Evidence for the loss of snow-deposited MSA to the interstitial gaseous phase in central Antarctic firn

We have examined several MSA (methanesulfonic acid) records from the upper 200 m of the Antarctic ice sheet and in particular the new Dome F profile. At all the four sites studied, concentration profiles exhibit similar patterns as a function of depth. They suggest that snow metamorphism and solid phase migration are responsible for a marked release of gaseous MSA to interstitial firn air as well as probably to the free atmosphere, in particular at extremely low accumulation sites. Snow acidity can also modify MSA concentration. It is proposed that, below the upper few metres where the communication with the free atmosphere is possible, gaseous MSA may remain in the firn layers and be entrapped later in air bubbles at pore close-off, i.e. when firn is transformed into ice. Chemical measurements on the firn core do not take into account the MSA released to the gaseous phase, but this fraction is measurable in ice samples. In spite of these alterations occurring in the firn layers, relative changes of the atmospheric MSA concentration in the past are probably still there deep within the Antarctic ice sheet. However, for glacial periods, different processes have to be considered in relation to modified aerosol properties.     

Bond rolling resistance and its effect on yielding of bonded granulates by DEM analyses

A discrete element modelling of bonded granulates and investigation on the bond effect on their behaviour are very important to geomechanics. This paper presents a two‐dimensional (2‐D) discrete element theory for bonded granulates with bond rolling resistance and provides a numerical investigation into the effect of bond rolling resistance on the yielding of bonded granulates. The model consists of mechanical contact models and equations governing the motion of bonded particles. The key point of the theory is that the assumption in the original bond contact model previously proposed by the authors (55th CSCE‐ASCE Conference, Hamilton, Ont., Canada, 2002; 313–320; J. Eng. Mech. (ASCE) 2005; 131 (11):1209–1213) that bonded particles are in contact at discrete points, is here replaced by a more reliable assumption that bonded particles are in contact over a width. By making the idealization that the bond contact width is continuously distributed with the normal/tangential basic elements (BE) (each BE is composed of spring, dashpot, bond, slider or divider), we establish a bond rolling contact model together with bond normal/tangential contact models, and also relate the governing equations to local equilibrium. Only one physical parameter β needs to be introduced in the theory in comparison to the original bond discrete element model. The model has been implemented into a 2‐D distinct element method code, NS2D. Using the NS2D, a total of 86 1‐D, constant stress ratio, and biaxial compressions tests have been carried out on the bonded granular samples of different densities, bonding strengths and rolling resistances. The numerical results show that: (i) the new theory predicts a larger internal friction angle, a larger yielding stress, more brittle behaviour and larger final broken contact ratio than the original bond model; (ii) the yielding stress increases nonlinearly with the increasing value of β, and (iii) the first‐yield curve (initiation of bond breakage), which define a zone of none bond breakage and which shape and size are affected by the material density, is amplified by the bond rolling resistance in analogous to that predicted by the original bond model. Copyright © 2006 John Wiley & Sons, Ltd.     

Modelling of deformation response and chemo‐mechanical coupling in chalk

A constitutive relation is derived for describing the mechanical response of chalk. The approach is based on a phenomenological framework which employs chemo‐plasticity. The properties of the material are assumed to be affected by the physico‐chemical processes that occur through the interaction between the skeleton and the pore fluid. The underlying mechanism is discussed by invoking a micromechanical analysis. The performance of the framework is illustrated by examining the evolution of mechanical characteristics in the presence of different pore fluids. Copyright © 2006 John Wiley & Sons, Ltd.     

The Electron Energy Spectrum from Large Solar Flares

We report on the differential electron spectrum for intense transient events seen at one AU by the EPAM instrument on the Advanced Composition Explorer (ACE) spacecraft. Over an observing period from September 1997 to September 2005, there were 45 major events that could be reliably identified with a source flare on the Sun. In the ∼40 – 300 keV energy range, the electron spectral index was between one and three for all but two of the events. Twenty-five of the events were associated with Geostationary Operational Environmental Satellites (GOES) X-ray class X flares. We compare this result with the spectral index measured from electron pulse events, lasting approx. one hour or less, where the spectral index is typically much softer than three. This suggests that the measured spectral index of near-relativistic electrons at one AU may be a reliable indicator of the source. We also examine the likelihood that fast coronal mass ejections (CMEs) are responsible in themselves for accelerating near-relativistic electrons and conclude that they do not.     

