Stable isotope study of base metal deposits from the Eastern High Atlas,Morocco

Tertiary epigenetic lead ± zinc and copper mineralizations occur in the Mesozoic carbonate cover and stibnite, barite and copper mineralization in the Precambrian to Palaezoic basement in the Eastern High Atlas, Morocco. The carbon isotope data from host carbonates range from +3 to -1‰ PDB. The data are typical for marine carbon. There is no difference between surrounding dolomites and younger vein dolomites. The oxygen isotopic composition of the samples is enriched in ¹⁶O; the range is from -3 to -11‰ PDB with respect to that of carbonates in equilibrium with marine water. It is postulated that the isotopic composition was changed during dolomitization being caused by transition of connate formation waters diluted to some degree by meteoritic water. The bacteriogenically reduced sulphur from syngenetic sulphides and Mesozoic marine sulphate mobilized during Tertiary orogenesis are thought to be the source of H₂S and SO₄. Cambro-Ordovicien sulphate is also supposed to be the source of sulphur in the Jebel Zelmou barite deposit in the basement. Isotopic composition of lead from galenas in the Tertiary deposits from the Mesozoic cover are strikingly homogenous. Model ages vary between 230–180 Ma. It is suggested that important mobilization processes are responsible for Tertiary metallogeny in Morocco.

     

Lymanα forests and the evolution of the universe

The Lyα forest absorption lines in the spectra of quasars are interpreted as caused by the crossings of the light beam with the walls of a bubble structure (expanding with the Hubble flow only). Then, the typical separation between the absorption lines is proportional to the mean size of the bubbles. The variable factor is the expansion rate H[z]. The Friedmann regression analysis of the observed line separations determines the density parameter ω₀ and the normalized cosmological term λ₀ = λc²/3H²₀ of the appropriate cosmological model: ω₀ = 0.014 ± 0.002, λ₀ = 1.080 ± 0.006. Depending on the Hubble parameter this method reveals the values of the present mean matter density pm,0 = 2.6 h² · 10⁻²⁸ kg m⁻³ and of the cosmological constant Λ = 3.77 h² · 10⁻⁵² m⁻² (with h = H₀/(100 km/s·Mpc)). According to our analysis all models with Λ = 0 must be excluded. The curvature of space is positive. The curvature radius R₀ is 3.3 times the Hubble radius (c/H₀). The age t₀ is 2.8 times the Hubble age (H₀⁻¹).     

High-resolution ion-microprobe measurement of lead isotopes: Variations within single zircons from Lac Seul,northwestern Ontario

Selected-area measurements of lead-isotope ratios in zircons have been made at high mass resolution using a modified A.E.I. IM20 ion-microprobe. At a working resolution of 3200 it is shown that the important interfering molecular peaks generated from the zircon matrix may be separated from atomic lead peaks. Corrections for overlapping peaks, which are necessary in measurements of lead isotopes at low mass resolution, are then only required for ²⁰⁸Pb.Measurements on N.B.S. standards show no isotope discrimination within counting statistics. Determination of ²⁰⁷Pb/²⁰⁶Pb on 29 single zircon grains from a tonalite gneiss and a granite from Lac Seul, northwestern Ontario, give very variable ratios with mean values close to those of bulk separates. Peaks in the distribution of 207/206 ratios obtained from the tonalite gneiss may be interpreted as evidence for two stages of lead loss. High 207/206 ratios are shown to be significant for at least two zircons and probably record a minimum age of formation of 3.3 ± 0.1 b.y. for the gneiss.     

Observations of the structure and evolution of solar flares with a soft X-ray telescope

132 soft X-ray flare events have been observed with The Aerospace Corporation/Marshall Space Flight Center S-056 X-ray telescope that was part of the ATM complement of instruments aboard Skylab. Analyses of these data are reported in this paper. The observations are summarized and a detailed discussion of the X-ray flare structures is presented. The data indicated that soft X-rays emitted by a flare come primarily from an intense well-defined core surrounded by a region of fainter, more diffuse emission. Loop structures are found to constitute a fundamental characteristic of flare cores and arcades of loops are found to play a more important role in the flare phenomena than previously thought. Size distributions of these core features are presented and a classification scheme describing the brightest flare X-ray features is proposed. The data show no correlations between the size of core features and: (1) the peak X-ray intensity, as indicated by detectors on the SOLRAD satellite; (2) the rise time of the X-ray flare event, or (3) the presence of a nonthermal X-ray component. An analysis of flare evolution indicates evidence for preliminary heating and energy release prior to the main phase of the flare. Core features are found to be remarkably stable and retain their shape throughout a flare. Most changes in the overall configuration seem to be the result of the appearance, disappearance or change in brightness of individual features, rather than the restructuring or re-orientation of these features. Brief comparisons with several theories are presented.     

