Variations in the natural abundance of 15N in estuarine suspended particulate matter: A specific indicator of biological processing

In this study, the ¹⁴N:¹⁵N ratio of suspended particulate material collected from the Tamar river estuary, south-west England, is described. Three populations of particles, distinguishable by their ¹⁵N content, were observed. This investigation has shown that populations of estuarine particles are generated by biological transformations in situ and that the ¹⁵N content of estuarine particles does not merely reflect hydrodynamic mixing of the freshwater and seawater source particulate material.     

Acoustic oceanography by remote sensing

Ocean dynamical processes exist over a wide range of temporal and spatial scales. Remotely stationed acoustic devices are being used to "sense" the interior of the oceans at previously unattainable scales. The method is similar to computer-aided tomography (CAT) scans of the brain, but the measurement difficulties are far more severe. The results of a demonstration experiment are reviewed and some directions for acoustic oceanography are discussed.     

Deep-ocean piezometer probe technology for geotechnical investigations

Two single-sensor piezometer probes, 8 mm in diameter, were developed for deep-ocean geotechnical investigations. These probes were tested in a hyperbaric chamber pressurized to 55 MPa (8000 psi). Testing was performed for a period of five weeks under high hydrostatic pressure with the probes inserted in reconstituted illitic marine sediment. Small differential pore-water pressures were generated in response to both mechanically and thermally generated forcing functions. During deep-ocean simulated pressure tests, the sensors exhibited excellent sensitivity and stability. These developments in piezometer-probe technology provide a quantitative means of assessing important geotechnical parameters of fine-grained seabed deposits.     

Generalized strain probing of constitutive models

Advanced material constitutive models are used to describe complex soil behaviour. These models are often used in the solution of boundary value problems under general loading conditions. Users and developers of constitutive models need to methodically investigate the represented soil response under a wide range of loading conditions. This paper presents a systematic procedure for probing constitutive models. A general incremental strain probe, 6D hyperspherical strain probe (HSP), is introduced to examine rate‐independent model response under all possible strain loading conditions. Two special cases of HSP, the true triaxial strain probe (TTSP) and the plane‐strain strain probe (PSSP), are used to generate 3‐D objects that represent model stress response to probing. The TTSP, PSSP and general HSP procedures are demonstrated using elasto‐plastic models. The objects resulting from the probing procedure readily highlight important model characteristics including anisotropy, yielding, hardening, softening and failure. The PSSP procedure is applied to a Neural Network (NN) based constitutive model. It shows that this probing is especially useful in understanding NN constitutive models, which do not contain explicit functions for yield surface, hardening, or anisotropy. Copyright © 2004 John Wiley & Sons, Ltd.     

Theoretical accuracy of synthetic aperture sonar micronavigation using a displaced phase-center antenna

The Cramer-Rao lower bounds on the cross-track translation and rotation of a displaced phase-center antenna (DPCA) in the slant range plane between two successive pings (known as DPCA sway and yaw in what follows) are computed, assuming statistically homogeneous backscatter. These bounds are validated using experimental data from a 118-182-kHz sonar, showing an accuracy of the order of 20 microns on the ping-to-ping cross-track displacements. Next, the accuracy required on the DPCA sway and yaw in order to achieve a given synthetic aperture sonar (SAS) beampattern specification, specified by the expected SAS array gain, is computed as a function of the number P of pings in the SAS. Higher accuracy is required when P increases to counter the accumulation of errors during the integration of the elementary ping-to-ping estimates: the standard deviation must decrease as P/sup -1/2/ for the DPCA sway and P/sup -3/2/ for the yaw. Finally, by combining the above results, the lower bounds on DPCA micronavigation accuracy are established. These bounds set an upper limit to the SAS length achievable in practice. The maximum gain Q in cross-range resolution achievable by a DPCA micronavigated SAS is computed as a function of the key SAS parameters. These theoretical predictions are compared with simulations and experimental results.     

Metamorphism in Archaean greenstone belts: calculated fluid compositions and implications for gold mineralization

An inescapable consequence of the metamorphism of greenstone belt sequences is the release of a large volume of metamorphic fluid of low salinity with chemical characteristics controlled by the mineral assemblages involved in the devolatilization reactions. For mafic and ultramafic sequences, the composition of fluids released at upper greenschist to lower amphibolite facies conditions for the necessary relatively hot geotherm corresponds to those inferred for greenstone gold deposits (X_CO2= 0.2–0.3). This result follows from the calculation of mineral equilibria in the model system CaO–MgO–FeO–Al₂O₃–SiO₂–H₂O–CO₂, using a new, expanded, internally consistent dataset. Greenstone metamorphism cannot have involved much crustal over-thickening, because very shallow levels of greenstone belts are preserved. Such orogeny can be accounted for if compressive deformation of the crust is accompanied by thinning of the mantle lithosphere. In this case, the observed metamorphism, which was contemporaneous with deformation, is of the low-P high-T type. For this type of metamorphism, the metamorphic peak should have occurred earlier at deeper levels in the crust; i.e. the piezothermal array should be of the ‘deeper-earlier’type. However, at shallow crustal levels, the piezothermal array is likely to have been of ‘deeper-later’type, as a consequence of erosion. Thus, while the lower crust reached maximum temperatures, and partially melted to produce the observed granites, mid-crustal levels were releasing fluids prograde into shallow crustal levels that were already retrograde. We propose that these fluids are responsible for the gold mineralization. Thus, the contemporaneity of igneous activity and gold mineralization is a natural consequence of the thermal evolution, and does not mean that the mineralization has to be a consequence of igneous processes. Upward migration of metamorphic fluid, via appropriate structurally controlled pathways, will bring the fluid into contact with mineral assemblages that have equilibrated with a fluid with significantly lower X_CO2. These assemblages are therefore grossly out of equilibrium with the fluid. In the case of infiltrated metabasic rocks, intense carbonation and sulphidation is predicted. If, as seems reasonable, gold is mobilized by the fluid generated by devolatilization, then the combination of processes proposed, most of which are an inevitable consequence of the metamorphism, leads to the formation of greenstone gold deposits predominantly from metamorphic fluids.     

