New compositional and optical data for antimonian and bismuthian varieties of hemusite from Japan

Summary New compositional and optical data are reported for antimonian and antimonianbismuthian varieties of hemusite from epithermal Au-Ag-Cu deposits in Japan. The empirical formula for the antimonian variety, from the Iriki mine is: (Cu_5.83Fe_0.14Ag_0.01)_5.98Mo_1.03(Sn_0.54Sb_0.41Te_0.03Bi_0.02)_1.00(S_7.85Se_0.15)_8.00, and that of the Sb-Bi variety from the Kawazu mine is: (Cu_5.84Fe_0.14Ag_0.01)_5.99Mo_1.03(Sn_0.82Sb_0.11Bi_0.l0Te_0.04)_1.07(S_7.80Se_0.12)_7.92. The theoretical formula of hemusite is Cu⁺ ₄Cu²⁺ ₂MO⁴⁺Sn⁴⁺S₈, whilst the most probable formula of the Iriki hemusite is Cu⁺ _4.5CU²⁺ _1.5Mo⁴⁺Sn⁴⁺ _0.5Sb⁵⁺ _0.5S₈, with Sb⁵⁺ substituting for Sn⁴⁺ and forming (SbS₄)^3– tetrahedra as might be expected, given that the metal to sulphur ratio is 1, and given the sphalerite-like structure of the mineral. However Bi³⁺ cannot be so accommodated, resulting in a deficiency in (S + Se) for Kawazu hemusite. Reflectance spectra for both are compared with those of the tungsten analogue (compositional) of hemusite, kiddcreekite. The relationship between hemusitesensu stricto and these newly reported varieties is discussed in terms of simple and coupled chemical substitutions, and inferences are drawn on the valency of Sb, Bi, Mo and Cu in the hemusite structure.

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Neue chemische und optische Daten für antimon- und bismuthführende Varietäten von Hemusit aus Japan

Zusammenfassung Neue chemische und optische Daten für antimon- und bismuthführende Hemusite auf epithermalen Au-Ag-Cu Lagerstätten in Japan werden vorgelegt. Die empirische Formel für die antimon-führende Varietät aus der Iriki-Mine ist: (Cu_5.83Fe_0.14Ag_0.01)_5.98Mo_1.03(Sn_0.54Sb_0.41Te_0.03Bi_0.02)_1.00 (S_7.85Se_0.15)_8.00, und die der Sb-Bi Varietät aus der Kawazu Mine ist: (Cu_5.84Fe_0.14Ag_0.01)_5.99M0_1.03(Sn_0.82Sb_0.11Bi_0.l0Te_0.04)_1.07 (S_7.80Se_0.12)_7.92. Die theoretische Formel von Hemusit ist Cu⁺ ₄Cu²⁺ ₂Mo⁴⁺Sn⁴⁺S₈, während die wahrscheinlichere Formel für den Hemusit von Iriki Cu⁺ ₄Cu²⁺ _1.5Mo⁴⁺Sn⁴⁺ _0.5Sb⁵⁺ _0.5S₈, mit Sb⁵⁺ an der Stelle von Sn⁴⁺, das(SbS₄)^3– Tetraeder bildet, wie zu erwarten ist, unter der Voraussetzung, da das Metall zu Schwefelverhältnis 1 und die Struktur sphaleritähnlich ist. Bi³⁺ kann jedoch nicht in dieser Weise untergebracht werden, und das führt zu einem Mangel an (S + Se) für den Hemusit von Kawazu. Die Reflektions-Spektren beider Minerale werden mit denen des Wolfram-Equivalents von Hemusit (Kiddcreekit) verglichen. Die Beziehung zwischen Hemusitsensu stricto und diesen jetzt beschriebenen Varietäten wird auf der Basis einfacher und gekoppelter chemischer Substitution diskutiert. Auf dieser Basis werden Schlüsse auf die Valenz von Sb, Bi Mo und Cu in der Hemusit-Struktur gezogen.

