Large-scale structure in the NIR-selected MUNICS survey

The Munich Near-IR Cluster Survey (MUNICS) is a wide-area, medium-deep, photometric survey selected in the K' band. The project's main scientific aims are the identification of galaxy clusters up to redshifts of unity and the selection of a large sample of field early-type galaxies up to z < 1.5 for evolutionary studies. We created a Large Scale Structure catalog, using a new structure finding technique specialized for photometric datasets, that we developed on the basis of a friends-of-friends algorithm. We tested the plausibility of the resulting galaxy group and cluster catalog with the help of Color-Magnitude Diagrams (CMD), as well as a likelihood- and Voronoi-approach. This revised version was published online in August 2006 with corrections to the Cover Date.     

A sedimentary record of the rise and fall of the metal industry in Bergslagen,south central Sweden

Detailed stratigraphic analyses of sediments deposited in Lake Botjärnen, a small boreal forest lake in the shield terrain of central Sweden, clearly reflect progressively increasing human impact on terrestrial and aquatic ecosystems following settlement and establishment of an iron industry in the 17th century. Rising frequencies of pollen and spores from light-demanding plants provide evidence of extensive forest clearance for charcoal and timber production, which peaked in the early 20th century. An associated increase in catchment erosion is reflected by changing carbon and nitrogen elemental content and carbon–isotope composition of sediment organic matter and by increased magnetic susceptibility of the sediments. Records of air-borne pollutants (lead, zinc and sulphur) can be correlated to the development of local and regional mining and metal industry as inferred from historical accounts. Rapid recession of the iron industry led to re-forestation and recovery of the aquatic nutrient status to pre-industrial conditions over the past 100 years. The chronology of the sediment succession, which is based on ²¹⁰Pb and ¹³⁷Cs radionuclide data in combination with radiocarbon dating, is confirmed by historical lead pollution trends established for the region.     

Measurement of stress effects (scope for growth) and contaminant levels in mussels (Mytilus edulis) collected from the Irish Sea

The objective of this research was to quantify the impact of pollution along the coastlines of the Irish Sea. Pollution assessment was based on the combined measurement of scope for growth (SFG), and chemical contaminants in the tissues of mussels (Mytilus edulis) collected from 38 coastal sites around the Irish Sea during June-July in 1996 and 1997. On the UK mainland coast, the SFG showed a general trend with a significant decline in water quality in the Liverpool and Morecambe Bay region. High water quality was recorded along the west coast of Wales, as well as southwest England and northwest Scotland (clean reference sites outside the Irish Sea). Along the coast of Ireland there was a similar trend with reduced SFG within the Irish Sea region. SFG was generally low north of Duncannon and then improved north of Belfast. The poor water quality on both sides of the Irish Sea is consistent with the prevailing hydrodynamics and the spatial distribution of contaminants associated with urban/ industrial development. The decline in SFG of mussels on both sides of the Irish Sea was associated with a general increase in contaminant levels in the mussels. Certain contaminants, including PAHs, TBT, sigmaDDT, Dieldrin, gamma-HCH, PCBs, and a few of the metals (Cd, Se, Ag, Pb), showed elevated concentrations. Many of these contaminants were particularly elevated in the coastal margins of Liverpool Bay, Morecambe Bay and Dublin Bay. A quantitative toxicological interpretation (QTI) of the combined tissue residue chemistry and SFG measurements indicated that at the majority of coastal sites, c. 50 to > 80% of the observed decline in SFG was due to PAHs as a result of fossil fuel combustion and oil spills. TBT levels were highest at major ports and harbours, but these concentrations only made a minor contribution to the overall reduction in SFG. At no sites were individual metals accumulated to concentrations that could cause a significant effect on SFG. The study identified many sites where the observed reduction in SFG was far greater than predicted from the limited number of chemical contaminants analysed, thus indicating the presence of additional 'unknown toxicants'. Sewage (containing domestic, agricultural and industrial components) appears to be an important contributor to reduced SFG and linear alkylbenzenes (LABs) and As may provide suitable 'sewage markers'. There was a highly significant positive correlation between SFG and As (P < 0.001). This relationship may be due to reduced As uptake by algal food material and mussels at sites with elevated P04 concentrations (e.g. at sites with sewage inputs). Phosphate is a known competitive inhibitor of As accumulation, at least in algae. The results highlight that further research is required on 'sewage markers' in mussels. The SFG approach therefore provides a rapid, cost-effective and quantitative measure of pollution impact, as well as a means of identifying the causes through a QTI of tissue contaminants levels. It also serves to identify the presence of unidentified toxicants and areas that require further study.     