Dissolution and depletion of ferromagnesian minerals from Holocene tephra layers in an acid bog,New Zealand,and implications for tephra correlation

This study examines the depletion of ferromagnesian silicate minerals from a sequence of thin, distal, mainly rhyolitic tephra layers of Holocene age preserved in an acid peat bog (Kopouatai), North Island, New Zealand. The rate of such depletion has been fast, as indicated by the complete loss of biotite from one tephra layer (Kaharoa Tephra), in which it is normally dominant, in only ca. 770 yr. Chemical dissolution is advocated as the likely cause for the depletion, with amphiboles and other mineral grains commonly showing etch pits, microcaves, and other characteristic surface solution features. Theoretical thermodynamic and kinetic models show a marked increase in the rate of dissolution of all ferromagnesian minerals under conditions of low pH (< 4), but that where silica concentrations in solution are high the relative proportions of minerals remaining are unaffected. However, where concentrations of dissolved silica are low, as in most bog environments, the relative proportions of ferromagnesian minerals are affected as well as absolute amounts being decreased. Amphiboles are depleted relative to pyroxenes, consistent with kinetic studies. The results show that the identification and correlation of tephras on the basis of relative abundances of ferromagnesian minerals alone may be unreliable, and emphasise the need to use multiple criteria in such studies.     

Response of circular footings and anchor plates in non-homogeneous elastic soils

The axisymmetric elastic response of circular footings and anchor plates in a linearly non-homogeneous elastic soil is analysed. It is assumed that footings/anchors are flexible and subjected to axisymmetric vertical loads. The response of the footing/anchor is modelled by using the classical Poisson–Kirchhoff thin plate theory. A variational technique is used to analyse the interaction problem. A representation for the contact stress is established by using a fundamental solution corresponding to a unit vertical pressure acting over an annular region in the interior of the non-homogeneous soil. The fundamental solution can be derived by using rigorous analytical procedures. The influence of the footing flexibility and the degree of soil non-homogeneity on the displacements, bending moments and contact stresses of a surface footing is examined over a wide range of governing parameters. In the case of anchor plates the influence of depth of embedment, degree of soil non-homogeneity and anchor flexibility on the anchor displacement is investigated.     

A high resolution,multiproxy Late‐glacial record of climate change and intrasystem responses in northwest England

A lacustrine carbonate sequence from Hawes Water, Lancashire, UK, has been studied using stable isotopic, lithological, pollen and mineral magnetic analysis. The data reveal four abrupt climatic oscillations in the Late‐glacial Interstadial leading up to the onset of the Loch Lomond Stadial. The data also point to climatic warming relatively early within the stadial, ca. 12 500 GRIP yr, prior to the onset of the Holocene. The oxygen isotope record is taken as a signature of climate forcing against which the response of the lake‐system can be monitored. By adopting this approach it is revealed that the response of the biological system to the rapid climatic oscillations is non‐linear and primarily a function of the antecedent conditions. A significant end‐Devensian isotopic excursion (A) is matched by only minor changes in the cold‐adapted floras and faunas. During the warmer interstadial, the response of the biological ecosystem (events B–D) is clearly influenced by thresholds: major changes in the catchment vegetation associated with relatively minor oscillations in the isotopic signature. The stratigraphical patterns reveal significant lag effects between the onset of climate deterioration and resulting changes in vegetation. Copyright © 2002 John Wiley & Sons, Ltd.     

A sapphirine–phlogopite–cordierite paragenesis in a low-P amphibolite facies terrain, Arunta Inlier, Australia

Summary Silica-undersaturated phlogopite schists from the Cackleberry Metamorphics, Arunta Inlier, central Australia, preserve relatively low-temperature sapphirine-bearing parageneses that developed during low-pressure upper amphibolite facies metamorphism. Peak metamorphic phlogopite–cordierite–sapphirine assemblages are interpreted to have formed during the same event recorded in nearby metapelites, at c.3 kbar and 650–700 °C. Initial cooling of the terrain resulted in the breakdown of sapphirine to corundum–chlorite–phlogopite and corundum–spinel–chlorite assemblages. Further retrogression at greenschist facies conditions resulted in the replacement of sapphirine by diaspore–chlorite intergrowths. The reaction textures are consistent with a near-isobaric heating-cooling path at low-pressure, and provide evidence for the stability of sapphirine at c.700 °C at low pressures in rocks of an appropriate Mg- and Fe³⁺-rich bulk composition. Received August 15, 2001 accepted December 27, 2001