Mössbauer study of Meridiani Planum,the first iron‐nickel meteorite found on the surface of Mars by the MER Opportunity

Abstract— –Meridiani Planum is the first iron meteorite found on Mars. It was discovered in 2005 by the Mars Exploration Rover Opportunity (MER‐B). Mössbauer spectra (MS) of the unbrushed and brushed meteorite species were acquired in 10 degrees temperature windows in the range of 210–260 K. Earlier examinations of these MS have led to the conclusion that the meteorite, which contains ～～7 wt% Ni, belongs to the IAB meteorite group. Here, making use of a recently developed calibration/folding procedure for MER MS, we report the results of the MS analyses for the single temperature windows m5 (210–220 K), m6 (220–230 K), m7 (230–240 K), and m89 (240–260 K). All spectra consist of a sextet and a ferric doublet. The hyperfine field of the sextet, extrapolated to room temperature, is ～～34.5 T, which is, based on Mössbauer studies of meteorites found on Earth, indeed consistent with the presence of kamacite. The fractional spectral area of the sextet is ～～0.96 of the total spectrum. The ferric doublet has an average quadrupole splitting of 0.70 mm/s and is not diagnostic of any specific Fe mineral.     

Morphology of Younger Dryas subglacial and ice-proximal submarine landforms, inner Vestfjorden, northern Norway

The sea-floor morphology of two pronounced across-fjord bedrock thresholds located at the mouths of Ofotfjorden and Tysfjorden, northern Norway, has been analysed based on swath bathymetry and seismic data. The Younger Dryas ice front was located here during the recession of one of the large palaeo-ice streams of the Fennoscandian Ice Sheet. The thresholds are several kilometres long and wide, rising to several hundred metres above the adjacent sea floor, and the slopes are steep, up to 25°. The Ofotfjorden threshold is draped by acoustically discontinuous to chaotic sediments partly infilling the bedrock relief. A pattern of well-developed, subglacial bedforms (e.g. crag-and-tail formations, drumlins and glacial lineations) on top of both thresholds suggests fast-flowing ice. A series of smaller transverse ridges is identified on both thresholds and probably records ice-front oscillations during the final deglaciation. The distal parts of the sediments have been remobilized by slides that occurred after glacial retreat from the thresholds. Earthquake activity due to the isostatic rebound following ice retreat from this area was the most likely triggering mechanism for the slides. The location of the ice front on a prominent bedrock threshold indicates that the basin configuration was important in locating the maximum position of the climatically induced re-advance, i.e. a topographic control on the maximum Younger Dryas position in the Ofotfjorden and Tysfjorden area is suggested.     

Magnetic mineralogy of the sediments in Lake Ådran, eastern Sweden, and an interpretation of early Holocene water level changes

A number of magnetic parameters have been measured on samples from a master sequence in Lake Adran, eastern Sweden. Based on the results, frequency dependent magnetic susceptibility, high isothermal rem-anence magnetization and different magnetic ratios have been calculated. The results from the master sequence have also been compared with magnetically analysed soil samples from the lake catchment. The results of the magnetic analyses show that the sediments in Lake Ådran originate from two sources, one regional and one local. The different sources can be related to water level changes during the Ancylus and Litorina stages. Sediments originating from the regional source are characterized by high ferrimagnetic to antiferromagnetic ratios (high S-ratios) and are assumed to have been deposited when the water level was well above the threshold. Sediments derived from the catchment, having lower S-ratios, are assumed to have been deposited when the basin was cut off from the regional water circulation. On the basis of the magnetic results, combined with pollen and diatom analyses, tentative water level changes for the Lake Adran basin are compiled.     

Controlling factors of volumetrically important marine carbonate cementation in deep slope settings

The controlling parameters of early marine carbonate cementation in shoal water and hemipelagic to pelagic domains are well‐studied. In contrast, the mechanisms driving the precipitation of early marine carbonate cements at deeper slope settings have received less attention, despite the fact that considerable volumes of early marine cement are present at recent and fossil carbonate slopes in water depths of several hundreds of metres. In order to better understand the controlling factors of pervasive early marine cementation at greater water depths, marine carbonate cements observed along time‐parallel platform to basin transects of two intact Pennsylvanian carbonate slopes are compared with those present in the slope deposits of the Permian Capitan Reef and Neogene Mururoa Atoll. In all four settings, significant amounts of marine cements occlude primary pore spaces downslope into thermoclinal water depths, i.e. in a bathymetric range between some tens and several hundreds of metres. Radial, radiaxial and fascicular optic fibrous calcites, and radiaxial prismatic calcites are associated with re‐deposited facies, boundstones and rudstones. Botryoidal (formerly) aragonitic precipitates are common in microbially induced limestones. From these case studies, it is tentatively concluded that sea water circulation in an extensive, near‐sea floor pore system is a first‐order control on carbonate ion supply and marine cementation. Coastal upwelling and internal or tidal currents are the most probable mechanisms driving pore water circulation at these depths. Carbonate cements precipitated under conditions of normal to elevated alkalinity, locally elevated nutrient levels and variable sea water temperatures. The implications of these findings and suggestions for future work are discussed.     

