山东省优质地下水资源评价研究

地下水是水资源的重要组成部分,山东省作为我国的北方大省,近年来随着人口的增长和经济发展,地下水环境问题日渐突出,表现为水质型缺水和水源型缺水两方面。本文以山东省地下水为研究对象,对全省富水地段及已建水源地逐一进行水质评价及开采潜力评价研究,结果显示:山东省优质水占49.53%,主要分布在鲁中南山区和鲁东低山丘陵区,新圈定的优质地下水富水地段及有开采潜力水源地共计88处,优质地下水允许开采量184.095×10~4m^3/d,可满足一千余万居民生活用水需求。应急情况下富水地段(水源地)允许开采量为434.299×10~4m^3/d,应急开采潜力为279.295×10~4m^3/d,可解决两千余万人生活用水困难。     

电感耦合等离子体质谱法(7900 ICP-MS)测定土壤中30种痕量元素

本文中土壤样品利用HNO3-HF-HCl O4混酸消解和王水提取后,采用电感耦合等离子体质谱(ICP-MS)法同时测定了国家标准土壤样品中30种痕量元素(Ba、Be、Bi、Cd、Ce、Co、Cr、Cs、Cu、Ga、Hf、In、La、Li、Mn、Mo、Nb、Ni、Pb、Rb、Sb、Sc、Sr、Ta、Th、Tl、U、V、W、Zn)的含量。其测定值与标准值相符,准确度符合国家标准要求。该方法所有元素的相关系数在0.9990~1.0000之间,各元素的方法检出限均满足要求,相对标准偏差(RSD)≤10%,结果表明该方法满足土壤中痕量元素的分析要求,建立的方法样品前处理程序简单快速,线性范围宽,分析重现性好,结果准确,可以运用于大批量地质样品中痕量元素含量的同时测定。最后用已建立的方法测定了北京某地区的土壤样品,测试结果满意。     

X射线荧光光谱法测定土壤中34种主、次痕量元素

采用粉末样品压片制样,水系沉积物及土壤国家一级标准物质作为标准,使用经验系数法和散射线内标法校正元素间的吸收增强效应,用X射线光谱仪对土壤样品中的Fe_2O_3、Cao、Cl、S、As、Ba、Br、Ce、Co、Cr、Ni、Cu、Zn等34种主次痕量元素进行测定,用国家一级标准物质GBW07452(GSS-23),GBW07405(GSS-5)和GBW07404(GSS-4)分析检验准确度和精密度,分析结果与标样标准值吻合,除Cl、S、As、Br、Ce、Co、Ni、Th、Sc、Hf、Nb、Nd的精密度小于10.00%以外,其他各元素精密度均在5.00%以内,各元素检出限均满足化探要求。     

Network-based triple-frequency carrier phase ambiguity resolution between reference stations using BDS data for long baselines

Network-based ambiguity resolution (AR) between reference stations is the prerequisite to realize a precise real-time kinematic positioning service. With the help of BDS triple-frequency signals, we can efficiently deal with the ionospheric delay and tropospheric delay, and achieve rapid and reliable AR. To overcome the inaccurate ionospheric delay estimated by the geometry-free three carrier ambiguity resolution (GF TCAR) technique, which leads to failure in the original ambiguity resolution, we propose an ionospheric-free (IF) TCAR method to resolve the ambiguity between the reference stations over long baselines. Taking full advantage of the known positions of the reference stations, the easily resolved extra-wide-lane (EWL) ambiguity, and the IF phase combinations, we can reliably fix the wide-lane (WL) ambiguity. A Kalman filter is applied to estimate precise IF ambiguities and the original ambiguity is resolved with the fixed WL ambiguity. A numerical analysis with triple-frequency BDS data from three long baselines of a CORS network is provided to compare the AR performance of GF TCAR with that of IF TCAR. The results show that both methods can reliably resolve the WL ambiguity with a remarkable correctly-fixed rate of higher than 99%, and the reliably-fixed rates of the IF TCAR slightly increase from 92.19, 94.67 and 94.61–98.26, 99.54 and 97.51% for the three baselines. Herein “correctly-fixed” and “reliably-fixed” mean the difference between the float ambiguity and the true one are less than ± 0.5 and ± 0.25 cycles, respectively. On the other hand, the AR performance of the original signals with the IF TCAR method is much better than that with the GF TCAR method attaining a 100% correctly-fixed rate, while the GF TCAR method can hardly fix the original ambiguity with the largest bias being as much as 4 cycles because of the amplified systematic bias.     

An improved ionosphere interpolation algorithm for network RTK in low-latitude regions

A traditional interpolation algorithm with the linear interpolation method (LIM) using a fixed number of reference stations is widely used in network RTK to obtain the ionospheric delays for the users. In low-latitude regions, where the ionosphere is relatively active, however, large interpolation errors exist, especially for satellites at low elevation angles. Considering the characteristics of “coinciding ionospheric pierce points (CIPPs)” with a similar nature of ionospheric delays, an improved interpolation algorithm is proposed. In this algorithm, all stations with CIPPs are used to establish the interpolation model; thus, more precise interpolation model is achieved. To validate the performance of the proposed algorithm, data from some reference stations in Guangdong Province of China were used, and the results are compared with those with the traditional interpolation algorithm. Numerical analysis shows that the interpolation accuracy of the proposed algorithm increases by 10–30% compared with the traditional one. Since the number of reference stations is flexible, the proposed algorithm can also balance the model accuracy with the computation burdens. In addition, the proposed algorithm is less affected by the selection of master reference station. In terms of network RTK on-the-fly positioning, the time-to-first-fix is reduced when replacing the traditional interpolation algorithm with the proposed one.     

