White-light promoted degradation of leucopterin and related pteridines dissolved in seawater, with evidence for involvement of complexation from major divalent cations of seawater

The photochemical instability of several related pteridines in seawater was investigated by aseptic incubation of solutions at 20–22°C under illumination from cool-white light of intensity 6 kerg cm⁻² sec⁻¹, and the chemical changes were spectrophotometrically monitored. All the pteridines showed markedly accelerated degradation from this illumination relative to their behaviour in total darkness.Pterin and lumazine were degraded very slowly with zero-order reaction kinetics, while the other pteridines photolysed rapidly (according to first-order kinetics) with decomposition rates increasing in the order dioxylumazine (2,4,6,7-tetrahydroxypteridine) < leucopterin < isoxanthopterin < xanthopterin < oxylumazine (2,4,6-trihydroxypteridine). Excepting leucopterin and dioxylumazine, the photolysis rates were attributable to the pH of seawater and not its salt content; this was also the case with oxylumazine which required the salt content of seawater for decomposition in darkness. Leucopterin and dioxylumazine (both 6,7-dihydroxylated pteridines) gave evidence of complexation with the major divalent cations (Ca²⁺, Mg²⁺) of seawater, by virtue of which their photolytic degradation rates were enhanced to magnitudes obtained in pH-10 buffer without seawater. It is proposed that such complexation produces structural forms of these pteridines analogous to their normal ionic forms at pH 10–12.The photolysis of the 6-hydroxylated pteridines (xanthopterin, oxylumazine) proceeded via intermediate formation of their corresponding 7-hydroxylated derivatives (leucopterin, dioxylumazine).     

The impact of wave loads and pore-water pressure generation on initiation of sediment transport

The build-up of pore-water pressure by waves can lead to sediment liquefaction and subsequent transport by traction currents. This process was investigated by measuring pore-water pressures both in a field experiment and laboratory wave tank tests. Liquefaction was observed in the wave tank tests. The results suggest that sand is less susceptible than silts to wave-induced liquefaction because of the tendency to partially dissipate pore-water pressures. However, previous studies have determined that pore-water pressures must approach liquefaction before current velocities necessary to initiate transport are reduced. Once liquefaction has occurred more sediment can be transported.     

Raising the packing density of computerized oceanographic data records

In this paper the peculiarities of compiled oceanographic data sets, which consist primarily in the presence of some characteristic information as well as in the planned incomplete filling of the files with observations, are discussed. A number of special ways are suggested which essentially improve the packing density of computerized data without applying special archiving algorithms. The effectiveness of these methods has been tested by treating thein situ hydrological/chemical data file compiled in the Black Sea in 1988.Translated by Vladimir A. Puchkin.     

China's population: an alternative perspective

The author presents a selection of cartograms designed to illustrate aspects of the demography of China. Topics covered include population growth, density, regional variations in fertility, and age distribution. A discussion of the advantages of using cartograms (maps drawn proportional to a given variable) as opposed to conventional, area-based maps, is included.     

The homologous flare events in solar active regions

This paper consists of two parts. We first discuss recent general results on the study of properties of flare homology, and their relevance to the physical interpretation of the flare phenomenon at large. We devote particular attention to the discovery of homologous flares which occur in rapid succession, within a few minutes of each other in many cases. We name these kind of flares rafales. These flares signal the existence of several episodes of energy release within the same magnetic configuration. We also show the existence of particular sites in the solar atmosphere which have peculiar characteristics in terms of solar rotation, and where recurrent flaring may take place over and over again in different solar rotations. This indicates that the disturbance causing the emergence of activity is deep seated, below the solar photosphere. Finally, in the second part, we discuss an extensive set of observations of two homologous flares of a rafale, stressing the dynamic aspects of the observations, particularly the presence of peaks in the vertical component of the velocity field. These results are shown to be in agreement with studies of filament activations and the surging arches which are observed before the flash phase of solar flares.     

Far beyond the Gulf: the implications of warfare for Asian labour migration

The implications of the Gulf War are assessed for the countries in Asia that send labor migrants to the Middle East. "This paper seeks to examine the effects of...the loss of remittances (and related issues, including return migration), primarily in terms of the long-term implications of the War for the future of contract labour migration in the Asian region...."     

Rosat wide field camera data and the temperature of the interstellar medium

The shadowing effects of the molecular clouds in the nearby interstellar medium on the soft x-ray background has been investigated, using ROSAT WFC data in conjunction with previous rocket B and C band surveys. Shadowing over a 5° extent occurs only for a few percent of the sky, but the mixed model of the ISM is supported.Detailed modelling of the Draco shadowing region shows little evidence for a multi-temperature, hot ISM component.     

The American whale oil industry: A look back to the future of the American petroleum industry?

The American whaling industry rose from humble beginnings off Long island to become an international giant. In its peak year, 1846, 735 ships and 70,000 people served the industry. As whale stocks and reserves decreased, whalers were forced to go farther and farther from their New England home ports. Voyages became longer, and risks on required return-on-investment became higher. The easy money of Atlantic and Pacific whaling was no more: the only remaining profitable ventures were to Arctic and Antarctic waters. Many ships returned empty, if at all. in 1871, most of the Arctic whaling fleet was crushed by early winter ice and lost. This calamity, in conjunction with the long-term diminishing whale stocks, the diversion of investment capital to more profitable ventures, and the discovery, development, and refinement of abundant petroleum crude oil, struck the death blow to the American whaling industry. By 1890, only 200 whaling vessels were at work, and by 1971, no American commercial whaling ship sailed the world's oceans.It is apparent that no single event caused the final, rapid decline. However, a single calamity, in an already stressed industry, that was self-insured and commercially interlinked, precipitated the end. Today's American petroleum industry, although adopting some principles of the American whaling industry, also has embraced other activities such as work process reengineering and customer alliances, which may preempt, or postpone, a similar catastrophic demise.