as sole criterion, the populations investigated could not be separated. Possible explanations for the uniformity of blood proteins can be exchange of bears between geographical areas and/or a high selective pressure in polar bears.     

Exsolution of dolomite and application of calcite–dolomite solvus geothermometry in high‐grade marbles: an example from Skallevikshalsen,East Antarctica

Calcite–dolomite solvus geothermometry is a versatile method for the estimation of metamorphic temperature because of its simplicity. However, in medium‐ to high‐grade metamorphic rocks the accuracy of estimating temperature by the integration of unmixed dolomite and calcite is hampered by the heterogeneous distribution of unmixed dolomite, difficulties in distinguishing between preexisting and exsolved dolomite and demarcating grain boundaries. In this study, it is shown that calcite–dolomite solvus thermometry can be applied to calcite inclusions in forsterite and spinel for the estimation of peak metamorphic temperature in granulite facies marbles from Skallevikshalsen, East Antarctica. The marbles are comprised of a granoblastic mineral assemblage of calcite + dolomite + forsterite + diopside + spinel + phlogopite ± apatite, characteristic of granulite facies metamorphic conditions. Forsterite, spinel and apatite frequently contain ‘negative crystal’ inclusions of carbonates that display homogeneously distributed dolomite lamellae. On the basis of narrow ranges of temperature (850–870 °C) recorded from carbonate inclusions compared with the range from matrix carbonate it is regarded that the inclusion carbonates represent a closed system. Furthermore, this estimate is consistent with dolomite–graphite carbon isotope geothermometry, and is considered to be the best estimate of peak metamorphic temperature for this region. Matrix calcite records different stages of retrograde metamorphism and re‐equilibration of calcite that continued until Mg diffusion ceased at ～460 °C. Electron backscattered diffraction (EBSD) results together with morphological features of unmixed coarse tabular dolomite suggest anisotropic diffusion and mineral growth are influenced by crystallographic orientation. Identification of sub‐grain boundaries and formation of fine‐grained unmixing in calcite rims suggest the presence of grain boundary fluids in the late retrograde stages of metamorphic evolution. These results, thus, demonstrate the usefulness of carbonate inclusion geothermometry in estimating the peak metamorphic temperatures of high‐grade terranes and the application of EBSD in understanding the unmixing behaviour of minerals with solid solutions.     

Impact of Ganges–Brahmaputra interannual discharge variations on Bay of Bengal salinity and temperature during 1992–1999 period

This study investigates the impact of monthly Ganges–Brahmaputra river discharge variations on Bay of Bengal salinity and temperature during the period 1992–1999. The Ganges–Brahmaputra river discharge is characterized by a well-defined seasonal cycle with strong interannual variations. The highest/lowest yearly peak discharge occurs in summer 1998/summer 1992, with 1998 value amounting to twice that of 1992. This river discharge is then used to force an ocean general circulation model. Our main result is that the impact of these rivers on the variability of Bay of Bengal sea surface salinity is strong in the northern part, with excess run-off forcing fresh anomalies, and vice versa. Most of the years, the influence of the interannual variability of river discharge on the Bay salinity does not extend south of ~10°N. This stands in contrast with the available observations and is probably linked to the relatively coarse resolution of our model. However, the extreme discharge anomaly of 1998 is exported through the southern boundary of the Bay and penetrates the south-eastern Arabian Sea a few months after the discharge peak. In response to the discharge anomalies, the model simulates significant mixed-layer temperature anomalies in the northern Bay of Bengal. This has the potential to influence the climate of the area. From our conclusions, it appears necessary to use a numerical model with higher resolution (both on the horizontal and vertical) to quantitatively investigate the upper Bay of Bengal salinity structure.