     

The structural state of the former lower continental crust in Calabria (S. Italy)

In the Northern Serre (S. Italy), a continuous section through a former lower continental crust is exposed (Schenk 1984, 1985). These granulite facies rocks have not been penetratively deformed during their uplift to higher crustal levels. Therefore, they allow to study the structural state of the lower continental crust. Most rockforming minerals, among them ortho- and clinopyroxene and cordierite, show recrystallization structures. Quarz basal subgrain boundaries are developed in lower levels of the lower crust and disappear toward higher levels. In addition to dimensional orientations of the rockforming minerals, the preferred crystallographic orientations of plagioclases, cordierite, amphibole, pyroxenes and, rarely, quartz reflect the strain orientation of the prograde high-T deformation. During this deformation, the stretching direction was constant NNE-SSW throughout the exposed lower crustal section. Shear indicators are rare. This points to the fact that deformation has been homogeneous and coaxial flattening. There is only a small variation in orientation and strength of textures throughout the exposed lower crust. Therefore, neighbouring layers of different composition rather than different deformation might serve as seismic reflectors in the former lower crust.

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Zusammenfassung In der nördlichen Serre (Süditalien) ist ein zusammenhängender Bereich einer ehemaligen kontinentalen Unterkruste aufgeschlossen (Schenk 1984, 1985). Diese granulitfaziellen Gesteine sind bei ihrem Aufstieg in höhere Krustenbereiche nicht durchgreifend überprägt worden. Deshalb läßt sich an ihnen noch der strukturelle Zustand der ehemaligen Unterkruste studieren. Außer in Feldspäten, Quarz und Amphibol tritt auch in Ortho- und Klinopyroxen und in Cordierit Rekristallisation auf. In tieferen Krustenniveaus sind im Quarz basisparallele Subkorngrenzen entwickelt, die in höheren Krustenbereichen nicht auftreten. Sowohl die Gestaltregelungen der gesteinsbildenden Minerale als auch die kristallographischen Plagioklas-, Cordierit-, Amphibol-, Pyroxen- und (seltener) Quarzregelungen spiegeln die Strain-orientierung der prograden hochtemperierten Deformation wider. Während dieser Deformation blieb die Streckung im gesamten Unterkrustenbereich konstant NNE-SSW orientiert. Scherindikatoren sind selten. Beides deutet darauf hin, daß die Deformation homogen und als koachsiale Plättung abgelaufen ist. Im gesamten aufgeschlossenen Unterkrustenbereich variieren weder Intensität noch Orientierung der kristallographischen und gestaltlichen Regelungen der gesteinsbildenden Minerale wesentlich. Deshalb sollten in der ehemaligen Unterkruste Lagen unterschiedlicher Deformation weniger als seismische Reflektoren in Frage kommen als Lagen unterschiedlicher Zusammensetzung.

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Résumé Le Massif de la Serre Septentrionale en Calabre (Sud de l'Italie) représente un tronçon d'une ancienne croûte continentale profonde (Schenk 1984, 1985). Les roches du faciès granulite qui le constituent n'ont pas subi de déformation penetrative lors de leur ascension dans les niveaux plus superficiels de la croûte. Leur étude permet donc de reconstruire les caractéristiques structurales de l'ancienne croûte profonde. Non seulement les feldspaths, le quartz et l'amphibole, mais encore l'orthopyroxène, le clinopyroxène et la cordiérite ont recristallisé. Dans les niveaux les plus profonds de la croûte on observe dans les cristaux de quartz des bordures de sous-grains parallèles à la base. Celles-ci n'apparaissent plus dans les niveaux plus superficiels. L'orientation des cristaux des minéraux constitutifs des roches, de même que l'orientation des réseaux cristallins du plagioclase, de la cordiérite, de l'amphibole, du pyroxène et (mais plus rarement) du quartz réflètent la direction de contrainte de la phase de déformation prograde de haute température. Pendant cette phase de déformation, la direction d'extension est demeurée NNE-SSW. Les témoins de cisaillement sont rares, ce qui montre que la déformation s'est effectuée de façon homogène, en relation avec un aplatissement coaxial. Les textures varient très peu en orientation comme en intensité dans toute la coupe de croûte profonde exposée. En conséquence, l'existence de réflecteurs sismiques devrait refléter des différences dans les compositions minéralogiques des roches plutôt que dans leurs caractéristiques structurales.