A major sulphur isotope event at c. 510 Ma: a possible anoxia–extinction–volcanism connection during the Early–Middle Cambrian transition?

A new approach to constraining seawater δ³⁴S and sulphate concentration using francolite‐bound sulphate reveals an abrupt increase in δ³⁴S to +50‰ around the Early–Middle Cambrian boundary. Such high δ³⁴S values are best explained by increased rates of pyrite burial due to ocean anoxia coupled with an increased sensitivity of the ocean sulphate reservoir to perturbations due to low sulphate concentrations of 500–700 μgL^?1. We argue that the spread of anoxic waters at this time was partly the result of greenhouse warming related to the eruption of the Kalkarindji Large Igneous Province of northern Australia and that it triggered the collapse of early metazoan reef ecosystems during the latest Early Cambrian. Mass extinctions of the last 260 Myr have all coincided with enhanced volcanic activity, while several are also associated with positive shifts in seawater δ³⁴S. Extending this correlation back in time further implicates volcanically induced climate change as a major determining factor in biosphere evolution. Terra Nova, 18, 257–263, 2006     

Effect of the star limb darkening law on the probabilities of discovering detached close binary stars as eclipsing variables

The probabilities of discovering detached close binary (type DM) stars as eclipsing variables are calculated as a function of the mass of the main component, mass ratio, major semiaxis, and angle of inclination of the orbit. The case of total limb darkening (hypothesis “D”) is examined. This is compared with earlier results for uniformly bright stellar disks (hypothesis “U”). Based on data from Svechnikov and Kuznetsova’s Catalog of Approximate Photometric and Absolute Elements of Eclipsing Variables, the spatial density of stars of this type in the neighborhood of the sun is estimated to be ≈ 460 · 10 ⁻⁶ pc⁻³. __________ Translated from Astrofizika, Vol. 49, No. 1, pp. 151–169 (February 2006).     

Understanding the behavior of Prometheus and Pandora

We revisit the dynamics of Prometheus and Pandora, two small moons flanking Saturn's F ring. Departures of their orbits from freely precessing ellipses result from mutual interactions via their 121:118 mean motion resonance. Motions are chaotic because the resonance is split into four overlapping components. Orbital longitudes were observed to drift away from predictions based on Voyager ephemerides. A sudden jump in mean motions took place close to the time at which the orbits' apses were antialigned in 2000. Numerical integrations reproduce both the longitude drifts and the jumps. The latter have been attributed to the greater strength of interactions near apse antialignment (every 6.2 yr), and it has been assumed that this drift-jump behavior will continue indefinitely. We re-examine the dynamics of the Prometheus-Pandora system by analogy with that of a nearly adiabatic, parametric pendulum. In terms of this analogy, the current value of the action of the satellite system is close to its maximum in the chaotic zone. Consequently, at present, the two separatrix crossings per precessional cycle occur close to apse antialignment. In this state libration only occurs when the potential's amplitude is nearly maximal, and the “jumps” in mean motion arise during the short intervals of libration that separate long stretches of circulation. Because chaotic systems explore the entire region of phase space available to them, we expect that at other times the Prometheus-Pandora system would be found in states of medium or low action. In a low action state it would spend most of the time in libration, and separatrix crossings would occur near apse alignment. We predict that transitions between these different states can happen in as little as a decade. Therefore, it is incorrect to assume that sudden changes in the orbits only happen near apse antialignment.     

The size distribution of trans-Neptunian bodies

The magnitude distribution of the trans-Neptunian bodies composed of the Kuiper Belt Objects (KBOs) and Scattered Disk Objects (SDOs) is determined for absolute magnitudes H?7, using maximum likelihood estimation methods. This is translated into a corresponding size distribution. This gave a differential size index of q=3.966±0.15 for KBOs and q=3.016±0.32 for SDOs. It was found that these two distributions were statistically different. The KBOs were further split into classical KBOs and Plutinos which had indices of q=4.074±0.18 and q=3.301±0.37, respectively. There was no statistical evidence that these are different populations. The classical KBOs were further split and examined for four different semi-major axis ranges and it was found that there was moderate evidence that the entire sample was not well represented by one index. The distribution indices of the SDOs were compared with the distributions of short period comets and found to be similar. It is likely that the scattered disk population is the source of the short period comets.