Diagenetic formation of gypsum and dolomite in a cold‐water coral mound in the Porcupine Seabight,off Ireland

Authigenic gypsum was found in a gravity core, retrieved from the top of Mound Perseverance, a giant cold‐water coral mound in the Porcupine Basin, off Ireland. The occurrence of gypsum in such an environment is intriguing, because gypsum, a classic evaporitic mineral, is undersaturated with respect to sea water. Sedimentological, petrographic and isotopic evidence point to diagenetic formation of the gypsum, tied to oxidation of sedimentary sulphide minerals (i.e. pyrite). This oxidation is attributed to a phase of increased bottom currents which caused erosion and enhanced inflow of oxidizing fluids into the mound sediments. The oxidation of pyrite produced acidity, causing carbonate dissolution and subsequently leading to pore‐water oversaturation with respect to gypsum and dolomite. Calculations based on the isotopic compositions of gypsum and pyrite reveal that between 21·6% and 28·6% of the sulphate incorporated into the gypsum derived from pyrite oxidation. The dissolution of carbonate increased the porosity in the affected sediment layer but promoted lithification of the sediments at the sediment‐water interface. Thus, authigenic gypsum can serve as a signature for diagenetic oxidation events in carbonate‐rich sediments. These observations demonstrate that fluid flow, steered by environmental factors, has an important effect on the diagenesis of coral mounds.     

Subglacial bedforms and conditions associated with the 1991 surge of Skeiðarárjökull, Iceland

Much previous research at surge-type glaciers has sought to identify features diagnostic of surge-type behaviour. However, in comparatively little work have subglacial landform–sediment characteristics been used to reconstruct changing basal processes and conditions during surge events. Subglacial bedforms described in this article are associated with the 1991 surge of Skeiðarárjökull, Iceland, and include a series of drumlins with superimposed flutes and basal crevasse-fill ridges. The drumlins were formed by the subglacial erosion of ice-contact fans. Sedimentary evidence indicates a shift from rigid-bed to soft-bed conditions during the surge. The presence of eroded but undeformed fan sediments suggests that they acted as a rigid bed when initially overridden. Subsequent deposition of a layer of deformation till resulted in a change to soft-bed conditions and the generation of flutes and subglacial crevasse-fill ridges. The lack of mixing between this till and the underlying stratified sediments indicates that subglacial sediment deformation was restricted to a thin layer and that its deposition resulted in a cessation of subglacial erosion. The drumlin is therefore a composite of both rigid-bed and soft-bed processes that illustrates changes in basal conditions and processes during the course of the event. The limited time frame in which the drumlin formed and the presence of kettleholes across its surface are distinctive features that may warrant further investigation in the search for features diagnostic of past surge events.     

Infrared stimulated luminescence dating of an Eemian (MIS 5e) site in Denmark using K‐feldspar

Buylaert, J.‐P., Huot, S., Murray, A.S. & Van den haute, P.: Infrared stimulated luminescence dating of an Eemian (MIS 5e) site in Denmark using K‐feldspar. Boreas, 10.1111/j.1502‐3885.2010.00156.x. ISSN 0300‐9483. Infrared stimulated luminescence (IRSL) dating of K‐feldspars may be an alternative to quartz optically stimulated luminescence (OSL) dating when the quartz OSL signal is too close to saturation or when the quartz luminescence characteristics are unsuitable. In this paper, Eemian (MIS 5e) coastal marine sands exposed in a cliff section on the coast of southern Jutland (Denmark) are used to test the accuracy and precision of IRSL dating using K‐feldspars. This material has been used previously to test quartz OSL dating ( Murray & Funder 2003 ): a small systematic underestimation of <10% compared to the expected age of ～130 ka was reported. In our study, a single‐aliquot regenerative‐dose (SAR) IRSL protocol is used to determine values of equivalent dose (D_e) and the corresponding fading rates (g values). A significant age underestimation (of up to ～35%) is observed; this is attributed to anomalous fading. Using a single site‐average fading rate of 3.66 ± 0.09%/decade to correct the IRSL ages for all samples provides good agreement between the average fading‐corrected K‐feldspar age (119 ± 6 ka) and the independent age control (132–125 ka). This is despite the reservations of Huntley & Lamothe (2001) that their fading correction method is not expected to work on samples older than ～20–50 ka. This fading‐corrected feldspar result is not significantly different from the overall revised quartz age (114 ± 7 ka) also presented here. We conclude that fading‐corrected IRSL ages measured using K‐feldspar may be both precise and accurate over a greater age range than might be otherwise expected.     

Palaeohydrology and global continental changes - panta rhei?

Branson, J., Brown, A. G. & Gregory, K. J. (cds.) 1996: Glubai Continental Changes: The Context of Palaeohydrology