Simultaneous optical polarimetry and X-ray observations of the magnetic CV CP Tuc (AX J2315−592)

CP Tuc (AX J2315–592) shows a dip in X-rays which lasts for approximately half the binary orbit and is deeper in soft X-rays compared with hard X-rays. It has been proposed that this dip is due to the accretion stream obscuring the accretion region from view. If CP Tuc were a polar, as has been suggested, then the length of such a dip would make it unique amongst polars since in those polars in which a dip is seen in hard X-rays the dip lasts for only 0.1 of the orbit. We present optical polarimetry and RXTE observations of CP Tuc which show circular polarization levels of ∼10 per cent and find evidence for only one photometric period. These data confirm CP Tuc as a polar. Our modelling of the polarization data implies that the X-ray dip is due to the bulk of the primary accretion region being self-eclipsed by the white dwarf. The energy dependence of the dip is due to a combination of this self-eclipse and also the presence of an X-ray temperature gradient over the primary accretion region.     

Shocked quartz in polymict impact breccia from the Upper Cretaceous Yallalie impact structure in Western Australia

Yallalie is a ~12 km diameter circular structure located ~200 km north of Perth, Australia. Previous studies have proposed that the buried structure is a complex impact crater based on geophysical data. Allochthonous breccia exposed near the structure has previously been interpreted as proximal impact ejecta; however, no diagnostic indicators of shock metamorphism have been found. Here we report multiple (27) shocked quartz grains containing planar fractures (PFs) and planar deformation features (PDFs) in the breccia. The PFs occur in up to five sets per grain, while the PDFs occur in up to four sets per grain. Universal stage measurements of all 27 shocked quartz grains confirms that the planar microstructures occur in known crystallographic orientations in quartz corresponding to shock compression from 5 to 20 GPa. Proximity to the buried structure (~4 km) and occurrence of shocked quartz indicates that the breccia represents either primary or reworked ejecta. Ejecta distribution simulated using iSALE hydrocode predicts the same distribution of shock levels at the site as those found in the breccia, which supports a primary ejecta interpretation, although local reworking cannot be excluded. The Yallalie impact event is stratigraphically constrained to have occurred in the interval from 89.8 to 83.6 Ma based on the occurrence of Coniacian clasts in the breccia and undisturbed overlying Santonian to Campanian sedimentary rocks. Yallalie is thus the first confirmed Upper Cretaceous impact structure in Australia.     

White-light promoted degradation of leucopterin and related pteridines dissolved in seawater, with evidence for involvement of complexation from major divalent cations of seawater

The photochemical instability of several related pteridines in seawater was investigated by aseptic incubation of solutions at 20–22°C under illumination from cool-white light of intensity 6 kerg cm⁻² sec⁻¹, and the chemical changes were spectrophotometrically monitored. All the pteridines showed markedly accelerated degradation from this illumination relative to their behaviour in total darkness.Pterin and lumazine were degraded very slowly with zero-order reaction kinetics, while the other pteridines photolysed rapidly (according to first-order kinetics) with decomposition rates increasing in the order dioxylumazine (2,4,6,7-tetrahydroxypteridine) < leucopterin < isoxanthopterin < xanthopterin < oxylumazine (2,4,6-trihydroxypteridine). Excepting leucopterin and dioxylumazine, the photolysis rates were attributable to the pH of seawater and not its salt content; this was also the case with oxylumazine which required the salt content of seawater for decomposition in darkness. Leucopterin and dioxylumazine (both 6,7-dihydroxylated pteridines) gave evidence of complexation with the major divalent cations (Ca²⁺, Mg²⁺) of seawater, by virtue of which their photolytic degradation rates were enhanced to magnitudes obtained in pH-10 buffer without seawater. It is proposed that such complexation produces structural forms of these pteridines analogous to their normal ionic forms at pH 10–12.The photolysis of the 6-hydroxylated pteridines (xanthopterin, oxylumazine) proceeded via intermediate formation of their corresponding 7-hydroxylated derivatives (leucopterin, dioxylumazine).     

Diver-operated piston corer for nearshore use

A diver-operated piston corer suitable for collecting cores of >3 m length from fine-grained nearshore sediment has been developed. The corer uses a platform that rests on the sediment surface supporting both the operators and a derrick that maintains the piston at the sediment-water interface. The core is insected into and recovered from the sediment manually. The technique offers several advantages; low cost, minimal disruption of the sediment-water interface, little compaction of the sediment, the ability to collect longer length cores than is possible with gravity corers, and the ability to be deployed from relatively small boats. Dissolved ammonium and inorganic carbon data are presented from a 3.3-m core collected by this technique from Tomales Bay, California.     