An assessment of geologic sequestration potential in the panhandle of Florida USA

One alternative to reduce global greenhouse gas emissions is to store the emissions in underground geologic sequestration repositories. The efficacy of this approach has been favorably evaluated by numerous authors over the last 15 years. This paper discusses an assessment of the overall feasibility of storing emissions in three different repositories in the Florida panhandle located in the Southeastern United States. The feasibility assessment evaluates both saline aquifers and oil reservoirs located in the panhandle region. The overall feasibility is driven by the available geologic sequestration capacity, the transportation cost to deliver emissions to a respective repository, and other engineering and regulatory issues. The geologic sequestration capacity is generally controlled by the so-called storage efficiency, a variable dependent on the site-specific geology, reservoir conditions, and the injected fluid characteristics. For this paper, storage efficiency for saline repositories was assessed in more detail using numerical modeling. Based on the work completed, the 3 repositories studied have at least 4.55 gigatonnes of capacity to sequester CO₂.     

Correlation of T-log with E-log in coal-bearing formations

The profile of temperature gradient versus depth (T-log) has been found to be very useful for correlation with electrical resistivity log (E-log) in coal-bearing formations. A positive correlation between electrical resistivity and thermal resistivity is observed in coal sections whereas a negative correlation is found in sandstone/shale beds, thus helping in coal prospect evaluation. T logs have been used to correct the location of coal bed which had apparently been misinterpreted by the E-log. Hole to hole correlation of T-log and E-log is found to be excellent and it is observed that thermal resistivity characteristics of given formations remain fairly uniform. A rough estimation of coal grade is possible from the detailed study of the T-logs. Abrupt changes of temperature gradient as also its reversals have been observed in burnt coal sections.     

Simulating the moderating effect of a lake on downwind temperatures

A steady-state, two-dimensional numerical model is used to simulate air temperatures and humidity downwind of a lake at night. Thermal effects of the lake were modelled for the case of moderate and low surface winds under the cold-air advective conditions that occur following the passage of a cold front. Surface temperatures were found to be in good agreement with observations. A comparison of model results with thermal imagery indicated the model successfully predicts the downwind distance for which thermal effects due to the lake are significant.     

The measurement and extraction of the <nu>6 atmospheric emission band of CFC-12 from interfering emission features

Ground-based thermal emission measurements of the zenith sky have been made at Peterborough, Ontario since January 1993. In this paper, the measurement of the ₆ band of atmospheric CFC-12, an important greenhouse gas, is presented for a cold, clear day in January 1994. A spectrum of the non-CFC-12 emission features has been simulated using the FASCD3P radiation code and measured radiosonde profiles of temperature, pressure and humidity. This has enabled a satisfactory subtraction of the interfering emission features from the CFC-12 emission spectrum. A comparison of the observed and simulated ₆-bands of CFC-12 shows good agreement at all frequencies of emission. From these spectra the total downward greenhouse radiative flux from the CFC-12 ₆ emission based for a very cold day has been estimated to be 0.27 W m⁻²±10%.     

Geochronology of anthropogenic pollutants in riparian wetland sediments of the Lippe River (Germany)

Anthropogenic pollutants were determined in a dated sediment core, collected from a riparian wetland of the Lippe River (Ruhr district, Germany). The historical trend in heavy metals, polycyclic aromatic hydrocarbons, organochlorines, polychlorinated biphenyls and linear alkylbenzenes as well as more recent contaminants such as industrial additives, organotins, synthetic musks, methyltriclosan and some other compounds were determined for the time period between 1930 and 1986. Emission sources, information on technical production and usage, as well as on the individual pollution pathways, with appropriate environmental stability, were considered in the interpretation of the sediment contamination over the past 50 years.Contaminants were analysed and interpreted according to two different criteria: (a) the origin of the main contaminants as related to mining and industrial activities as well as municipal sewage and agricultural effluents and (b) the pollution history. Due to a significant appearance of formerly missing contaminants in sediments deposited since 1970, we suggest classifying contaminants as either common (predating 1970) or modern (postdating 1970).In summary, the study provided a comprehensive reconstruction of the pollution history of the Lippe River system.