河流湖泊湿地边界定位中遥感影像时相选择方法

选择高分遥感影像的时相是利用高分遥感影像精确定位湖泊河流湿地自然边界的关键问题之一。在没有或缺少水文观测数据的情况下,依据河流湖泊湿地的定义,本文提出了一种用于河流湖泊湿地边界定位的高分遥感影像时相快速选择方法,试验结果表明该方法合理、准确、有效。     

新疆萨热克砂砾岩型铜矿床成矿流体碳、氢-氧同位素组成及其意义

新疆萨热克铜矿为砂砾岩型铜矿床,赋矿地层为上侏罗统库孜贡苏组砂砾岩.矿体以层状为主,并有裂隙、碎裂构造岩相伴生,常见辉铜矿等金属硫化物与石英、方解石和白云石等胶结物沿砾石间隙或岩石裂隙充填分布.为了揭示成矿流体的性质、来源,文章对矿体中呈脉状产出的石英和碳酸盐矿物(方解石和白云石)中的流体包裹体和碳、氢-氧同位素进行了测定.研究表明:石英和方解石中流体包裹体的气相分数通常为5％～15％,均一温度变化范围88～249℃,平均为172℃;盐度变化范围为6.30％～12.51％,平均为9.46％,为中低温、中低盐度成矿流体.脉状方解石中的δD变化范围为-72‰～-62‰,平均-67.3‰;δ18O变化范围为3.9‰～8.0‰,平均5.3‰,脉状石英中 δD变化范围为-101.7‰～-87.1‰,平均-93.3‰;δ18O变化范围5.1‰～7.5‰,平均6.6‰,氢-氧同位素组成主要落在岩浆水和变质水重叠区及其附近.方解石(白云石)中的δ18O变化范围为-15.1‰～-9.5‰,平均为-12.9‰;δ13C变化范围为-2.5‰～-2.0‰,平均为-0.8‰.同位素组成显示其位于海相碳酸盐岩区左侧附近,与研究区石炭系等碳酸盐岩的碳、氧同位素相似,表明铜矿石中的脉状方解石脉(无机碳)主要与海相碳酸盐岩的溶解作用有关.综合考虑上述结果,文章推测在萨热克铜矿的北矿段深部可能存在隐伏岩体,成矿流体为变质流体与岩浆热液叠加形成的具中、低温,中、低盐度特征的混合流体,该研究区深部存在具有进一步找矿的潜力.     

积雪变化对中国森林凋落物分解影响研究进展

森林凋落物的分解对于维持生态系统物质循环和养分平衡具有重要意义,并受到不同积雪厚度下冻融格局的影响。冻融期（包括冻结过程期、完全冻结期、融化过程期）是冻土区凋落物分解的重要时期,该时期分解的凋落物量约占全年分解总量的一半。积雪减少通常会导致土壤温度降低、冻融循环次数增加,进而影响凋落物分解。通过综述近10年来积雪变化对我国森林凋落物分解影响的研究成果发现,积雪厚度减少在冻融期通常会抑制凋落物质量损失、碳元素释放和纤维素降解,生长季则起到促进作用,从全年来看多数表现为抑制作用。因此,冻融作用造成凋落物的物理破坏,对其分解的促进作用主要发生在后续生长季。积雪厚度减少在冻融期通常抑制氮元素释放,生长季和全年则无明显规律;磷元素和木质素目前研究还存在很大差异。最后,进一步阐述了积雪变化对凋落物分解影响研究存在的问题及未来研究发展方向。     

基于弱光栅技术的地面沉降自动化监测系统

光纤监测技术具有分布式、精度高等特点,在地面沉降监测中具有独特优势。但受限于监测成本较高与监测环境复杂,目前地面沉降光纤监测多通过人工采集数据,限制了在特殊环境变化情况下地面沉降的实时信息获取。文章在地面沉降钻孔全断面光纤监测技术的基础上,设计并建立了基于弱光栅技术的地面沉降自动化监测系统。该监测系统利用弱反射光栅、时分复用、物联网和数据库等技术,通过4G无线通信手段实现了地面沉降在线自动化监测和远程数据实时采集,并通过客户端系统软件实现数据的存储、查询和分析。将其应用到衡水地区地面沉降监测中,结果表明:钻孔内土层压缩变形主要发生在以黏性土为主的隔水层（Ad2、Ad3、Ad4）;受季节性地下水开采的影响,钻孔100～400 m深度范围内砂土含水层存在波动变化,在监测期内,冬季略回弹,随后春季地下水开采量增大,地下水位下降,土层呈现压缩趋势。监测结果验证了该系统的可行性与准确性,使得整个地面沉降监测流程趋于自动化、规范化和低成本化,具有广泛的应用前景。     

旋挖钻机在特殊工况中的减压钻进研究

为解决旋挖钻机在脆性岩层或者软硬交替地层等特殊工况中加压钻进出现的钻机高频高幅振动和钻孔极易倾斜等问题,对旋挖钻机入岩的碎岩机理进行分析,找出加压钻进产生问题的原因。对减压钻进施工工艺进行研究,提出实现方式及适用范围,并进行实际工程应用,验证了旋挖钻机使用减压钻进施工的可行性。应用结果表明,特殊工况下减压钻进对降低设备的入岩振动、提高设备的结构稳定性以及保证成孔质量都具有重要作用。