Rare earth elements in the clay fraction of coaliferous sediments of the Arkagalinskoe (Magadan district) and Dolinskoe (Sakhalin Island) coalfields

The study of REE distribution in the clay fraction of sedimentary rocks from two coalfields made it possible to distinguish several types of REE distribution, which correlate with their mineral composition. It is shown that the REE fractionation was related to the mineral reconstruction of the primary clay fraction and some detrital minerals in the course of postsedimentary transformations of rocks during diagenesis, early catagenesis, and beginning of late catagenesis. These transformations were governed by several factors, such as the composition of sediments; hydrochemical features of accumulation environment; the chemical composition, dynamics, and feeding sources of pore solutions; the porosity and permeability of sediments and rocks; and the content of organic matter and its reaction ability.     

Copper(II) humate mobility in kaolinite soil

An investigation of the influence of humate on the mobility of copper(II) ions in a kaolinite soil using leaching tests and electrokinetic experiments is reported. The data are interpreted in terms of humate–copper–clay interactions and humate electrical charge. Humate is mostly immobile below pH8 but is more mobile in alkaline conditions (sorption to kaolinite reduces its mobility in neutral conditions). Copper humate complexes are mobile in both acidic and alkaline conditions, but not in neutral conditions where they are sorbed. The dissolved copper humate complexes that form in acidic conditions are positively charged. The net effect of humate is to increase cupric ion mobility in kaolinite soil, especially in alkaline conditions.     

Reconstruction of palaeosalinity using carbon isotopes and benthic associations: a comparison

Carbon and oxygen isotopes were determined on 40 recrystallized shells of Late Jurassic bivalves from the Lusitanian Basin of Portugal. In contrast with the oxygen isotopes, which exhibited considerable diagenetic distortion, the carbon isotopes are thought to preserve a record of the salinity of the Jurassic marginal marine seas in which these bivalves lived. The reconstructed palaeosalinities range from 35%o (euhaline) to 5% (oligohaline). Comparing these values with the palaeosalinity reconstructed from a palaeoecological analysis of 17 stratigraphic levels within the basin, the independently derived values agree in most cases. Strongly differing values are explained as being due to biotic factors and to diagenetic distortion of the isotopic signal; they are less likely to be due to smallscale time-averaging or insufficient microstratigraphic sampling. On the whole, the carbon isotope analyses are thought to produce reasonable palaeosalinity values, although data from infaunal, originally aragonitic bivalves appear to be less reliable than those from epifaunal bivalves with a predominantly or exclusively calcitic shell. As diagenetic alteration of the carbon isotope signal is, however, unpredictable and biotic effects on the isotopic composition are insufficiently known, palaeosalinity reconstructions based on stable isotope data should be supported by palaeoecological data.     

Improved Petrological Modal Analyses from X-ray Powder Diffraction Data by use of the Rietveld Method I. Selected Igneous, Volcanic, and Metamorphic Rocks

Mineral modes have been determined for specimens of eight rocktypes from CuK X-ray powder diffraction data using the Rietveldmethod. The samples include two granites, a granodiorite, adamellite,gabbro, basalt, trachyte, and two granulite-facies metamorphicrocks. Up to eight individual mineral components have been measuredin each sample (no glassy phases were observed), with a detectionlimit of {small tilde}1 wt.%, depending on the mineral assemblage.Marked variations in grain size (i.e., granite vs. trachyte)provide no difficulties for the X-ray method. The X-ray resultscompare very favourably with (1) optical modes determined forthe medium–coarse-grained samples by point counting, (2)normative calculations obtained using locally enhanced catanormand mesonorm software, and (3) corresponding Rietveld modesdetermined, for two samples, from neutron powder data. Wheredifferences occur, these are discussed in relation to the limitationsof each of the methods. The improved accuracy of the X-ray method is due primarily tothe incorporation of the full diffraction profile in the Rietveldanalysis calculations, and the elimination of preferred orientationby collecting the data from samples packed in glass capillaries(i.e., Debye–Scherrer mode). The good agreement of theX-ray and neutron modes shows that the usual problems encounteredwith microabsorption, extinction, and sampling are of littleconcern in these rocks. The results highlight one of the majoradvantages provided by Rietveld modal analysis over the moretraditional ‘reference intensity’ X-ray methods,namely, that the crystal chemistry (and thus the calibrationconstants) of the individual phases can be adjusted dynamicallyduring each individual analysis. This not only provides moreaccurate phase abundances, but also gives important supplementaryinformation about the mineralogy of the major components.     

Desert vegetation and timing of solar radiation

Timing and amount of solar radiation were examined as factors influencing the distribution of seven perennial plants on a small mountain located in the Chihuahuan Desert. Average direct beam solar radiation fluxes at differing times throughout the day and year were estimated with computer calculations. Principal components analysis was used to reduce the number of solar radiation parameters and include the maximum available information with a manageable number of variables. The remaining solar radiation parameters were compared to plant distributions using redundancy analysis and generalized additive models. Unimodal, bimodal, and monotonic responses were all found depending upon the species and solar radiation parameter. Niche separation at this location depends upon the timing as well as the amount of solar radiation.     

