Fluid production and isograd reactions at contacts of carbonate-rich and carbonate-poor layers during progressive metamorphism

ABSTRACT With increasing temperature during prograde metamorphism reactions will occur first at the lithological contacts of mixed pelite and calcsilicate terranes. At these interfaces, a fluid of lower chemical potential of H₂O and CO₂ than that required to produce a fluid in either layer can be produced whether reaction is caused by fluid infiltration or is initially fluid absent. If the interface region does not allow fluid transport then as temperature increases, a fluid pressure greater than lithostatic can develop. At some degree of over-pressure relative to rock pressure, the fluid hydraulically fractures the rock and a gradient in fluid composition away from the contact can be produced. These phenomena occur at the compositional interfaces whenever univariant reactions in the differing layers cross on a temperature vs. mole fraction of CO₂ diagram with slopes of opposite sign. The first occurrence of these reaction products at lithological contacts delineates an isograd that defines temperature as well as the mole fraction of CO₂ at constant pressure in systems open to fluid transport. These isograds can be contrasted with fluid-producing isograds in closed systems. As an illustration of possible effects, the reactions quartz + clinozoisite + muscovite = anorthite + K-feldspar + H₂O and phlogopite + quartz + calcite = tremolite + K-feldspar + H₂O + CO₂ at 4 kbar are analysed and equations for fluid production and transport are developed.     

Climatic changes in central and eastern Canada inferred from deep borehole temperature data

We analyzed data from 23 boreholes at 19 sites in central and eastern Canada, for the purpose of estimating ground surface temperature (GST) histories. These boreholes were logged down to at least 550 m depth with thermistor probes. Thermal conductivity measurements had been previously made at small depth intervals for the entire depth ranges of most of the boreholes. The temperature profiles of these boreholes do not indicate water disturbance. We estimated terrain effects for each borehole using a time dependent solid-angle method. The thermal perturbations caused by lakes or deforestation near the borehole sites are insignificant in most cases. However, four of the holes were found to be severely influenced by terrain effects. GSTs estimated from the borehole data less influenced by the terraineffects form two groups. The first group, which are generally from data of better quality, show a cold period near the end of the last century before the recent warming trend; the second show it 80–100 years earlier. We consider the former typical of the climate of the Boreal climatic region of Canada. The difference between the two groups may reflect the spacial variability of the climate. Four GST estimates do not belong to either type, and the reasons are discussed.     

SHRIMP U–Pb ages of diagenetic and hydrothermal xenotime from the Archaean Witwatersrand Supergroup of South Africa

SHRIMP dating of xenotime overgrowths on detrital zircon grains can constrain maximum durations since diagenesis and therefore provide minimum dates of sediment deposition. Thus, xenotime dating has significant economic application to Precambrian sediment-hosted ore deposits, such as Witwatersrand Au–U, for which there are no precise depositional ages. The growth history of xenotime in the Witwatersrand Supergroup is texturally complex, with several phases evident. The oldest authigenic xenotime ²⁰⁷Pb/²⁰⁶Pb age obtained in sandstone underlying the Vaal Reef is 2764 ± 5 Myr (1 σ), and most likely represents a mixture of diagenetic and hydrothermal growth. Nevertheless, this represents the oldest authigenic mineral age yet recorded in the sequence and provides a minimum age of deposition. Other xenotime data record a spread of ages that correspond to numerous post-diagenetic thermotectonic events (including a Ventersdorp event at ≈ 2720 Ma) up to the ≈2020 Ma Vredefort event.     

The mass ratio of Nova Muscae 1991

We report intermediate resolution H spectroscopy of the black hole candidate Nova Muscae 1991 during quiescence. We classify the companion star as a K3-K4V which contributes 85±6 percent to the total flux from the binary. The photospheric absorption lines are broadened by 106±13 kms⁻¹ with respect to template field stars, leading to a system mass ratio of q =M₁/M₂ = 7.8_−2.0^+3.4. Doppler imaging of the H line shows strong emission coming from the secondary star (EW=3.1±0.6Å) which we associate with chromospheric activity. However, the hot-spot is not detected and this may indicate a lower mass transfer rate than in other X-ray transients of comparable orbital periods. The surface brightness distribution of the accretion disk in H follows a relation I∝R^−1.1, less steep than typically observed in cataclysmic variables. Updated system parameters are also presented.     

Dynamics of the Nuclear Outflow in NGC 1068

A short survey is presented of dynamical (and thermodynamical) issues relevant to outflows in Seyfert galaxies like NGC 1068. Numerical simulations incorporating both realistic radiative heating and cooling, and angular momentum, show that the fraction of injected gas which escapes in a wind is very sensitive to both the injection pressure and the gas's angular momentum. Radiation pressure acting through a variety of atomic opacity processes may also be important. This revised version was published online in July 2006 with corrections to the Cover Date.     

Relaxation of the Vela pulsar’s angular velocity following its jumps

The dynamics of the vortex lattice in the inner crust of a neutron star is considered. A general equation of motion is obtained and solved under the assumption that there are regions of pinned and of free vortices. By comparing these solutions with observational data for the Vela pulsar, the relative moments of inertia of regions of relaxation with the corresponding characteristic times are calculated for two model stars with different equations of state. It is shown that the theory can be reconciled with observations of the relaxation of pulsar angular velocity only for model stars with extremely stiff equations of state. Translated from Astrofizika, Vol. 40, No. 1, pp. 67–76, January–March, 1997.     

Modelling Gas And Dust Release From Comet Hale–Bopp

Numerical simulations of the evolving activity of comet Hale-Bopp are presented, assuming a porous, spherical nucleus, 20 km in radius, made of dust and gas-laden amorphous ice. The main effects included are: crystallization of amorphous ice and release of occluded gas, condensation, sublimation and flow of gases through the pores, changing pore sizes, and flow of dust grains. The model parameters, such as initial pore size and porosity, emissivity, dust grain size, are varied in order to match the observed activity. In all cases, a sharp rise in the activity of the nucleus occurs at a large heliocentric distance pre-perihelion, marked by a few orders of magnitude increase in the CO and the CO₂ fluxes and in the rate of dust emission. This is due to the onset of crystallization, advancing down to a few meters below the surface, accompanied by release of the trapped gases. A period of sustained, but variable, activity ensues. The emission of water molecules is found to surpass that of CO at a heliocentric distance of 3 AU. Thereafter the activity is largely determined by the behaviour of the dust. If a dust mantle is allowed to build up, the water production rate does not increase dramatically towards perihelion; if most of the dust is ejected, the surface activity increases rapidly, producing a very bright comet. This revised version was published online in July 2006 with corrections to the Cover Date.