Thermodynamic controls on element partitioning between titanomagnetite and andesitic–dacitic silicate melts

Titanomagnetite–melt partitioning of Mg, Mn, Al, Ti, Sc, V, Co, Ni, Cu, Zn, Ga, Zr, Nb, Mo, Hf and Ta was investigated experimentally as a function of oxygen fugacity (fO₂) and temperature (T) in an andesitic–dacitic bulk-chemical compositional range. In these bulk systems, at constant T, there are strong increases in the titanomagnetite–melt partitioning of the divalent cations (Mg²⁺, Mn²⁺, Co²⁺, Ni²⁺, Zn²⁺) and Cu²⁺/Cu⁺ with increasing fO₂ between 0.2 and 3.7 log units above the fayalite–magnetite–quartz buffer. This is attributed to a coupling between magnetite crystallisation and melt composition. Although melt structure has been invoked to explain the patterns of mineral–melt partitioning of divalent cations, a more rigorous justification of magnetite–melt partitioning can be derived from thermodynamic principles, which accounts for much of the supposed influence ascribed to melt structure. The presence of magnetite-rich spinel in equilibrium with melt over a range of fO₂ implies a reciprocal relationship between a(Fe²⁺O) and a(Fe³⁺O_1.5) in the melt. We show that this relationship accounts for the observed dependence of titanomagnetite–melt partitioning of divalent cations with fO₂ in magnetite-rich spinel. As a result of this, titanomagnetite–melt partitioning of divalent cations is indirectly sensitive to changes in fO₂ in silicic, but less so in mafic bulk systems.     

Acid mine drainage at Cerro Rico de Potosí I: unabated high-strength discharges reflect a five century legacy of mining

Intensive mining and processing of Ag, Sn, Pb and Zn ores have occurred in various locations within and around the city of Potosí, Bolivia since 1545. Surface and subsurface waters, stream sediments and soils are contaminated with various ecotoxic metals in the headwaters of the economically vital, yet highly impacted, upper Rio Pilcomayo watershed. Previous studies have documented downstream trace metal contamination, however, not addressed specific sources. The AMD discharges identified in this study help link downstream pollution to primary origins. The majority of AMD would be considered high-strength due to metal concentrations and acidity orders of magnitude greater than typical AMD. Discharges from both operating and abandoned portals as well as tailings-related deposits displayed a high degree of heterogeneity with total metal concentrations ranging from 0.11 to 7480, <0.022 to 889, <0.0006 to 65.3, <0.001 to 310, 0.12 to 72,100, 0.3 to 402, <0.012 to 34.8, and 0.24 to 19,600 mg/L of Al, As, Cd, Cu, Fe, Mn, Pb and Zn, respectively. Net acidity and pH ranged from −10 to 246,000 mg/L as CaCO₃ equivalent and 0.90–6.94 standard units, respectively. Data were gathered during two sampling events centered around the most extreme periods of the dry and wet seasons of one water-year. Loadings to local streams were marginally greater for most metals in the wet season. If observed loadings are historically representative, Cerro Rico AMD has contributed thousands of tonnes of ecotoxic metals to the upper Rio Pilcomayo over the last five centuries. Metal and hydrogen ion concentrations in the majority of AMD sampled were several orders of magnitude above discharge limits set by the Bolivian government, yet no action has historically or contemporarily been taken.     

Central Europe: Active or residual tectonic stresses

The regional stress field in the Western Alps and their northern foreland has been investigated byin situ stress determinations. More than 600 strain relief measurements were made with resistance strain gages in boreholes carried out in mines, tunnels and quarries. The stresses calculated and data obtained from other papers were used to get a detailed idea of the stress conditions in Central Europe.The measurements confirm a continuous flux of compressive stress from the Alps to the northern foreland east of the Rhinegraben. The largest stresses are observed in the Central Alps, the lowest in the Rhinegraben rift system. The horizontal stresses exceed at nearly all places the vertical ones. Evidently the excess of horizontal stress is generated by active plate tectonics in the Alps. A tectonic model to explain the observed stress pattern is presented.     

The acute aquatic toxicity of some substances carried by ships

At the request of the International Maritime Organization (IMO), our laboratory has performed acute toxicity testing with 43 substances, for which insufficient or no data had been available for hazard rating concerning damage to marine living resources.     