A 2D finite volume model for bebris flow and its application to events occurred in the Eastern Pyrenees

FLATModel is a 2D finite volume code that contains several original approaches to improve debris-flow simulation. Firstly, FLATModel incorporates a ＂stop-and-go＂ technique in each cell to allow continuous collapses and remobilizations of the debris-flow mass. Secondly, flow velocity and consequently yield stress is directly associated with the type of rheology to improve boundary accuracy. Thirdly, a simple approach for entrainment is also included in the model to analyse the effect of basal erosion of debris flows. FLATMODEL was tested at several events that occurred in the Eastern Pyrenees and simulation results indicated that the model can represent rather well the different characteristics observed in the field.     

Rock-weathering rates as functions of time

The scarcity of documented numerical relations between rock weathering and time has led to a common assumption that rates of weathering are linear. This assumption has been strengthened by studies that have calculated long-term average rates. However, little theoretical or empirical evidence exists to support linear rates for most chemical-weathering processes, with the exception of congruent dissolution processes. The few previous studies of rock-weathering rates that contain quantitative documentation of the relation between chemical weathering and time suggest that the rates of most weathering processes decrease with time. Recent studies of weathering rinds on basaltic and andesitic stones in glacial deposits in the western United States also clearly demonstrate that rock-weathering processes slow with time. Some weathering processes appear to conform to exponential functions of time, such as the square-root time function for hydration of volcanic glass, which conforms to the theoretical predictions of diffusion kinetics. However, weathering of mineralogically heterogeneous rocks involves complex physical and chemical processes that generally can be expressed only empirically, commonly by way of logarithmic time functions. Incongruent dissolution and other weathering processes produce residues, which are commonly used as measures of weathering. These residues appear to slow movement of water to unaltered material and impede chemical transport away from it. If weathering residues impede weathering processes then rates of weathering and rates of residue production are inversely proportional to some function of the residue thickness. This results in simple mathematical analogs for weathering that imply nonlinear time functions. The rate of weathering becomes constant only when an equilibrium thickness of the residue is reached. Because weathering residues are relatively stable chemically, and because physical removal of residues below the ground surface is slight, many weathering features require considerable time to reach constant rates of change. For weathering rinds on volcanic stones in the western United States, this time is at least 0.5 my.     

Changes in temperature and precipitation extremes in the CMIP5 ensemble

Twenty-year temperature and precipitation extremes and their projected future changes are evaluated in an ensemble of climate models participating in the Coupled Model Intercomparison Project Phase 5 (CMIP5), updating a similar study based on the CMIP3 ensemble. The projected changes are documented for three radiative forcing scenarios. The performance of the CMIP5 models in simulating 20-year temperature and precipitation extremes is comparable to that of the CMIP3 ensemble. The models simulate late 20th century warm extremes reasonably well, compared to estimates from reanalyses. The model discrepancies in simulating cold extremes are generally larger than those for warm extremes. Simulated late 20th century precipitation extremes are plausible in the extratropics but uncertainty in extreme precipitation in the tropics and subtropics remains very large, both in the models and the observationally-constrained datasets. Consistent with CMIP3 results, CMIP5 cold extremes generally warm faster than warm extremes, mainly in regions where snow and sea-ice retreat with global warming. There are tropical and subtropical regions where warming rates of warm extremes exceed those of cold extremes. Relative changes in the intensity of precipitation extremes generally exceed relative changes in annual mean precipitation. The corresponding waiting times for late 20th century extreme precipitation events are reduced almost everywhere, except for a few subtropical regions. The CMIP5 planetary sensitivity in extreme precipitation is about 6 %/°C, with generally lower values over extratropical land.     

The born-again (very late thermal pulse) scenario revisited: the mass of the remnants and implications for V4334 Sgr

We present 1D numerical simulations of the very late thermal pulse (VLTP) scenario for a wide range of remnant masses. We show that by taking into account the different possible remnant masses, the observed evolution of V4334 Sgr (a.k.a. Sakurai's object) can be reproduced within the standard 1D mixing length theory (MLT) stellar evolutionary models without the inclusion of any ad hoc reduced mixing efficiency. Our simulations hint at a consistent picture with present observations of V4334 Sgr. From energetics, and within the standard MLT approach, we show that low-mass remnants  ( M ≲ 0.6 M_⊙)  are expected to behave markedly differently from higher mass remnants  ( M ≳ 0.6 M_⊙)  in the sense that the latter remnants are not expected to expand significantly as a result of the violent H-burning that takes place during the VLTP. We also assess the discrepancy in the born-again times obtained by different authors by comparing the energy that can be liberated by H-burning during the VLTP event.     

On the eigenvalues of kinematic α-effect dynamos

The kinematic α-effect dynamo problem is investigated in the case of an exterior perfect conductor. It is shown that certain approximate symmetries discovered in the numerical analysis of ROBERTS (1972) are exact for this case. As an illustration, an exact solution is given in a cylindrical geometry, where the equations can be written in terms of one variable. The implications for the earth's dynamo are discussed.