Fire and vegetation change during the Early Pleistocene in southeastern Australia

Early Pleistocene vegetation in upland southeastern Australia included diverse rainforests and sclerophyll forests, which alternated on precessional timescales. The nature and timing of transitions between these biomes, and the role of fire in maintaining or driving transitions between them, are uncertain. Here we present a high‐resolution pollen record from Stony Creek Basin, a small Early Pleistocene palaeolake in southeastern Australia. The pollen record documents a pattern of vegetation change, over ca. 10 ka at ca. 1590–1600 ka, between sclerophyll forests, dominated by Eucalyptus, Callitris (Cupressaceae) or Casuarinaceae, and rainforests dominated by either angiosperms or conifers of the family Podocarpaceae. Transitions between these biomes typically occurred within ca. 1–2 ka. The associated charcoal record suggests that greatest biomass combustion occurred when local vegetation was dominated by Eucalyptus, and the least biomass combustion occurred when local vegetation was dominated by Podocarpaceae. However, local fires burnt in both sclerophyll and angiosperm‐dominated rainforest vegetation, at least once every several centuries. Fire was very rare (less than about one fire per millennium) only when the local vegetation was rainforest dominated by Podocarpaceae. This suggests that fire was an irregular presence in both sclerophyll‐ and angiosperm‐dominated rainforest biomes during the late Neogene, though was largely absent in Podocarpaceae‐dominated rainforests. Copyright © 2011 John Wiley & Sons, Ltd.     

The flocculation and de-watering of kimberlite clay slimes

The crushing of kimberlite at certain diamond mines produces a very persistent “slime” which is exceptionally difficult to filter or de-water. The colloidally stable component has been identified as a swelling clay, saponite, which carries a strong negative charge in alkaline media.Methods of coagulating or flocculating these slimes have been investigated; the most convenient method found was the combined use of magnesium sulphate and an anionic polyacrylamide (A-130 from B.T.I. Chemicals Ltd.). Optimal results were obtained only in a narrow range of conditions but with these it was possible to build flocs of any required size.The permeability and de-watering of coagulated or flocculated kimberlite slimes has been investigated with a hydraulic apparatus and in the capillary suction time (c.s.t.) apparatus. Typically compressible filter-cakes are obtained, their character varying greatly with the flocculation conditions.     

Enamel diagenesis at South African Australopith sites: Implications for paleoecological reconstruction with trace elements

Elemental ratio data from archaeological and paleontological bone have often been used for paleoecological reconstruction, but recent studies have shown that, even when solubility profiling techniques are employed in an attempt to recover biogenic signals, bone is an unreliable material. As a result, there has been renewed interest in using enamel for such studies, as it is known to be less susceptible to diagenesis. Nevertheless, enamel is not immune from diagenetic processes, and several studies have suggested that paleoecologically relevant elements may be altered in fossil enamel. Here, we investigate Sr, Ba, Zn, and Pb compositions of enamel from South African karstic cave sites in an effort to ascertain whether or not this material provides reliable paleoecological information. We compared enamel data for mammals from three fossil sites aged 1.8-3.0 Ma, all of which are on dolomites, with data from modern mammals living on dolomitic and granitic substrates. Sr/Ca and Ba/Ca are about three times higher in enamel from modern mammals on granites than those living on dolomites, stressing the need for geologically appropriate modern/fossil comparisons. After pretreatment with dilute acid, we found no evidence of increased Sr/Ca, Ba/Ca, or Pb/Ca in fossil enamel. In contrast, Zn/Ca increased by over five times at one site (Makapansgat), but much more subtly elsewhere. Ecological patterning in Sr/Ca, Ba/Ca, and Sr/Ba ratios was also retained in fossil enamel. This study suggests that Sr/Ca, Ba/Ca, and Pb/Ca data likely preserve paleoecological information from these sites, but also demonstrates that geologically similar sites can differ in the degree to which they impart certain elements (Zn in this case) to fossils. Thus, screening is probably necessary on a site-by-site basis. Lastly, further investigation of elemental distributions in modern foodwebs is necessary before elemental ratio analysis can become a common tool for paleoecological reconstruction.     

Joint PDF Modelling of Turbulent Flow and Dispersion in an Urban Street Canyon

The joint probability density function (PDF) of turbulent velocity and concentration of a passive scalar in an urban street canyon is computed using a newly developed particle-in-cell Monte Carlo method. Compared to moment closures, the PDF methodology provides the full one-point one-time PDF of the underlying fields containing all higher moments and correlations. The small-scale mixing of the scalar released from a concentrated source at the street level is modelled by the interaction by exchange with the conditional mean (IECM) model, with a micro-mixing time scale designed for geometrically complex settings. The boundary layer along no-slip walls (building sides and tops) is fully resolved using an elliptic relaxation technique, which captures the high anisotropy and inhomogeneity of the Reynolds stress tensor in these regions. A less computationally intensive technique based on wall functions to represent the boundary layers and its effect on the solution are also explored. The calculated statistics are compared to experimental data and large-eddy simulation. The present work can be considered as the first example of computation of the full joint PDF of velocity and a transported passive scalar in an urban setting. The methodology proves successful in providing high level statistical information on the turbulence and pollutant concentration fields in complex urban scenarios.     

Coherence analysis of granular intensity

A high resolution spectrogram of the Mg b₂ line from the quiet Sun disc centre is subjected to a coherence analysis. We find that the coherence between intensity fluctuations in the continuum and the wings of the line breaks down at a distance = 0.35 Å from line centre. From this and the r.m.s. intensity contrast as a function of we are led to the following simple model of temperature fluctuation T in the solar photosphere: A lower part (below 50 km, or ₅₀₀₀ > 0.25) with strongly inward increasing T and an upper part (above 50 km) with constant T = 75 K. The two parts are supposed to fluctuate incoherently.Mitteilungen aus dem Kiepenheuer Institut Nr. 166.