锈蚀钢筋在疲劳荷载作用下压磁场分布研究

针对锈蚀钢筋的疲劳损伤与寿命评估中的难度大、精度低等问题,引入压磁检测技术,对锈蚀钢筋疲劳过程中的压磁场分布进行检测,从宏观与微观相结合的角度分析压磁场分布与疲劳损伤之间的联系。试验结果表明,锈蚀钢筋的压磁场分布能够反映疲劳损伤的演变规律,疲劳后期非线性特征加剧,锈蚀率及应力幅越大则变化越为明显,磁感强度值、磁场分布梯度、"反转"现象等均有助于进行疲劳损伤评价与寿命预测。研究结果可为压磁无损检测技术在钢筋混凝土结构中的应用提供依据。     

Influence of urban expansion on the urban heat island effect in Shanghai

The urban heat island (UHI) effect resulting from rapid urbanization is attracting increasing attention among the global scientific community. This research analyzed the relationship between urban expansion and the UHI effect utilizing an integrated approach, including urban land interpretation and retrieving land surface temperature based on remote sensing, and spatial overlay analysis for revealing the relationship for different time periods between 1984 and 2014 in Shanghai, China. The results show that (1) the spatiotemporal changes in UHI are consistent with the expansion of urban land, and rapid urban expansion leads to an expansion of the UHI, in particular along roadways. (2) The mode of urban expansion is an important factor influencing the UHI effect. Urban sprawl (urban expansion in the edge-expansion way) is a form of typical expansion that leads to the rapid increase in the UHI. When the urban compactness ratio is less than 0.15, a compact design can effectively control the expansion rate of the UHI and mitigate its range of influence and intensity. However, when the urban compactness ratio is greater than 0.15, the urban design has a marked influence on the UHI ratio index: a more compact form produces a stronger UHI effect. So, finding an equilibrium between urban compactness ratio and urban expansion rate is good for effective urban management and planning.     

频谱分解技术在泥页岩储层含气性预测中的应用——以柴达木盆地鱼卡凹陷为例

针对柴达木盆地北缘鱼卡凹陷中侏罗统大煤沟组泥页岩,利用地震频谱曲线在不同流体介质储层中的形态、斜率、主频与中心频率的差值等属性参数特征,识别陆相泥页岩层系的地震频谱属性特征,预测含气性。研究结果表明,中侏罗统大煤沟组上部能量系数较低,平均为0.6719,下部能量系数较高,平均为0.7521,结合现场含气量和全烃特征认为,可以以能量系数0.7为界线,作为识别下部和上部含气性的标志,下部明显比上部含气性好。平面上进一步圈定了2个有利目标区,得到柴页1井勘探验证。因此,频谱分解技术可应用于中国陆相页岩气的勘查开发。     

柴达木盆地北缘侏罗系页岩气地质条件

侏罗系泥页岩是柴达木盆地的主力烃源岩之一,具备形成页岩油气的地质条件。对采自柴北缘鱼卡、大煤沟、小煤沟、开源、绿草沟、大头羊等煤矿附近地表露头的11块中侏罗统泥页岩样品进行单样品多参数实验分析,探讨了陆相页岩有机地化、储层物性、含气量等参数之间的关系,建立了页岩气资源评价参数体系。结果表明,柴达木盆地北缘中侏罗世处于浅湖-半深湖湖相沉积,断裂较发育,泥页岩富含有机质,具有低孔、低渗、低熟、较高含气量等特点,具备形成页岩油气的地质条件,进一步的勘查开发需优选地层压力系数高、保存条件较好、脆性矿物含量高的页岩气甜点区。     

Interannual variability of summer monsoon rainfall over Myanmar

Observed summer (May–October) rainfall in Myanmar for the period 1981–2010 was used to investigate the interannual variability of summer monsoon rainfall over Myanmar. Empirical orthogonal function, the sequential Mann-Kendall test, power spectrum analysis, and singular value decomposition (SVD) were deployed in the study. Results from spectral analysis showed that the variability of rainfall over Myanmar exhibits a 2- to 6-year cycle. An abrupt change in rainfall over the country was noted in 1992. There was a notable increasing rainfall trend from 1989. After the sudden change, the mean rainfall increased by 36.1 mm, compared with the mean rainfall before the sudden change, and was associated with a rise in temperature of about 0.2 °C. An increase in heavy rainfall days was observed from the early 1990s to 2010. IOD and ENSO play an important role in the interannual variability of the summer rainfall over Myanmar. The covariability between rainfall over Myanmar and Indian Ocean SST generally suggests that a positive IOD mode is associated with suppressed rainfall in the central and northern parts of Myanmar. During a negative IOD mode, nearly the whole Myanmar experiences enhanced rainfall, which is associated with devastating socioeconomic impacts. The covariability between the rainfall over Myanmar and the sea surface temperature in the Pacific Ocean in the first and second SVD modes was dominated by warming in the east and central Pacific—an El Niño-like pattern—resulting in dry conditions in central Myanmar.     