Elemental (C,N, H and P) and stable isotope (δ<Superscript>15</Superscript>N and δ<Superscript>13</Superscript>C) signatures in sediments from Zeekoevlei,South Africa: a record of human intervention in the lake

We used elemental carbon, nitrogen, phosphorus and hydrogen ratios (C/N, N/P and H/C) with total organic carbon (TOC) and total phosphorus (TP) as well as stable carbon and nitrogen isotopes (δ¹³C and δ¹⁵N) to investigate the source and depositional conditions of organic matter in sediments from Zeekoevlei, the largest freshwater lake in South Africa. Typical C/N (10–12), H/C ratios (≥1.7) and δ¹³C_organic values (−22 to −19‰) together with the increase in TOC concentration indicate elevated primary productivity in lower middle (18–22 cm) and top (0–8 cm) sections of the sediment cores. Seepage of nutrients from a nearby waste water treatment plant, rapid urbanization and heavily fertilized farming in the catchments are responsible for the increased productivity. Consistent with this, measured δ¹⁵N_organic values (∼11‰) indicate increased raw sewage input towards the top-section of the core. Although cyanobacterial blooms are evident from the low δ¹⁵N values (∼3‰) in mid-section of the core, they did not outnumber the phytoplankton population. Low N/P ratio (∼0) and high TP (100–2,200 mg l⁻¹) support cyanobacterial growth under N limited condition, and insignificant input of macrophytes towards the organic matter pool. Dredging in 1983, caused sub-aerial exposure of the suspended and surface sediments, and affected organic matter preservation in the upper mid-section (12–14 cm) of the core.     

Jökulhlaup-related Ice Fracture and Supraglacial Water Release During the November 1996 Jökulhlaup, Skeiðarárjökull, Iceland

During the initial stages of the November 1996 jökulhlaup at Skeiðarárjökull, Iceland, floodwaters burst onto the glacier surface via a series of fractures. This supraglacial drainage led to the formation of a number of distinct ice surface depressions, one of which is investigated in detail. The morphology and structural characteristics of this feature are described, as well as the sedimentology of an associated assemblage of debris-filled fractures. This work suggests that debris-charged subglacial floodwaters travelled up to the glacier surface, where supraglacial flow occurred initially via an extensive network of fractures, orientated parallel to the glacier margin. Supraglacial discharge became progressively more focused into a series of discrete outlets, leading to the mechanical erosion of a number of depressions on the glacier surface. The associated transfer of subglacially derived floodwaters to high levels within the glacier resulted in the rapid entrainment of large volumes of sediment which may influence the patterns, processes and products of ice-marginal sedimentation in the future.     

The dynamics and thermodynamics of precipitation loading

A one-dimensional, time-dependent numerical cloud model is used to analyze the factors in the dynamic and thermodynamic equations which lead to a steady-state or nonsteady-state solution for the cloud vertical motion, buoyancy, precipitation, and cloud water fields. ‘Bulk water’ microphysical techniques are used for the cloud, rain, and hail variables. An atmospheric sounding from a severe storm situation is used as initial and environmental conditions, yielding model updrafts of 40 m sec^?1 maximum and more than 10 m sec^?1 over the entire cloud region. ‘Early conversion’ of the cloud water to rain leads to loading of lower portions of the updraft by rain, the formation of appreciable amounts of hail by freezing of the supercooled rain, and subsequent loading of the middle and upper portions of the updraft so that the updraft erodes throughout the cloud depth and the cloud dissipates, yielding a vigorous rain shower. A delay in the conversion of the cloud water to rain results in a steady-state solution, no rain or hail falling through the updraft. A two-dimensional cloud simulation of this same case shows rain and hail in the upper cloud regions recycled in the two-dimensional flow into the updraft near cloud base and a breakdown of the updraft with resultant rainout (negligible hail reaching the ground). The breakdown of the updraft has profound effects on the temperature field within the cloud, causing the lapse rate to deviate from the steady-state condition and approach the initial environmental conditions. The results emphasize the fact that the local change in temperature (and other dependent variables as well) is not independent of the vertical velocity, in general. This has implications for the interpretation of measurements made within clouds.     