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Sublethal abnormalities in embryos of winter flounder,Pseudopleuronectes americanus,from Long Island Sound

Sublethal abnormalities were examined in developing embryos of the winter flounder,Pseudopleuronectes americanus, as part of a study of its early reproductive success in Long Island Sound and two sites in Boston Harbor. These sites represented varying levels of anthropogenic contamination that were possibly affecting reproduction, as ascertained by chromosomal abnormalities and lowered developmental rates in the embryos. Effort was focused on examination of blastula and tail-bund embryos from field-captured females spawned at the laboratory. Abnormalities observed included evidence of cytotoxicity and chromosome damage. Embryos of fish from New Haven were usually the most aberrant, while embryos from other sites, notably Hempstead, Shoreham, and both Boston Harbor stations, showed subtle indications of abnormality.     

Can Brans-Dicke universes in five dimensions be interpreted as 4-dimensional general relativity cosmologies?

The 5-dimensional Jordan-Brans-Dicke cosmologies in vacuum are found for the Bianchi type I metric, their relation with general relativity cosmologies is studied. Two solutions are possible, both produce effective pressure and energy density in the 4-dimensional G.R.-universes. One is a power-law relation, with two cases, the first one is forp _eff=_eff and the other forp _eff=_eff(– 1 < < 1) has a behaviour as the open flat universe. The second solution is an exponential only valid forp _eff=–_eff. In all cases the three-space expansion reaches infinity ast and the fifth dimension can be made to decrease approaching zero. The scalar field can increase or decrease with time.     

Cosmological implications of BL Lac objects

It has become clear in recent years that relativistic beaming is a good explanation for the BL Lac phenomenon. Of studies based on the relativistic beaming model of BL Lac objects, we note that the orientation of jet's axis to the line-of-sight is very small and, therefore, the observed flux emitted from a rapidly moving source is orders of magnitude higher than the flux in its rest-frame:F _obs = ^{3 +} F _intr, where is the bulk relativistic Doppler factor. Then the observed apparent magnitudem _v must be corrected for this effect. For our 39 samples, the corrected apparent magnitudem _v ^corr and logZ have a good correlation.     

Realisation of a celestial system based on VLBI geodynamics programs

The relative orientations of various VLBI celestial reference frames are evaluated on the basis of coordinate differences of common sources. It is shown that an accuracy better than 0.001 can be achieved. Possible regional deformations in the different catalogues are investigated; they are found to reach a few 0.001 in some restricted zones. The application of these studies to the realisation of a combined celestial reference frame consistent with the BIH Terrestrial System is outlined.     

Observed nonpotential magnetic fields and the inferred flow of electric currents at a location of repeated flaring

We have analyzed the vector magnetic field of an active region at a location of repeated flaring to determine the nature of the currents flowing in the areas where the flares initiated. The component of electric current density crossing the photosphere along the line-of-sight was derived from the observed transverse component of the magnetic field. The maximum concentrations of these currents occurred exactly at the sites of flare initiation and where the photospheric field was sheared the most. The calculated distribution of current density at the flare sites suggested that currents were flowing out of an area of positive magnetic polarity and across the magnetic inversion line into two areas of negative polarity. This interpretation was reinforced by a calculation of the source field, the magnetic field produced in the photosphere by the electric currents above the photosphere. In the vicinity of the flare sites, the calculated source field exhibited three particular characteristics: (1) maximum magnitudes at the sites of flare initiation, (2) a rotational direction where the vertical current density was concentrated, and (3) a fairly constant angular orientation with the magnetic inversion line. The source field was thus very similar to the field produced by two arcades of currents crossing the inversion line at the locations of greatest magnetic shear with orientations of about 60° to the inversion line. With this orientation, the inferred arcades would be aligned with the observed chromospheric fibrils seen in the H data so that the currents were field-aligned above the photosphere. The field thus exhibited a vertical gradient of magnetic shear with the shear decreasing upward from the photosphere. We estimated the currents in the two arcades by matching the source field derived from observations with that produced by a model of parallel loops of currents. We found that the loops of the model would each have a radius of 4500 km, a separation of 1830 km, and carry a current of 0.15 × 10¹² A. Values of vertical current densities and source fields appearing in the umbrae of the two large sunspots away from the flare sites were shown to lie at or below the level of uncertainty in the data. The main source of this uncertainty lay in the method by which the 180° ambiguity in the azimuth of the transverse field is resolved in umbral areas. We thus concluded that these quantities in large umbrae should be treated with a healthy skepticism. Finally, we found that the source field at the flare sites was produced almost entirely by the angular difference between the observed and potential field and not by the difference in field intensity.     