Observations of rapid mean flow produced in mercury by a moving heater

Abstract

Experimental and theoretical results are described for the moving flame experiment, where a heat source moves under a horizontal, annular channel filled with liquid mercury. The physical range under discussion consists of the creep flow limit, in which inertial forces are less than viscous forces. A mean surface flow was observed on the mercury. This flow was up to four times greater than the heater speed, and in an opposite direction. The ratio of mean flow to heater speed was theoretically and experimentally found to be proportional to the square of the thermal amplitude, in agreement with a special limit of Davey's earlier results. The basic flow here, as contrasted to those flows analyzed by earlier theories, appears to be generated by surface tension. However, the Reynolds stress mechanism which generates the mean flow is the same. Some experimental flows were so rapid that the range of validity of the present, as well as some earlier theories, was exceeded. The present theory suggests that the higher order nonlinearities may have cancellative effects, which implies that the present and some earlier theories are valid beyond their normal range of validity.     

Meteor44 Video Meteor Photometry

Meteor44 is a software system developed at MSFC for the calibration and analysis of video meteor data. The photometric range of the (8 bit) video data is extended from a visual magnitude range of from 8 to 3 to from 8 to −8 for both meteors and stellar images using saturation compensation. Camera and lens specific saturation compensation coefficients are derived from artificial variable star laboratory measurements. Saturation compensation significantly increases the number of meteors with measured intensity and improves the estimation of meteoroid mass distribution. Astrometry is automated to determine each image's plate coefficient using appropriate star catalogs. The images are simultaneously intensity calibrated from the contained stars to determine the photon sensitivity and the saturation level referenced above the atmosphere. The camera's spectral response is used to compensate for stellar color index and typical meteor spectra in order to report meteor light curves in traditional visual magnitude units. Recent efforts include improved camera calibration procedures and long focal length "streak" meteor photometry. Meteor44 has been used to analyze data from the 2001, 2002 and 2003 MSFC Leonid observational campaigns as well as several lesser showers.     

Tropospheric Ozone in a Global-Scale Three-Dimensional Lagrangian Model and Its Response to NOX Emission Controls

A three-dimensional Lagrangian tropospheric chemistry modelis used toinvestigate the impact of human activities on the tropospheric distributionofozone and hydroxyl radicals. The model describes the behaviour of 50 speciesincluding methane, carbon monoxide, oxides of nitrogen, sulphur dioxide andnineorganic compounds emitted from human activities and a range of other sources.Thechemical mechanism involves about 100 chemical reactions of which 16 arephotochemical reactions whose diurnal dependence is treated in full. The modelutilises a five minute chemistry time step and a three hour advection timestepfor the 50,000 air parcels. Meteorological data for the winds, temperatures,clouds and so on are taken from the UK Meteorological Office global model for1994 onwards. The impacts of a 50% reduction in European NO_Xemissions onglobal ozone concentrations are assessed. Surface ozoneconcentrations decrease in summertime and rise in wintertime, but to differentextents.     

A NEW APPROACH TO THE INVERSION OF SEISMIC DATA*

A new inversion method for seismic reflection data is based on impedance concepts and uses transformations to reduce the essentially non-linear problem to a linear eigenvalue formulation without approximation. A set of reflection data has been inverted using this method. The characteristic impedances of the layers so determined are compared with log data from a reference borehole.     

Closed-form solution of P4P or the three-dimensional resection problem in terms of Möbius barycentric coordinates

 The perspective 4 point (P4P) problem - also called the three-dimensional resection problem - is solved by means of a new algorithm: At first the unknown Cartesian coordinates of the perspective center are computed by means of M?bius barycentric coordinates. Secondly these coordinates are represented in terms of observables, namely space angles in the five-dimensional simplex generated by the unknown point and the four known points. Substitution of M?bius barycentric coordinates leads to the unknown Cartesian coordinates (2.8)–(2.10) of Box 2.2. The unknown distances within the five-dimensional simplex are determined by solving the Grunert equations, namely by forward reduction to one algebraic equation (3.8) of order four and backward linear substitution. Tables 1.–4. contain a numerical example. Finally we give a reference to the solution of the 3 point (P3P) problem, the two-dimensional resection problem, namely to the Ansermet barycentric coordinates initiated by C.F. Gau? (1842), A. Schreiber (1908) and A.␣Ansermet (1910). Received: 05 March 1996; Accepted: 15 October 1996