海底管道检测中侧扫声纳声波掠射角的优化设计

针对利用侧扫声纳检测海底管道时因其检测声影图像模糊而导致管道悬空高度检测误差过大的问题,提出了侧扫声纳声波掠射角优化设计的思路及方法。阐述了利用侧扫声纳对海底管道进行检测的工作原理,并利用海底管道和海底底质反向散射强度的计算公式探讨了声波在海底的反向散射强度、侧扫声纳声影图像的质量以及声波掠射角的取值这三者之间的关系对海底管道悬空高度h计算精度的影响,从理论上确定声波掠射角最佳取值范围的存在。通过工程实例的现场检测与比对试验,获得了在本试验所处海域环境中利用侧扫声纳检测海底管道时声波掠射角的最佳取值范围,对于类似的海底管道检测工程具有一定的指导意义。     

应用两次展开法求解系泊柱体慢漂运动方程

在深海中系泊的海洋平台,如Spar平台,水下部分为带有系泊的圆柱结构,其水平方向运动响应往往具有较低的自振频率,容易在低频波浪力(源于非线性的差频效应)作用下发生共振响应,使结构发生大幅水平慢漂。当浮体的瞬时位置大幅偏离初始位置时,基于初始平衡位置的摄动展开法会存在较大误差。针对这一问题,采用两次展开方法,对大幅慢漂运动开展时域模拟研究。对双色波作用下自由漂浮圆柱的大幅运动响应问题进行数值分析,并与采用基于初始平衡位置的摄动展开法的计算结果进行了对比。结果表明,采用新的两次展开法可以计算出波浪遭遇频率的变化和波浪漂移阻尼,而这无法从基于初始平衡位置的常规摄动展开法中得到,体现了两次展开法在分析大幅慢漂问题上的优势。     

深海细菌太平洋火色杆菌中α-淀粉酶基因amy608的克隆表达及其酶学性质研究

从来自深海沉积物的太平洋火色杆菌(Flammeovirga pacifica)的基因组中发现了一个全长为1 875 bp的α-淀粉酶基因amy608.该基因在数据库中找不到具有同源性的序列,而所编码的Amy608蛋白与已注册蛋白的氨基酸序列相似性最高仅为56%,但具有α-淀粉酶水解活性所必需的保守基序DXEXD.进化树分析表明其属于糖苷水解酶13(GH13)家族第二亚家族.构建了p ColdΙ-amy608表达载体,在大肠杆菌中进行重组Amy608蛋白的异源表达,并采用镍离子亲和层析柱对重组蛋白进行了纯化.酶学性质分析表明,重组酶Amy608的最适作用温度为40℃,在40℃保温4 d后,仍保留70%以上的酶活,显示出良好的中温热稳定性;最适p H值为7.0,p H值范围在6~9时仍保留60%以上的酶活力,表明该酶具有较宽的p H值作用范围.Ca2+、Na+、K+对α-淀粉酶Amy608有激活作用,尤其是Ca2+可使酶活显著提高40%.薄层色谱分析结果显示该酶水解可溶性淀粉的最终产物以葡萄糖为主,表明该酶是一个糖化型淀粉水解内切酶.这些结果表明Amy608为GH13家族第二亚家族中一个新型的α-淀粉酶.     

深海细菌Pseudomonas sp. IOFA1中甲醛歧化酶FM11的纯化及性质研究

从印度洋深海沉积物中分离出一株能够高效降解甲醛的假单胞菌(Pseudomonas sp.IOFA1),该菌株可在40 min内完全降解100 mg/cm~3的甲醛.通过阴离子交换柱层析对菌株破碎液中的粗酶液进行纯化,得到一条具有甲醛降解活性的单一蛋白条带.经MALDI-TOF/TOF质谱鉴定,该蛋白为甲醛歧化酶蛋白(FM11).序列分析表明FM11与其它物种已知醛脱氢酶的氨基酸序列最高相似性为65%;结构域分析表明FM11含有2个保守的锌结合位点和一个NAD结合位点.酶学性质分析结果显示,FM11的最适反应温度为40℃,在25~50℃范围内能够保留95%以上的酶活力,尤其是在高于70℃的高温环境下仍保有约50%的活力,表现出广泛的温度适应性.FM11具有非常广泛的最适反应pH值范围(pH值为5~9),且在pH值4和pH值10时仍分别保留50%和80%左右的酶活力,表现出广泛的pH适应性.在pH值为5~7的条件下孵育1 h后,FM11仍保有97%以上的酶活,且在pH值为7~10条件下孵育1 h后,仍保留90%以上的酶活,表现出极好的酸性和碱性稳定性.Ca~(2+)、Mg~(2+)在低浓度时(0.5 mmol/dm~3)对FM11有较明显的激活作用.这些研究为我们进一步开发Pseudomonas sp.IOFA1甲醛歧化酶在降解甲醛方面的用途奠定了基础.