The 1 Mpc giant head-tail radio galaxy IC 711: 3-dimensional simulation and additional constraints on the ram pressure theory

Recent observations of the longest known head-tail galaxy IC 711, at long wavelengths have shown it to extend farther than previously known. At δ 74 cm, Vallée and Roger (1987) found it to stretch 17′ (930 kpc) behind the optical nucleus of this elliptical galaxy. At δ92 cm, Vallée and Strom (1988) found it to stretch 18.3′ (1 Mpc) behind the optical nucleus. What new physics can be learned from it? To that end, a theoretical simulation in 3 dimensions of the longest head-tail galaxy has been performed, building the radio trail cell by cell inside a volume of space composed of 8 million cells, with each cell being assigned a proper radio emissivity. Matching ram pressure theory and recent observations yields a primary fast decrease of the radio luminosity with time or distance from the optical nucleus of the galaxy, and a secondary periodic variation of the radio luminosity every 500 kpc. Near the end of the tail, a sudden and unpredicted flare-up of the observed width of the tail requires a sudden change in the jet's physical conditions about 2 Gyr earlier, or that of the surroundings. These simulations provide some additional constraints on the ram pressure theory. Along the tail ridge, particle aging and particle acceleration must combine to give a luminosity function that mimics an exponential decrease with time. Across the tail ridge, no edge brightening is necessary, suggesting that particle aging and particle acceleration must combine via central turbulences and central instabilities (not by edge effects). The disappearance of the radio trail at two points along the radio ridge is unexpected from the ram pressure theory. Thus particle aging and particle acceleration must combine once more to mimic a sinusoidal modulation with time of the radio luminosity, perhaps near the nucleus inside the optical galaxy.     

Spectrophotometric observations of delta Capricorni

Spectrophotometric observations of the eclipsing binary system Capricorni, covering the wavelength interval 3300–7300 Å, have been presented. Comparison of the standard spectral scans of Cap with the spectral scans of the stars of known spectral types and luminosity classes taken from the Breger (1976) catalogue shows that, near the phase of secondary eclipse, Cap shows the spectral-luminosity type as A8-9III. This is in agreement with the photometric findings of Srivastava (1987b). H emission is not visible convincingly, however, some irregularities are apparent, at least in two scans, around the H region.     

Heterodyne spectroscopy of the 158 micron C II line in M42

We have obtained velocity-resolved spectra of the 12C II 157.8 microns 2P3/2-2P1/2 fine structure line in the M42 region of Orion. Observations at 0.8 km s-1 resolution with a laser heterodyne spectrometer show multiple velocity components in some locations, with typical linewidths of 3-5 km s-1. Spectra of theta 1C and BN-KL also show weak emission from the F = 2-1 hyperfine component of the equivalent 13C II line. From the observed 12C II/13C II line intensity ratios, we deduce that the 12C II emission is optically thick with tau approximately 5 at both positions. Excitation temperatures of 128 K and 90 K, together with column densities of approximately 1 x 10(19) cm-2 and approximately 4 x 10(18) cm-2, are derived for theta 1C and BN-KL, respectively.