The origin of organic matter in the solar system: evidence from the interplanetary dust particles

The detailed examination of meteorites and interplanetary dust particles provides an opportunity to infer the origin of the organic matter found in primitive Solar System materials. If this organic matter were produced by aqueous alteration of elemental (graphitic or amorphous) carbon on an asteroid, then we would expect to see the organic matter occurring preferentially in interplanetary materials that exhibit evidence of aqueous activity, such as the presence of hydrated silicates. On the other hand, if the organic matter were produced either during the nebula phase of Solar System evolution or in the interstellar medium, we might expect this organic matter to be incorporated into the dust as it formed. In that case pre-biotic organic matter would be present in both the anhydrous and the hydrated interplanetary materials. We have performed carbon X-ray absorption near-edge structure spectroscopy and infrared spectroscopy on primitive anhydrous and hydrated interplanetary dust particles (IDPs) collected by NASA from the Earth's stratosphere. We find that organic matter is present in similar types and abundances in both the anhydrous and the hydrated IDPs, and, in the anhydrous IDPs some of this organic matter is the “glue” that holds grains together. These measurements provide the first direct, experimental evidence from the comparison of extraterrestrial samples that the bulk of the pre-biotic organic matter occurs in similar types and abundances in both hydrated and anhydrous samples. This indicates that the bulk of the pre-biotic organic matter in the Solar System did not form by aqueous processing, but, instead, had already formed at the time that primitive, anhydrous dust was being assembled. Thus, the bulk of the pre-biotic organic matter in the Solar System was formed by non-aqueous processing, occurring in either the Solar nebula or in an interstellar environment. Aqueous processing on asteroids may have altered this pre-existing organic matter, but such processing did not affect in any substantial way the C=O content of the organic matter, the aliphatic C-H abundance, or the mean aliphatic chain length.     

Degradation of native wheat straw lignin by Streptomyces viridosporus T7A

Lignin is one of the major contributing factors toward the recalcitrance of lignocellulosic biomass. Understanding the process of lignin degradation in natural biological processes will provide useful information to develop novel biomass conversion technologies. Functional group changes in the lignin entities during the process may contribute to the cellulose degradation (utilization) by the microorganisms. In this study, compositional and advanced Fourier transform infrared, pyrolysis gas chromatography/mass spectrometry and ¹³C cross polarization/magic angle spinning nuclear magnetic resonance analysis were performed to explore the mechanism of biodegradation of wheat straw by Streptomyces viridosporus T7A. The results indicated that S. viridosporus T7A removed lignin and hemicelluloses as indicated by the increased carbohydrate/lignin ratio. Significant modification of carbonyl and methoxyl groups in the complex lignin structure was also evident. Most importantly, the quantitative results showed that lignin degradation was featured by deduction of guaiacyl unit. The results provide new insight for understanding lignin degradation by bacteria.     

The effects of source size on concentration fluctuations in plumes

The effects of source size on plume behaviour have been examined in a 1.2 m wind tunnel boundary layer for isokinetic sources with diameters from 3 to 35 mm at source heights of 230 mm and at ground level. Experimental measurements of mean concentration and the variance, intermittency and probability density functions of the concentration fluctuations were obtained. In addition, a fluctuating Gaussian plume model is presented which reproduces many of the observed features of the elevated emission. The mean plume width becomes independent of source size much more rapidly than the instantaneous plume width. Since it is the meandering of the instantaneous plume which generates most of the concentration fluctuations near the source, these are also dependent on source size. The flux of variance in the plume reaches a maximum, whose value is greatest for the smallest source size, close to the source and thereafter is monotonically decreasing. The intermittency factor reaches a minimum, whose value is lowest for the smallest source, and increases back towards one. Concentration fluctuations for the ground-level source are much less dependent on source size due to the effects of the surface.