Models to determine first-order rate coefficients from single-well push-pull tests

Push-pull tests (PPTs) have been successfully employed to quantify various microbially mediated processes in the subsurface. Current models for determining first-order rate coefficients (k) from PPTs assume complete and instantaneous mixing of injected test solution in the portion of the aquifer investigated by the test, i.e., the system is treated like a well-mixed reactor. Here we present two alternative models to estimate k that are based on different mixing assumptions, i.e., plug-flow and variably mixed reactor models. Rate coefficients estimated by the models were compared using a sensitivity analysis and numerical simulations of PPTs. Results indicated that all models yielded reasonably accurate k estimates (errors < 13%), while best accuracy (errors < 1%) was obtained using the variably mixed reactor model. The well-mixed reactor model generally overestimated true (simulation input) k values, whereas true k values were consistently underestimated by the plug-flow reactor model. However, estimates of k obtained with the latter models bracketed true k values in all cases. As the variably mixed reactor model is more difficult to apply, we suggest using the well-mixed and plug-flow reactor models to obtain intervals for k estimates that will encompass true k values with high certainty. In an example application, we used all models to reanalyze a published PPT data set to obtain k estimates for nitrate consumption in a petroleum-contaminated aquifer. Similar results were obtained for all three models (relative differences < 10% between k estimates), indicating that all three models are robust tools for estimating k values from PPT experimental data.     

Monitoring regional groundwater extraction: the problem

As hydraulic disturbances (signals) are propagated through a groundwater system two things happen: (1) the higher frequencies in the disturbance are filtered out by the physics of the system and (2) the disturbance takes time to propagate through the system. The filtering and time delays depend on the aquifer diffusivity. This means, for example, if one is observing a water table aquifer at some distance from where annual recharge is occurring, only the long-term average effect of the recharge will be transmitted to the observation point--the system filters out annual variations. These facts have profound impacts on what is feasible to monitor. For example, if one is concerned about the impact of pumping on a spring in a water table aquifer, where the pumping is more than 20 miles or so from the spring, there will be a long delay before the pumping impacts the spring and there will be an equally long delay before a long-term reduction in the pumping regime will restore the spring. The filtering by lower diffusivity groundwater systems makes it impossible to discriminate between the impacts of several major pumpers in the system and/or long-term climate changes.     

Estimating aquifer properties from the water level response to Earth tides

Water level fluctuations induced by tidal strains can be analyzed to estimate the elastic properties, porosity, and transmissivity of the surrounding aquifer material. We review underutilized methods for estimating aquifer properties from the confined response to earth tides. The earth tide analyses are applied to an open well penetrating a confined carbonate aquifer. The resulting range of elastic and hydraulic aquifer properties are in general agreement with that determined by other investigators for the area of the well. The analyses indicate that passive monitoring data from wells completed in sufficiently stiff, low porosity formations can provide useful information on the properties of the surrounding formation.     

Biological responses to contaminants in the Humber Estuary: disentangling complex relationships

Due to the ecological importance of estuaries, it is necessary to understand the biological effects that potentially toxic contaminants induce in bioindicator species. A key aspect is whether effects at lower levels of biological organisation transfer through the system to higher levels. In understanding such processes, characterising multivariate relationships between contaminants, sediment toxicities and detoxification processes are important. Worms (Hediste diversicolor) and sediments were collected along the Humber Estuary, England, and inorganic and organic contaminants were quantified. Sediment toxicities and glutathione-S-transferases (GSTs) activity in the ragworm were analysed. Concentrations of metals were highest near urban and industrial areas, whereas organic contaminants appeared at upstream locations. GST activity correlated with heavy metals. The genotoxicity, oestrogenicity, dioxin and dioxin-like activity were higher at upstream locations. Oestrogenicity correlated with alkylphenols and some organochlorines, whilst genotoxicity correlated with organochlorines and heavy metals. Despite this, higher level biological responses could not be predicted, indicating that homeostasis is operating.     

Feeding the family during times of stress: experience and determinants of food insecurity in an Inuit community

This paper uses a mixed methods approach to characterise the experience of food insecurity among Inuit community members in Igloolik, Nunavut, and examine the conditions and processes that constrain access, availability, and quality of food. We conducted semi-structured interviews (n= 66) and focus groups (n= 10) with community members, and key informant interviews with local and territorial health professionals and policymakers (n= 19). The study indicates widespread experience of food insecurity. Even individuals and households who were food secure at the time of the research had experienced food insecurity in the recent past, with food insecurity largely transitory in nature. Multiple determinants of food insecurity operating over different spatial-temporal scales are identified, including food affordability and budgeting, food knowledge and preferences, food quality and availability, environmental stress, declining hunting activity, and the cost of harvesting. These determinants are operating in the context of changing livelihoods and climate change, which in many cases are exacerbating food insecurity, although high-order manifestations of food insecurity (that is, starvation) are no longer experienced.     

Estimate of recharge of a rising water table in semiarid Niger from 3H and 14C modeling

A hydrodynamic survey carried out in semiarid southwest Niger revealed an increase in the unconfined ground water reserves of approximately 10% over the last 50 years due to the clearing of native vegetation. Isotopic samplings (3H, 18O, 2H for water and 14C, 13C for the dissolved inorganic carbon) were performed on about 3500 km2 of this silty aquifer to characterize recharge. Stable isotope analyses confirmed the indirect recharge process that had already been shown by hydrodynamic surveys and suggested the tracers are exclusively of atmospheric origin. An analytical model that takes into account the long-term rise in the water table was used to interpret 3H and 14C contents in ground water. The natural, preclearing median annual renewal rate (i.e., recharge as a fraction of the saturated aquifer volume) lies between 0.04% and 0.06%. For representative characteristics of the aquifer (30 m of saturated thickness, porosity between 10% and 25%), this implies a recharge of between 1 and 5 mm/year, which is much lower than the estimates of 20 to 50 mm/year for recent years, obtained using hydrological and hydrodynamic methods and the same aquifer parameters. Our study, therefore, reveals that land clearing in semiarid Niger increased ground water recharge by about one order of magnitude.