Copper bioavailability in a coastal environment of Northern Chile: comparison of bioassay and analytical speciation approaches

An integrated approach including chemical speciation analyses and microalgal bioassays was used to assess the impact of copper from copper mining on a coastal area in Northern Chile. Dissolved copper ranged from <1 microg l(-1) at reference sites to 48 microgl(-1) at sites close to the mine discharge. Dissolved copper at sites closest to the discharge always exceeded seawater complexing capacities determined by anodic stripping voltammetry (ASV), and consequently labile copper was always detected (1-37 microg l(-1)). Agreement between ASV-labile copper and copper retained by cation exchange (ALSA) columns was excellent. Measured labile copper also accurately predicted bioavailable copper determined by growth inhibition of Nitzschia closterium and enzyme inhibition in Dunaliella tertiolecta. Seawater from Caleta La Lancha had the highest dissolved and labile copper and was the most toxic to micro-algal growth and enzyme activity. Previous studies at this site confirmed it had the lowest level of biodiversity, suggesting that copper may have both direct and indirect effects on these communities.     

Biodiversity of rocky intertidal benthic communities associated with copper mine tailing discharges in northern Chile

Copper mine tailings have been discharged around the city of Chanaral, in northern Chile, for more than 60 years. This report summarizes a 17-month long monitoring study of species richness and biodiversity at five intertidal sites around the point of the tailing discharge. Total dissolved copper in sites close to the point of discharge varied between 8.72 microg/l and 34.15 microg/l, showing that there has not been a significant reduction since 1994. However, species richness has increased, suggesting a possible recovery of the system. While diversity of sessile organisms correlates negatively with dissolved copper, diversity of mobile invertebrates did not correlate with the metal concentration. To explain the observed results we discuss the role of algal turf interference on the distribution of mobile invertebrates at reference sites, a top-down effect caused by the absence of carnivores at impacted sites, and an avoidance strategy by some species to reduce their contact with contaminated seawater.     

Measuring the Cosmic Equation of State with Counts of Galaxies

We show that the gas in growing density perturbations is vulnerable to the influence of winds outflowing from nearby collapsed galaxies that have already formed stars. This suggests that the formation of nearby galaxies with masses less, similar10(9) M( middle dot in circle) is likely to be suppressed, irrespective of the details of galaxy formation. An impinging wind may shock-heat the gas of a nearby perturbation to above the virial temperature, thereby mechanically evaporating the gas, or the baryons may be stripped from the perturbation entirely if they are accelerated to above the escape velocity. We show that baryonic stripping is the most effective of these two processes, because shock-heated clouds that are too large to be stripped are able to radiatively cool within a sound crossing time, limiting evaporation. The intergalactic medium temperatures and star formation rates required for outflows to have a significant influence on the formation of low-mass galaxies are consistent with current observations, but may soon be examined directly via associated distortions in the cosmic microwave background and with near-infrared observations from the Next Generation Space Telescope, which may detect the supernovae from early-forming stars.     

An assessment of the potential use of the nematode to copepod ratio in the monitoring of metals pollution. The Chañaral case

We discuss the use of the nematode to copepod ratio in relation to determining the extent of metals impact using the Cha?aral area of northern Chile, where the dumping of copper mine tailings has taken place for many years, as an example. Data were collected from 12 beaches in the area on eight occasions between January 1997 and October 1998. We find that the ratio is not a good predictor of pollution due to the generally low densities of meiofauna on impacted beaches and the absence of harpacticoid copepods from those beaches. We suggest that in the case of metal pollution the mean number of Harpacticoida per site may be a better indicator of impact stress. We rule out the use of the nematode to copepod ratio as an indicator in biomonitoring studies where metal enrichment is thought to occur.     

Changes in benthic fish assemblages as a consequence of coastal works in a coastal lagoon: The Mar Menor (Spain, Western Mediterranean)

The benthic fish assemblage of the Mar Menor consisted of 37 species. Dominant species are: Gobius cobitis, Lipophrys pavo and Tripterygion tripteronotus on infralittoral rocks; Pomatoschistus marmoratus, Callionymus pussillus, Callionymus risso and Solea vulgaris on sandy bottoms and Gobius niger, Syngnathus abaster, Hippocampus ramulosus and Symphodus cinereus on Cymodocea nodosa-Caulerpa prolifera mixed beds. From 1985 to 1989 tourist development has led to the creation of new beaches and the installation of artificial rocky structures for retaining sediments. Dredging for the extraction of sand and subsequent pumping altered sediment characteristics causing a real stress leading to the substitution of typical sandy bottoms communities with Cymodocea nodosa by Caulerpa prolifera communities on mud. Soft bottom fish assemblages responded to changes in vegetation cover and substratum characteristics mainly changing the species composition, while artificial hard substrata contain a similar fish community than natural ones, harbouring even richer and more diverse assemblages. This positive effect of breakwaters should not obscure their likely negative effects on hydrodynamics and the subsequent changes of sediment quality and vegetation cover on the breakwaters' area of influence.     

Monitoring biomarkers in fish (Lepidorhombus boscii and Callionymus lyra) from the northern Iberian shelf after the Prestige oil spill

Hepatic biomarker responses were measured in two demersal fish species (Lepidorhombus boscii and Callionymus lyra) from the northern Iberian shelf associated with the massive Prestige oil spill (POS), five months after the accident. The biomarkers selected were 7-ethoxyresorufin-O-deethylase (EROD), glutathione-S-transferase (GST), glutathione reductase (GR), catalase (CAT), and DNA integrity. Interspecies differences and spatial variations in biomarker responses were observed along the shelf. GST, GR and CAT activities were significantly elevated in L. boscii in the most oil impacted area (Finisterre) and positively correlated (p<0.05) with POS tar aggregate densities. The lack of previous data from the area together with the existence of chronic background pollution of the shelf implies that the observed biomarker responses cannot be solely attributed to the petroleum hydrocarbon components of the spilled oil. This first biological effect assessment showed that L. boscii is a potentially suitable target species to be used in future biomonitoring programmes along the northern Iberian shelf.     

Quality assurance, information tracking, and consumer labeling

Reducing marine-based public health risk requires strict control of several attributes of seafood products, often including location and conditions of catch or aquaculture, processing, and handling throughout the supply chain. Buyers likely will also be interested in other attributes of these products such as eco-friendliness or taste. Development of markets for improved safety, as well as for other quality attributes, requires an effective certification and tracking of these attributes as well as their communication to buyers. Several challenges must be met if labeling, particularly consumer labeling, is to support the development of markets for improved seafood safety.     

国际矿物学协会新矿物及矿物命名委员会最近批准的新矿物

公布了国际矿物学协会新矿物及矿物命名委员会批准的１９９４年度的新矿物。各矿物的描内容为：化学式，国际矿物学协会编号，与其它矿物关系，晶系，空间群，晶胞参数、颜色，光泽，透明度，光性，Ｘ射线衍射的强线。