三元体系CaCl2?SrCl2?H2O的相平衡及其在钙锶分离中的应用

采用等温溶解平衡法研究了三元体系CaCl₂?SrCl₂?H₂O温度从323.15 K到353.15 K范围内的相平衡。基于该三元体系多温下的相平衡数据,设计开展了实验室模拟南翼山油田卤水中氯化钙和氯化锶在温度323.15 K下的分离实验。实验室模拟钙锶分离实验结果表明,在323.15 K下时分离一次固相产品中的钙锶摩尔比可以从25.46:1降至1.73:1,SrCl₂的回收率为52.47 %,所得一次固相产品在323.15 K下溶解并再次蒸发。钙和锶的摩尔比从1.73:1降至1.1:1,SrCl₂的回收率为78.67 %。     

2004年度天文学科科学基金面上项目

介绍了2004年度天文学科科学基金申请、资助的基本情况，并对其结果进行了分析．     

Establishment of digital model for dynamic simulation analysis on hydraulic impact perforator

Hydraulic impact perforator is powerful tools for trenchless project. It has advantages in cabinet structure, low cost, long life and easy protected. Compared with pneumatic DTH, the hydraulic impact spear worked under high pressure and using uncompressible fluid thusgreater impact energy and higher efficiency can be supported. The authors founded the dynamic simulation model of HDI-146 hydraulic impact spear. The project for solving the differential equation was suggested also. By means of virtual machine technology, the dynamic mechanism of HDI-146 can be explored and tutoring us to optimize the structural parameters can be made.     

冬小麦拔节期灌溉防霜冻效果研究

以矮抗58为研究对象,在冬小麦拔节期设置灌溉与未灌溉两种水分处理,通过对无霜冻年份(2012年)和晚霜冻年份(2013年)的对比试验,分析晚霜冻害对冬小麦群体密度、干物质积累、产量及其构成要素的影响,探讨拔节期灌溉的防霜效果。研究结果表明:1)孕穗-抽穗期发生晚霜冻害可使冬小麦群体密度下降、产量显著降低。2012年的产量整体高于2013年的,且2012年未灌溉处理的产量显著高于2013年灌溉处理的(P0.05);受霜冻影响,2013年灌溉与未灌溉的成熟期密度分别比抽穗期下降11.8%和14.8%,地上部分总干物质重先显著下降而后逐渐恢复,和抽穗期相比其下降幅度分别为18.5%(灌溉)和33.7%(未灌溉)。2013年成熟期叶片干重占地上部分总干物质重比例为43.5%(灌溉)和41.0%(未灌溉),显著高于2012年的16.3%(灌溉)和4.1%(未灌溉)。2)无论是否有霜冻害发生,拔节期灌溉均可显著提高产量,灌溉处理产量分别比未灌溉处理的偏高16.3%(2012年)和24.5%(2013年)。霜冻年份拔节期灌溉处理可显著降低穗粒数损失和抽穗期以后叶面积指数的衰减速度。3)2013年灌溉处理较2012年灌溉处理减产23.6%,未灌溉处理较2012年未灌溉处理减产32.9%。拔节期灌溉能够有效减少霜冻造成的产量损失,但这主要是由水分增加所引起,抽穗期的冬小麦抗霜能力并没有提高。     

湖北省PM2.5质量浓度遥感估算与时空分布特征

针对地面站点稀疏不足以提供高空间覆盖、高空间分辨率的面域PM_2.5数据支撑区域细颗粒物污染防治的问题,以湖北地区2015-2017年的MODIS卫星遥感气溶胶光学厚度（AOD）产品数据为主预测量,结合温度、湿度、风速、压强等气象参数和植被指数数据等辅助预测量,建立了AOD-PM_2.5关系逐日变化的线性混合效应（LME）模型,用于估算湖北地区的PM_2.5浓度水平.利用十折交叉验证方法进行了模型精度评估.结果表明：1）2015-2017年的交叉验证R²分别达到0.89、0.85和0.88,利用MODIS AOD数据反演近地面PM_2.5质量浓度的线性混合效应模型能很好地用于区域细颗粒物遥感监测;2）省内PM_2.5质量浓度空间差异显著,鄂东、鄂南和鄂北高,鄂西北和鄂东南低;3）全省PM_2.5估算时空数据年均值呈下降态势,分别为65.6±39.8、57.1±34.1和48.1±28.3 μg/m³,各市除随州、咸宁2016、2017年年均值持平外,都呈下降趋势.     

