Dissolution kinetics of fosteritic olivine at 90-150 °C including effects of the presence of CO2

The steady state dissolution rate of San Carlos olivine [Mg_1.82Fe_0.18 SiO₄] in dilute aqueous solutions was measured at 90, 120, and 150 °C and pH ranging from 2 to 12.5. Dissolution experiments were performed in a stirred flow-through reactor, under either a nitrogen or carbon dioxide atmosphere at pressures between 15 and 180 bar. Low pH values were achieved either by adding HCl to the solution or by pressurising the reactor with CO₂, whereas high pH values were achieved by adding LiOH. Dissolution was stoichiometric for almost all experiments except for a brief start-up period. At all three temperatures, the dissolution rate decreases with increasing pH at acidic to neutral conditions with a slope of close to 0.5; by regressing all data for 2 ? pH ? 8.5 and 90 °C ? T ? 150 °C together, the following correlation for the dissolution rate in CO₂-free solutions is obtained:

     

Considerations about antenna pattern measurements of 2-D aperture synthesis radiometers

Accurate measurement of the antenna voltage patterns of large-aperture synthesis radiometers is critical in order to achieve good radiometric accuracy, and a very time consuming and expensive task. Measurement requirements and a tradeoff study relating radiometric accuracy degradation and number of elements to be measured are presented.     

Characterization of potential zones of dust generation at eleven stations in the southern Sahara

Summary Synoptic wind data for multi-decadal periods at eleven stations located in the southern Sahara region (Agadez, Atar, Bilma, Dori, Gao, Kayes, Nema, Niamey, Nouadhibou, Ouagadougou and Tessalit) are used to study the monthly dust deflation power over the region. We found that, regardless of the conditions of the soil, the deflation power (or wind efficiency) is not sufficient to generate significant amounts of aerosols south of 15°N. North of this latitude, the deflation power is much larger, with potential zones of either very strong deflation (Nouadhibou and Bilma) or severe deflation (Gao, Tessalit, Nema, Atar, Agadez). Stations in the Sahel region such as Gao, Agadez and Tessalit are characterized by a gradual reinforcement of the deflation power between 1970 and 1984 in correspondence of increasing desertification over the region. During this same period, Bilma, a well know region of dust source, experienced a major reduction in deflation power due to shifts in large scale wind patterns.     

2,4,6-trinitrotoluene transformation by a tropical marine yeast, Yarrowia lipolytica NCIM 3589

Yarrowia lipolytica NCIM 3589, a tropical marine degrader of hydrocarbons and triglycerides transformed 2,4,6-trinitrotoluene (TNT) very efficiently. Though this yeast could not utilize TNT as the sole carbon or nitrogen source, it was capable of reducing the nitro groups in TNT to aminodinitrotoluene (ADNT). In a complete medium containing glucose and ammonium sulphate as the available carbon and nitrogen sources respectively, the culture was able to completely transform 1 mM (227 ppm) of TNT under such conditions. A dual pathway was found to be functional, one of which resulted in the formation of the hydride-Meisenheimer complex (H(-)TNT) as a transiently accumulating metabolite that was subsequently denitrated to 2,4-dinitrotoluene (2,4-DNT), whereas the other pathway resulted in the formation of amino derivatives. The presence of increasing amounts of reducing equivalents in the form of glucose promoted better growth and the nitroreductases of this yeast to reduce the aromatic ring to 2,4-DNT although, the reduction of the nitro groups to amino groups was the major functional pathway. The ability of this tropical marine yeast to transform TNT into products such as 2,4-DNT which in turn could be metabolized by other microbes has implications in the use of this yeast for bioremediation of TNT polluted marine environments.     

Excitation of PtI transitions ending at the levels of the main term

We have experimentally studied the excitation of transitions of the platinum atom ending in levels of the ³D main term. The atoms were excited by a 30 eV monoenergetic electron beam. The lines studied are located at wavelengths of 204–367 nm. The largest of the measured excitational cross sections exceed 10^?16 cm². The optical-excitation functions measured at electron energies of 0–200 eV have complex structures.     

New Calculation of the Electrical Microfield Distribution in Plasma

Recently new calculations for the probability field distribution in plasma generating a new expression for the Debye screening fields was carried out by Martin and Perez (1996). This field is a very accurate solution of the Poisson equation for a point test charge in a plasma described by a uniform charge density at Boltzmann thermal equilibrium. The method that we here present is based mainly on the introduction of this adequate field considering the dependence of the potential with the magnitude of the test charge in the calculus of the distribution. First we find the spectral function F(k) carrying out the Fourier transform of the field which is numerically calculated for each representative value of the variable in k space and then fitting these data in order to get F(k). Thus, after the usual numerical integration on the wave number space d³k, the field strength distribution is achieved. This approximation recovers the Holtsmark distribution in the limit of high temperature, and/or, small densities as also these where 0. As in previous works (Ecker, 1972; Spatschek, 1990) the most probable value of the field decreases as the temperature is reduced, and/or, the density increased.     

Abundance Gradients in the Outer Galactic Disk

Radial abundance gradients of the element ratios O/H, Ne/H, S/H, and Ar/H are determined for a sample of disk planetary nebulae, emphasizing the behaviour of the gradients at large galactocentric distances. This revised version was published online in July 2006 with corrections to the Cover Date.