GRAPES区域集合预报尺度混合初始扰动构造的新方案

集合预报初始扰动能否准确反映预报误差的结构特征是决定区域集合预报质量的关键因素之一。本文针对GRAPES区域数值预报模式,发展设计了一种基于资料同化思想的混合尺度初始扰动构造新方案。该方案以全球大尺度信息为背景场,区域模式预报作为观测资料,借助GRAPES三维变分同化系统,将高质量的全球大尺度信息与区域模式预报中质量较高的中小尺度信息有效融合,构造混合尺度区域集合预报初始扰动,并通过个例试验和批量试验,比较分析了新方案和原区域集合预报的性能。试验结果表明,基于资料同化构造的初始扰动能够有效融合全球大尺度信息和中小尺度天气系统的信息,其降水概率预报更具参考价值。总体上看,区域集合预报混合初始扰动新方案能够较好地改进区域集合预报质量,尤其是对高度场和温度场效果更为显著,但对风场的集合预报性能影响略小。     

纳米及微米级六角片状氢氧化镁的制备

以氯化钠为底料,水氯镁石和氢氧化钠为原料,不添加任何添加剂,采用双柱沉淀—水热法制备粒度分布均匀、分散性良好的氢氧化镁。研究了进料速度、2N_(Mg)/N_(Na)、物料浓度、水热温度、水热时间等因素对氢氧化镁粒径、形貌、过滤性能的影响。通过粒度分析仪、X射线衍射仪、低真空扫描电子显微镜对产品的粒度分布、结构和形貌进行了表征。结果表明,本研究得到的样品分散性好,粒度分布均匀,形貌为规则的六角片状,粒径为400~600 nm的纳米级氢氧化镁或者1~2μm的微米级氢氧化镁。     

Understanding spatial structures and organizational patterns of city networks in China: A highway passenger flow perspective

The use of multi-perspective and multi-scalar city networks has gradually developed into a range of critical approaches to understand spatial interactions and linkages. In particular, road linkages represent key characteristics of spatial dependence and distance decay, and are of great significance in depicting spatial relationships at the regional scale. Therefore, based on highway passenger flow data between prefecture-level administrative units, this paper attempted to identify the functional structures and regional impacts of city networks in China, and to further explore the spatial organization patterns of the existing functional regions, aiming to deepen our understanding of city network structures and to provide new cognitive perspectives for ongoing research. The research results lead to four key conclusions. First, city networks that are based on highway flows exhibit strong spatial dependence and hierarchical characteristics, to a large extent spatially coupled with the distributions of major megaregions in China. These phenomena are a reflection of spatial relationships at regional scales as well as core-periphery structure. Second, 19 communities that belong to an important type of spatial configuration are identified through community detection algorithm, and we suggest they are correspondingly urban economic regions within urban China. Their spatial metaphors include the administrative region economy, spatial spillover effects of megaregions, and core-periphery structure. Third, each community possesses a specific city network system and exhibits strong spatial dependence and various spatial organization patterns. Regional patterns have emerged as the result of multi-level, dynamic, and networked characteristics. Fourth, adopting a morphology-based perspective, the regional city network systems can be basically divided into monocentric, dual-nuclei, polycentric, and low-level equilibration spatial structures, while most are developing monocentrically.     

Plate subduction,oxygen fugacity,and mineralization

Plate subduction is the largest natural factory that processes elements, which controls recycling and mineralization of a variety of elements. There are three major ore deposit belts in the world: the circumPaci?c, the central Asian, and the Tethys belts. All the three belts are closely associated with plate subductions, the mechanism remains obscure. We approached this problem from systematic studies on the behaviours of elements during geologic processes. This contribution summaries the recent progress of our research group. Our results suggest that porphyry Cu deposits form through partial melting of subducted young oceanic crust under oxygen fugacities higher than ? FMQ ～+1.5, which is promoted after the elevation of atmospheric oxygen at ca. 550 Ma. Tin deposits are associated with reducing magmatic rocks formed as a consequence of slab rollback. The Neo-Tethys tectonic regime hosts more than 60% of the world's total Sn reserves. This is due to the reducing environment formed during the subduction of organic rich sediments. For the same reason, porphyry Cu deposits formed in the late stages during the closure of the Neo-Tethys Ocean. Tungsten deposits are also controlled by slab rollback, but is not so sensitive to oxygen fugacity. Subduction related W/Sn deposits are mostly accompanied by abundant accessory ?uorites due to the breakdown of phengite and apatite. Decomposition of phengite is also signi?cant for hard rock lithium deposits, whereas orogenic belt resulted from plate subduction promote the formation of Li brine deposits. Cretaceous red bed basins near the Nanling region are favorable for Li brines. Both Mo and Re are enriched in the oxidationreduction cycle during surface processes, and may get further enriched once Mo-, Re-enriched sediments are subducted and involved in magmatism. During plate subduction, Mo and Re fractionate from each other. Molybdenum is mainly hosted in porphyry Mo deposits and to a less extent, porphyry Cu-Mo deposits, whereas Re is predominantly hosted in porphyry Cu-Mo deposits and sedimentary sul?de deposits.